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    • 1. 发明申请
    • Thermoplastic Polyurethane With Reduced Tendency To Bloom From A Bio-Based Glycol
    • 热塑性聚氨酯具有降低从生物基二醇出现的倾向
    • US20140107311A1
    • 2014-04-17
    • US14118314
    • 2012-06-11
    • Julius Farkas
    • Julius Farkas
    • C08G71/04
    • C08G18/4238C08G18/10C08G18/664
    • The present invention discloses a thermoplastic polyurethane comprised of the reaction product of (1) a hydroxyl terminated polyester intermediate, (2) a polyisocyanate, and (3) a glycol chain extender; wherein the polyester intermediate is comprised of repeat units derived from a 1,3-propylene glycol component and a dicarboxylic acid wherein the 1,3-propylene glycol component comprises a bio-based 1,3-propylene glycol; wherein the polyester intermediate has a number average molecular weight from 500 to 10,000; and wherein the polyurethane includes hard segments that are the reaction product of the polyisocyanate and the glycol chain extender. This thermoplastic polyurethane is unique as it has a greatly reduced tendency to bloom and is prepared from a renewable material. Blooming causes articles containing the polyurethane to be hazy or foggy in appearance and can also reduce the ability of an article to be securely bound to another with an adhesive.
    • 本发明公开了一种由(1)羟基封端的聚酯中间体,(2)多异氰酸酯和(3)乙二醇扩链剂的反应产物组成的热塑性聚氨酯; 其中所述聚酯中间体由衍生自1,3-丙二醇组分和二羧酸的重复单元组成,其中所述1,3-丙二醇组分包含生物基1,3-丙二醇; 其中所述聚酯中间体的数均分子量为500至10,000; 并且其中所述聚氨酯包括作为所述多异氰酸酯和所述乙二醇扩链剂的反应产物的硬链段。 这种热塑性聚氨酯是独特的,因为它具有大大降低的开花倾向并且由可再生材料制备。 盛产会使含有聚氨酯的物品在外观上模糊或有雾,并且还可以降低制品与粘合剂牢固地粘结于另一种物品的能力。
    • 2. 发明授权
    • Melt spun polyether TPU fibers having mixed polyols and process
    • 具有混合多元醇和工艺的熔融纺丝聚醚TPU纤维
    • US08148475B2
    • 2012-04-03
    • US10880001
    • 2004-06-29
    • Ravi R. VedulaYona EcksteinYinbing XiaJames E. Bryson, Jr.Christopher A. SpragueJulius Farkas
    • Ravi R. VedulaYona EcksteinYinbing XiaJames E. Bryson, Jr.Christopher A. SpragueJulius Farkas
    • C08G18/10C08G18/48C08J3/24
    • D01F6/70C08G18/12C08G18/3206C08G18/3215C08G18/4808C08G18/4854C08G18/6674C08G18/7657D06P3/82Y10T442/60C08G18/48C08G18/42
    • Thermoplastic polyether polyurethane polymers are disclosed which are mixed with a crosslinking agent to achieve long run times in a melt spinning process to make elastic fibers. The crosslinking agent is preferably a polyether or polyester polyol reacted with a diisocyanate. A melt spinning process is also disclosed using a polyether polyurethane with a crosslinking agent. Long melt spinning run times can be achieved without experiencing excessive pressure buildup in the spinneret and fiber breakage. The thermoplastic polyether polyurethane polymers are made by reacting: (1) a blend of two or more hydroxyl terminated intermediates wherein one intermediate is a polyether intermediate and has a higher number average molecular weight than the other said polyether intermediates, and wherein the weighted average number average molecular weight of said blend is greater than 1200 Daltons; (2) at least one polyisocyanate; and (3) at least one hydroxyl terminated chain extender. Melt spun fibers disclosed have excellent dye pickup, bleach resistance, and color fastness. The melt spun fibers can be dyed with polyester fibers and retain excellent physical properties.
    • 公开了热塑性聚醚聚氨酯聚合物,其与交联剂混合以在熔融纺丝工艺中实现长时间以制备弹性纤维。 交联剂优选与二异氰酸酯反应的聚醚或聚酯多元醇。 还公开了使用具有交联剂的聚醚聚氨酯的熔融纺丝法。 可以实现长熔融纺丝运行时间,而不会在喷丝头和纤维断裂中产生过大的压力。 热塑性聚醚聚氨酯聚合物通过以下方法制备:(1)两个或多个羟基封端的中间体的共混物,其中一个中间体是聚醚中间体并且具有比其它所述聚醚中间体更高的数均分子量,并且其中加权平均数 所述共混物的平均分子量大于1200道尔顿; (2)至少一种多异氰酸酯; 和(3)至少一个羟基封端的扩链剂。 公开的熔纺纤维具有优异的染料吸收,耐漂白性和耐色牢度。 熔纺纤维可以用聚酯纤维染色并保持优异的物理性能。
    • 9. 发明授权
    • Soft, elastic, plasticizer-free thermoplastic polyurethane and process to synthesize the same
    • 软,弹性,无增塑剂的热塑性聚氨酯及其合成方法
    • US08183330B2
    • 2012-05-22
    • US12255889
    • 2008-10-22
    • Julius FarkasRavi R. VedulaCharles P. Jacobs
    • Julius FarkasRavi R. VedulaCharles P. Jacobs
    • C08G63/06
    • C08G18/664C08G18/0895C08G18/4238C08G2410/00Y10T442/30Y10T442/40Y10T442/681
    • The present invention discloses a thermoplastic polyurethane which is comprised of the reaction product of (1) a hydroxyl terminated intermediate, (2) a polyisocyanate, and (3) a glycol chain extender selected from the group consisting of ethylene glycol and propylene glycol; wherein the hydroxyl terminated intermediate is selected from the group consisting of hydroxyl terminated polyether intermediates and hydroxyl terminated polyester intermediates; wherein the hydroxyl terminated intermediate is comprised of repeat units that are derived from a branched glycol or is comprised of at least 2 different repeating units; wherein the thermoplastic polyurethane has a weight average molecular weight of at least 100,000 Daltons; wherein the thermoplastic polyurethane includes hard segments that are the reaction product of the polyisocyanate and the glycol chain extender; and wherein the hard segments represent from 10 to 40 weight percent of the total weight of the thermoplastic polyurethane.
    • 本发明公开了一种热塑性聚氨酯,其由(1)羟基封端的中间体,(2)多异氰酸酯和(3)选自乙二醇和丙二醇的二醇扩链剂的反应产物组成; 其中羟基封端的中间体选自羟基封端的聚醚中间体和羟基封端的聚酯中间体; 其中羟基封端的中间体由衍生自支化二醇的重复单元组成或由至少2个不同的重复单元组成; 其中所述热塑性聚氨酯具有至少100,000道尔顿的重均分子量; 其中所述热塑性聚氨酯包括作为所述多异氰酸酯和所述乙二醇增链剂的反应产物的硬链段; 并且其中硬链段占热塑性聚氨酯总重量的10-40重量%。