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1. 发明授权

US4702784A Process for production of a tungsten carbide-activated electrode 失效
标题翻译：生产碳化钨活化电极的方法
公开(公告)号：US4702784A
公开(公告)日：1987-10-27
申请号：US741637
申请日：1985-06-05
申请人： Aristides Naoumidis , Herbert Neumeister , Arno Schirbach , Bernd D. Struck , Dieter Triefenbach
发明人： Aristides Naoumidis , Herbert Neumeister , Arno Schirbach , Bernd D. Struck , Dieter Triefenbach
IPC分类号： C25B11/04 , C25B11/12 , C25B1/22
CPC分类号： C25B11/0447 , C25B11/12
摘要： A process is disclosed for the production of a tungsten carbide-activated electrode, particularly an electrode which is utilizable as a cathode, and which consists of an electrically-conductive substrate with an active surface layer of tungsten carbide. The tungsten carbide is adhesively bonded through chemical reaction to the surface of a substrate which is constituted of graphite or a graphite-like material. The graphite-like material is a graphite binder mixture, whose binder material components, other than the graphitic filler granules, are only carbonized, and may not be completely graphited.
摘要翻译：公开了用于生产碳化钨活化电极，特别是可用作阴极的电极，并且由具有碳化钨活性表面层的导电基底组成的方法。通过化学反应将碳化钨粘结到由石墨或石墨状材料构成的基板的表面上。石墨状材料是石墨粘合剂混合物，其除了石墨填料颗粒之外的粘合剂材料成分仅被碳化，并且可能不完全石墨化。

2. 发明授权

US5954935A Electrolytic cell arrangement for the deionization of aqueous solutions 失效
标题翻译：用于水溶液去离子的电解槽排列
公开(公告)号：US5954935A
公开(公告)日：1999-09-21
申请号：US756986
申请日：1996-11-26
申请人： Herbert Neumeister , Leander Furst , Reinhold Flucht
发明人： Herbert Neumeister , Leander Furst , Reinhold Flucht
IPC分类号： B01D61/44 , B01D61/48 , B01J47/08 , C02F1/42 , C02F1/46 , C02F1/469
CPC分类号： C02F1/4695 , B01D61/445 , B01D61/48 , B01J47/08 , C02F1/42 , C02F1/4604 , C02F2201/4611 , C02F2201/46115
摘要： In an electrochemical cell arrangement for the deionization of aqueous solutions by ion exchange including cathode and anode chambers having electrodes disposed therein, a brine chamber is disposed between, and directly adjacent to, the cathode and anode chambers which are filled with anion and cation exchanger materials such that the electrodes are directly in contact therewith and means are provided for conducting the aqueous solution to be treated through the cathode and anode chambers and means for passing brine through the brine chamber to be charged therein by the ions removed from the aqueous solution in the cathode and anode chambers.
摘要翻译：在用于通过离子交换去离子水溶液的电化学电池装置中，包括具有设置在其中的电极的阴极室和阳极室，盐水室设置在阴极室和阳极室之间，并且与阴极和阳离子交换材料使得电极直接与其接触，并且提供用于通过阴极和阳极室传导待处理水溶液的装置和用于使盐水通过盐水室的装置，以通过在水溶液中从在水溶液中除去的离子阴极和阳极室。

3. 发明授权

US4330378A Electrolysis cell and method for electrolytic production of hydrogen 失效
标题翻译：电解槽和氢电解生产方法
公开(公告)号：US4330378A
公开(公告)日：1982-05-18
申请号：US208933
申请日：1980-11-21
申请人： Dagmar Boltersdorf , Robert Junginger , Bernd D. Struck , Herbert Neumeister
发明人： Dagmar Boltersdorf , Robert Junginger , Bernd D. Struck , Herbert Neumeister
IPC分类号： C25B1/02 , C25B1/22 , C25B9/00 , C25B9/08
CPC分类号： C25B9/08 , C25B1/02 , C25B1/22
摘要： The production of hydrogen by electrolysis in a cell, in which the anode electrolyte contains sulfur dioxide as well as sulfuric acid and an intermediate chamber separated from the anode and cathode chambers by cation-exchanger membranes is provided through which an electrolyte flows in order to prevent sulfur dioxide from reaching the cathode chamber is greatly improved by using as the anode side membrane a cation-exchanger in which a polyvinyl chloride skeleton is combined with a polymer of styrol and divinyl benzol to which sulfonic acid groups have been attached, such a membrane having a very low resistivity, thus reducing the necessary electrolysis voltage. Such a membrane also loses conductivity with increasing sulfuric acid concentration at a lower rate than membranes previously used in such an electrolysis process and permits a higher sulfuric acid concentration in the anode electrolyte. The improvement on the anode side makes possible the operation of the cathode at low sulfuric acid electrolyte concentration, below 20 or even 10% by weight. Through-flow electrodes of porous graphite encased except on the membrane side by impermeable graphite further improve the operation of the process, especially if they fill the electrolyte chamber right up to the membrane.
摘要翻译：通过在电池中电解生产氢，其中阳极电解质含有二氧化硫以及硫酸，以及通过阳离子交换膜从阳极室和阴极室分离的中间室，通过电解液流过以防止通过将聚氯乙烯骨架与其中已经连接有磺酸基团的苯乙烯和二乙烯基苯酚的聚合物组合的阳离子交换剂用作阳极侧膜，可以大大改善到达阴极室的二氧化硫，这样的膜具有电阻率非常低，从而减少必要的电解电压。这样的膜也会随着硫酸浓度的增加而以比先前在这种电解方法中使用的膜低的速率降低导电性并允许阳极电解质中的较高的硫酸浓度。在阳极侧的改进使阴极在低硫酸电解质浓度下的操作成为可能，低于20甚至10重量％。通过不渗透石墨在膜侧除外的多孔石墨的通流电极进一步改善了该方法的操作，特别是如果它们将电解液室填充到膜上。

4. 发明授权

US4873121A Cathode/membrane assembly and method of making same 失效
标题翻译：阴极/膜组件及其制造方法
公开(公告)号：US4873121A
公开(公告)日：1989-10-10
申请号：US118416
申请日：1987-11-06
申请人： Bernd D. Struck , Herbert Neumeister , Aristides Naoumidis
发明人： Bernd D. Struck , Herbert Neumeister , Aristides Naoumidis
IPC分类号： C25B11/04 , C25B9/10
CPC分类号： C25B9/10
摘要： A cathode/membrane assembly for an electrolysis cell capable of producing hydrogen in a cathode compartment, utilizes as the cathode material on a proton-permeable solid-electrolite ion-exchange membrane, a layer of porous graphite in the form of carbonaceous fibers coated with tungsten carbide. The graphite felt can be impregnated with an aqueous solution of para-ammoniumtungstate or with an alcoholic solution of tungsten hexachloride and the tungsten compounds are then converted to the tungsten oxides. The tungsten oxide coated graphite felt is then subjected to carburization at a temperature of 620.degree. to 950.degree. C. in a carburizing atmosphere, preferably a flowing CO/CO.sub.2 mixture.
摘要翻译：用于在阴极室中产生氢的电解池的阴极/膜组件在质子可渗透的固体 - 电石离子交换膜上用作阴极材料，涂覆有钨的碳质纤维形式的多孔石墨层碳化物。石墨毡可以用钨酸钨铵水溶液或六氯化钨的醇溶液浸渍，然后将钨化合物转化成钨氧化物。然后将氧化钨涂覆的石墨毡在渗碳气氛中，优选流动的CO / CO 2混合物中，在620℃至950℃的温度下进行渗碳。

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