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1. 发明授权

US08852539B2 Second stage Fischer-Tropsch reaction system to enhance the conversion of synthetic gas 有权
标题翻译：二级费 - 托反应体系，提高合成气转化率
公开(公告)号：US08852539B2
公开(公告)日：2014-10-07
申请号：US13516855
申请日：2011-07-07
申请人： Ho Tae Lee , Heon Jung , Jung Il Yang , Hak Joo Kim , Dong Hyun Chun , Jung Hoon Yang , Ji Chan Park , Byung Kwon Kim
发明人： Ho Tae Lee , Heon Jung , Jung Il Yang , Hak Joo Kim , Dong Hyun Chun , Jung Hoon Yang , Ji Chan Park , Byung Kwon Kim
IPC分类号： B01J8/22 , B01J8/00 , C10G2/00 , C01B3/02
CPC分类号： B01J8/22 , B01J8/006 , B01J2208/00141 , B01J2208/00256 , B01J2219/0004 , C01B3/02 , C01B2203/062 , C10G2/332 , C10G2/341 , C10G2/342 , C10G2300/1022 , C10J2300/1659 , Y02E50/32 , Y02P20/52
摘要： A second stage Fischer-Tropsch reaction system to enhance a conversion ratio of a synthetic gas, includes, at least one first reactor that uses a Fe catalyst, receives a first synthetic gas extracted from a coal, biomass or natural gas, and reacts the first synthetic gas with the Fe catalyst to obtain a synthetic fuel, and a second reactor that uses a Fe.Co or Co catalyst, receives a second synthetic gas discharged from the first reactors after reaction, and reacts the second synthetic gas with the Fe.Co or Co catalyst to obtain a synthetic fuel.
摘要翻译：提供合成气转化率的第二级费 - 托反应系统包括使用Fe催化剂的至少一个第一反应器，接收从煤，生物质或天然气中提取的第一合成气体，并使第一合成气与Fe催化剂合成得到合成燃料，第二反应器使用Fe.Co或Co催化剂，接收反应后从第一反应器排出的第二合成气，并使第二合成气与Fe 或Co催化剂以获得合成燃料。

2. 发明授权

US08642500B2 Method for manufacturing iron catalyst 有权
标题翻译：铁催化剂的制造方法
公开(公告)号：US08642500B2
公开(公告)日：2014-02-04
申请号：US13318198
申请日：2010-11-19
申请人： Dong Hyun Chun , Hak Joo Kim , Ho Tae Lee , Jung Il Yang , Jung Hoon Yang , Heon Jung
发明人： Dong Hyun Chun , Hak Joo Kim , Ho Tae Lee , Jung Il Yang , Jung Hoon Yang , Heon Jung
IPC分类号： B01J21/00
CPC分类号： B01J23/78 , B01J23/745 , B01J23/75 , B01J35/0013 , B01J35/023 , B01J37/0045 , B01J37/0201 , B01J37/038 , B01J37/06 , C10G2/332
摘要： Disclosed is a method for manufacturing an iron catalyst, the method including: a mixing stage where a mixture solution is manufactured by mixing iron nitrate (Fe(NO3)3) solution and copper nitrate (Cu(NO3)2) solution; a precipitation slurry-forming stage where a precipitation slurry is formed by adding at least one of sodium carbonate (Na2CO3) or sodium hydroxide (Na2CO3) solutions to the mixture solution; a washing stage where the precipitation slurry is filtered and washed with distilled water; a silica adding stage where fumed silica powder and potassium carbonate (K2CO3) solution are added to the precipitation slurry and then agitated; a drying stage where the precipitation slurry is passed through a sieve having a size of 30 μm to 100 μm and dried by a spry drying method to manufacture a powdered iron catalyst; and a heat treatment stage where the iron catalyst is dried at a temperature of 50° to 150° C., and then heat-treated at a temperature of 300° C. to 500° C.
摘要翻译：本发明公开了一种铁催化剂的制造方法，其特征在于，包括：将硝酸铁（Fe（NO 3）3）溶液与硝酸铜（Cu（NO 3）2）溶液混合，制成混合溶液的混合阶段; 沉淀浆液形成阶段，其中通过向混合物溶液中加入至少一种碳酸钠（Na 2 CO 3）或氢氧化钠（Na 2 CO 3）溶液形成沉淀浆料; 洗涤阶段，其中沉淀浆液被过滤并用蒸馏水洗涤; 二氧化硅添加阶段，将沉淀二氧化硅粉末和碳酸钾（K 2 CO 3）溶液加入沉淀浆料中，然后搅拌; 将沉淀浆料通过尺寸为30μm至100μm的筛子的干燥阶段，并通过干燥法干燥以制造粉末状铁催化剂; 以及铁催化剂在50℃〜150℃的温度下干燥，然后在300℃〜500℃的温度下进行热处理的热处理阶段。

3. 发明申请

US20060171880A1 Compact steam reformer with metal monolith catalyst and method of producing hydrogen using the same 审中-公开
标题翻译：具有金属整料催化剂的紧凑型蒸汽重整器及使用其制备氢的方法
公开(公告)号：US20060171880A1
公开(公告)日：2006-08-03
申请号：US11322363
申请日：2006-01-03
申请人： Heon Jung , Wang-Lai Yoon , Ho-Tae Lee , Jong-Soo Park , Jung-Il Yang , Jae-Hong Ryu
发明人： Heon Jung , Wang-Lai Yoon , Ho-Tae Lee , Jong-Soo Park , Jung-Il Yang , Jae-Hong Ryu
IPC分类号： B01J23/00 , C01B3/26
CPC分类号： C01B3/40 , B01J8/067 , B01J19/2485 , B01J23/755 , B01J23/78 , B01J35/04 , B01J37/0225 , B01J37/0226 , B01J2208/00212 , B01J2208/00504 , B01J2219/00085 , B01J2219/00157 , C01B2203/0233 , C01B2203/1023 , C01B2203/1058 , C01B2203/1241 , C01B2203/1247 , Y02P20/52
摘要： Disclosed herein is a catalyst structure for steam reformation, in which a nickel-based steam reforming catalyst is coated on a metal monolith. Also disclosed is a method for producing hydrogen using a steam reforming reaction, the method comprising bringing a mixed gas of steam and hydrocarbon into contact with the disclosed catalyst structure.
摘要翻译：本文公开了一种用于蒸汽重整的催化剂结构，其中镍基蒸汽重整催化剂涂覆在金属整料上。还公开了使用蒸汽重整反应生产氢的方法，该方法包括使蒸汽和烃的混合气体与所公开的催化剂结构接触。

4. 发明申请

US20130237410A1 Method for Manufacturing Iron Catalyst 有权
标题翻译：制造铁催化剂的方法
公开(公告)号：US20130237410A1
公开(公告)日：2013-09-12
申请号：US13318198
申请日：2010-11-19
申请人： Dong Hyun Chun , Hak Joo Kim , Ho Tae Lee , Jung Il Yang , Jung Hoon Yang , Heon Jung
发明人： Dong Hyun Chun , Hak Joo Kim , Ho Tae Lee , Jung Il Yang , Jung Hoon Yang , Heon Jung
IPC分类号： B01J23/78
CPC分类号： B01J23/78 , B01J23/745 , B01J23/75 , B01J35/0013 , B01J35/023 , B01J37/0045 , B01J37/0201 , B01J37/038 , B01J37/06 , C10G2/332
摘要： Disclosed is a method for manufacturing an iron catalyst, the method including: a mixing stage where a mixture solution is manufactured by mixing iron nitrate (Fe(NO3)3) solution and copper nitrate (Cu(NO3)2) solution; a precipitation slurry-forming stage where a precipitation slurry is formed by adding at least one of sodium carbonate (Na2CO3) or sodium hydroxide (Na2CO3) solutions to the mixture solution; a washing stage where the precipitation slurry is filtered and washed with distilled water; a silica adding stage where fumed silica powder and potassium carbonate (K2CO3) solution are added to the precipitation slurry and then agitated; a drying stage where the precipitation slurry is passed through a sieve having a size of 30 μm to 100 μm and dried by a spry drying method to manufacture a powdered iron catalyst; and a heat treatment stage where the iron catalyst is dried at a temperature of 50° to 150° C., and then heat-treated at a temperature of 300° C. to 500° C.
摘要翻译：本发明公开了一种铁催化剂的制造方法，其特征在于，包括：将硝酸铁（Fe（NO 3）3）溶液与硝酸铜（Cu（NO 3）2）溶液混合而成的混合溶液的混合阶段，沉淀浆液形成阶段，其中通过向混合物溶液中加入至少一种碳酸钠（Na 2 CO 3）或氢氧化钠（Na 2 CO 3）溶液形成沉淀浆料; 洗涤阶段，其中沉淀浆液被过滤并用蒸馏水洗涤; 二氧化硅添加阶段，将沉淀二氧化硅粉末和碳酸钾（K 2 CO 3）溶液加入沉淀浆料中，然后搅拌; 将沉淀浆料通过尺寸为30μm至100μm的筛子的干燥阶段，并通过干燥法干燥以制造粉末状铁催化剂; 以及铁催化剂在50℃〜150℃的温度下干燥，然后在300℃〜500℃的温度下进行热处理的热处理阶段。

5. 发明申请

US20120329889A1 METHOD FOR MAKING A COBALT METAL FOAM CATALYST IN WHICH A COBALT CATALYST POWDER IS COATED ONTO THE SURFACE OF A METAL FOAM, THE COBALT METAL FOAM CATALYST, A THERMAL-MEDIUM- CIRCULATING HEAT-EXCHANGE REACTOR USING THE COBALT METAL FOAM CATALYST, AND A METHOD FOR PRODUCING A LIQUID FUEL BY MEANS OF A FISCHER-TROPSCH SYNTHESIS REACTION USING THE THERMAL-MEDIUM-CIRCULATING HEAT-EXCHANGE REACTOR 审中-公开
标题翻译：制备钴盐催化剂的方法，其中钴催化剂粉末涂覆在金属泡沫的表面上，钴金属泡沫催化剂，使用钴金属泡沫催化剂的中温循环交换反应器和方法用中温循环换热器反应器进行FISCHER-TROPSCH合成反应生产液体燃料
公开(公告)号：US20120329889A1
公开(公告)日：2012-12-27
申请号：US13579070
申请日：2010-02-25
申请人： Jung-Il Yang , Jung-Hoon Yang , Chang-Hyun Ko , Heon Jung , Ho-Tae Lee , Hak-Joo Kim , Dong-Hyun Chun
发明人： Jung-Il Yang , Jung-Hoon Yang , Chang-Hyun Ko , Heon Jung , Ho-Tae Lee , Hak-Joo Kim , Dong-Hyun Chun
IPC分类号： B01J23/755 , B01J19/00 , C07C1/04 , B01J23/75
CPC分类号： C10G2/34 , B01J8/22 , B01J23/75 , B01J35/04 , B01J37/0205 , B01J37/0217 , B01J37/0219 , B01J37/0225 , B01J37/0238 , B01J37/0244 , B01J37/0248 , B01J37/16 , B01J2208/00212 , C10G2/332 , C10G2300/70
摘要： The present invention relates to a method of manufacturing a cobalt metal foam catalyst including a metal foam coated with cobalt catalyst powder, a cobalt metal foam catalyst manufactured by the method, a thermal medium-circulated heat exchanger type reactor using the cobalt metal foam catalyst, and a method of producing liquid fuel by Fischer-Tropsch synthesis using the reactor. An object of the present invention is to provide a catalyst, which is used to obtain high liquid fuel productivity even at a low CO conversion ratio because the reaction temperature can be kept stable by controlling reaction heat with high efficiency in Fischer-Tropsch synthesis so that the mass transfer characteristics of a catalyst layer can be improved, and a method of manufacturing the catalyst, a reactor filled with the catalyst, and a method of producing liquid fuel using the reactor. The method of manufacturing a cobalt metal foam catalyst includes the steps of: surface-pretreating a metal foam by atomic layer deposition (ALD) using trimethylaluminum ((CH3)3Al) and water to form an Al2O3 thin film; preparing a cobalt catalyst slurry composed of a mixture of alumina sol, cobalt catalyst powder and isopropyl alcohol; surface-coating the surface-pretreated metal foam with the cobalt catalyst slurry by dip coating; and drying and calcinating the surface-pretreated metal foam coated with the cobalt catalyst slurry.
摘要翻译：本发明涉及一种制造钴金属泡沫催化剂的方法，该催化剂包括涂覆有钴催化剂粉末的金属泡沫，通过该方法制造的钴金属泡沫催化剂，使用该钴金属泡沫催化剂的热介质循环热交换器型反应器，以及使用该反应器通过费 - 托合成来生产液体燃料的方法。本发明的目的是提供一种催化剂，其即使在低CO转化率下也可用于获得高的液体燃料生产率，因为通过在费 - 托合成中以高效率控制反应热量可以保持反应温度稳定，使得可以提高催化剂层的传质特性，制造催化剂的方法，填充有催化剂的反应器和使用反应器生产液体燃料的方法。制造钴金属泡沫催化剂的方法包括以下步骤：使用三甲基铝（（CH3）3A1）和水来进行原子层沉积（ALD）表面预处理金属泡沫以形成Al 2 O 3薄膜; 制备由氧化铝溶胶，钴催化剂粉末和异丙醇的混合物组成的钴催化剂浆料; 通过浸涂用钴催化剂浆料表面涂覆表面处理的金属泡沫; 以及干燥和煅烧涂覆有钴催化剂浆料的表面处理的金属泡沫。

6. 发明授权

US06634119B2 Adsorptive ethanol drying apparatus using microwaves and operating method thereof 有权
公开(公告)号：US06634119B2
公开(公告)日：2003-10-21
申请号：US09897800
申请日：2001-06-29
申请人： Jong Kee Park , Soon Haeng Cho , Jong Nam Kim , Jung Il Yang , Hee Tae Beom
发明人： Jong Kee Park , Soon Haeng Cho , Jong Nam Kim , Jung Il Yang , Hee Tae Beom
IPC分类号： F26B300
CPC分类号： B01D53/0438 , B01D53/0423 , B01D53/261 , B01D2253/108 , B01D2256/24 , B01D2259/40094
摘要： Disclosed is an adsorptive ethanol drying apparatus in which microwaves are applied during the regeneration of an absorbent conducted in a continuous adsorption process for drying ethanol, so that the absorbent regeneration can be rapidly achieved at a temperature lower than that used in a conventional heating type regeneration method and within a reduced processing time, thereby being capable of allowing an efficient use of energy while improving the productivity per adsorbent mass. A method for operating the adsorptive ethanol drying apparatus is also disclosed. At an adsorption step, a vaporized ethanol azeotropic mixture is forced to pass through adsorption towers to adsorb water contained in the vaporized ethanol azeotropic mixture to an adsorbent charged in each of the adsorption towers while condensing ethanol in a storage tank. Simultaneously with the adsorption step conducted in one of the adsorption towers, microwaves generated from a microwave generating device are guided to the other adsorption tower via waveguides in accordance with a switching operation of a switching waveguide, thereby activating water adsorbed to the adsorbent in the adsorption step to allow the water to be desorbed from the adsorbent. Slight vacuum is also applied to the other adsorption tower, thereby removing the desorbed water.

7. 发明授权

US06476652B1 Delay locked loop for use in synchronous dynamic random access memory 有权
标题翻译：延迟锁定环用于同步动态随机存取存储器
公开(公告)号：US06476652B1
公开(公告)日：2002-11-05
申请号：US09703406
申请日：2000-10-31
申请人： Seong-Hoon Lee , Jung-Il Yang
发明人： Seong-Hoon Lee , Jung-Il Yang
IPC分类号： H03L700
CPC分类号： G11C7/222 , G11C7/22
摘要： A delay locked loop (DLL) is used to compensate for a skew in a synchronous dynamic random access memory. The delay locked loop includes: a delay model for delaying an external clock signal by the skew to generate a delayed clock signal; a signal generation unit, in response to the external clock signal and the delayed clock signal, for generating control signals; a first delay unit, in response to the control signals, for delaying the delayed control signal to generate a first DLL clock signal, wherein the first delay unit has a large unit delay; and a second delay unit, in response to the control signals, for delaying the first DLL clock signal to generate a second DLL clock signal, wherein the second delay means in a small unit delay.
摘要翻译：延迟锁定环（DLL）用于补偿同步动态随机存取存储器中的偏斜。延迟锁定环包括：用于通过偏斜延迟外部时钟信号以产生延迟的时钟信号的延迟模型; 信号生成单元，响应于所述外部时钟信号和所述延迟的时钟信号，用于产生控制信号; 第一延迟单元，响应于所述控制信号，用于延迟所述延迟的控制信号以产生第一DLL时钟信号，其中所述第一延迟单元具有大的单位延迟; 以及响应于所述控制信号的第二延迟单元，用于延迟所述第一DLL时钟信号以产生第二DLL时钟信号，其中所述第二延迟装置以小的单位延迟。

8. 发明申请

US20120275975A1 SECOND STAGE FISCHER-TROPSCH REACTION SYSTEM TO ENHANCE THE CONVERSION OF SYNTHETIC GAS 有权
标题翻译：第二阶段FISCHER-TROPSCH反应系统，以提高合成气转化率
公开(公告)号：US20120275975A1
公开(公告)日：2012-11-01
申请号：US13516855
申请日：2011-07-07
申请人： Ho Tae Lee , Heon Jung , Jung Il Yang , Hak Joo Kim , Dong Hyun Chun , Jung Hoon Yang , Ji Chan Park , Byung Kwon Kim
发明人： Ho Tae Lee , Heon Jung , Jung Il Yang , Hak Joo Kim , Dong Hyun Chun , Jung Hoon Yang , Ji Chan Park , Byung Kwon Kim
IPC分类号： B01J8/00
CPC分类号： B01J8/22 , B01J8/006 , B01J2208/00141 , B01J2208/00256 , B01J2219/0004 , C01B3/02 , C01B2203/062 , C10G2/332 , C10G2/341 , C10G2/342 , C10G2300/1022 , C10J2300/1659 , Y02E50/32 , Y02P20/52
摘要： A second stage Fischer-Tropsch reaction system to enhance a conversion ratio of a synthetic gas, includes, at least one first reactor that uses a Fe catalyst, receives a first synthetic gas extracted from a coal, biomass or natural gas, and reacts the first synthetic gas with the Fe catalyst to obtain a synthetic fuel, and a second reactor that uses a Fe.Co or Co catalyst, receives a second synthetic gas discharged from the first reactors after reaction, and reacts the second synthetic gas with the Fe.Co or Co catalyst to obtain a synthetic fuel.
摘要翻译：提供合成气转化率的第二级费 - 托反应系统包括使用Fe催化剂的至少一个第一反应器，接收从煤，生物质或天然气中提取的第一合成气体，并使第一合成气与Fe催化剂合成得到合成燃料，第二反应器使用Fe.Co或Co催化剂，接收反应后从第一反应器排出的第二合成气，并使第二合成气与Fe 或Co催化剂以获得合成燃料。

9. 发明授权

US6022398A Adsorption separation and purification apparatus and process for high purity isobutane production 失效
标题翻译：高纯异丁烷生产吸附分离纯化装置及工艺
公开(公告)号：US6022398A
公开(公告)日：2000-02-08
申请号：US34023
申请日：1998-03-02
申请人： Soon-Haeng Cho , Sang-Sup Han , Jong-Nam Kim , Kuck-Tack Chue , Jung-Il Yang , Hee-Tae Beum
发明人： Soon-Haeng Cho , Sang-Sup Han , Jong-Nam Kim , Kuck-Tack Chue , Jung-Il Yang , Hee-Tae Beum
IPC分类号： B01D53/04 , B01D53/02 , B01D53/053 , C07C7/12 , C07C9/12
CPC分类号： B01D53/053 , B01D2253/102 , B01D2253/108 , B01D2256/24 , B01D2259/40007 , B01D2259/40066 , B01D2259/402 , B01D53/0423 , B01D53/0446
摘要： A high purity isobutane adsorption separation and purification apparatus is provided including a pressure regulator which regulates the pressure of an isobutane-containing gas; the at least one adsorption bed packed with zeolite 5A and carbon molecular sieve arranged downstream of and operatively associated with the pressure regulator; a flow control valve disposed between the pressure regulator and the at least one adsorption bed; a surge tank operatively associated with and for receiving a purified isobutane product from the at least one adsorption bed; a vacuum pump operatively associated with and for removal of impurities from the at least one adsorption bed; and valves disposed between the pressure regulator and the at least one adsorption bed, between the at least one adsorption bed and the surge tank, and between the at least one adsorption bed and the vacuum pump. An adsorptive separation and isobutane purification process is also provided which may be used with the apparatus of the invention.
摘要翻译：提供了一种高纯度异丁烷吸附分离和净化装置，包括调节含异丁烷的气体的压力的压力调节器; 填充有沸石5A的至少一个吸附床和布置在压力调节器的下游并与压力调节器可操作地相关联的碳分子筛; 设置在所述压力调节器和所述至少一个吸附床之间的流量控制阀; 调节罐，其与所述至少一个吸附床可操作地相关联并用于接收纯化的异丁烷产物; 与所述至少一个吸附床可操作地相关联并用于从所述至少一个吸附床去除杂质的真空泵; 以及设置在所述压力调节器和所述至少一个吸附床之间，所述至少一个吸附床和所述缓冲罐之间以及所述至少一个吸附床和所述真空泵之间的阀。还提供了可与本发明的装置一起使用的吸附分离和异丁烷纯化方法。

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