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1. 发明授权

US5763730A Process for alkane isomerization using reactive chromatography 失效
标题翻译：使用反应层析的烷烃异构化方法
公开(公告)号：US5763730A
公开(公告)日：1998-06-09
申请号：US666717
申请日：1996-06-18
申请人： Hemant W. Dandekar , Gregory A. Funk , Ralph D. Gillespie , Herman A. Zinnen , Charles P. McGonegal , Masami Kojima , Simon H. Hobbs
发明人： Hemant W. Dandekar , Gregory A. Funk , Ralph D. Gillespie , Herman A. Zinnen , Charles P. McGonegal , Masami Kojima , Simon H. Hobbs
IPC分类号： C07C5/27 , C07C7/13 , C07C9/12 , C07C9/16 , C07C9/18 , C07C5/122
CPC分类号： C07C5/2789 , C07C5/2791 , C07C7/13 , C07C9/12 , C07C9/16 , C07C9/18 , C07C2521/04 , C07C2521/06 , C07C2523/42 , C07C2523/54 , C07C2527/126 , C07C2529/22 , Y02P20/582
摘要： A process for the continuous isomerization of an alkane to produce an isomerized product through contacting the alkane with a simulated moving bed acting as a catalyst for isomerization and an adsorbent for the alkanes has been developed. The alkane may be n-butane and the isomerized product 2-methylpropane, the alkane may be n-pentane and the isomerized product 2-methylbutane or 2,2-dimethylpropane, the alkane may have from 6 up to about 8 carbon atoms with no more than one methyl branch and the isomerized product having the same number of carbon atoms and at least two methyl branches, or the reactant may be a mixture of the foregoing alkanes with the corresponding isomerized products being formed. In a zone of the simulated moving bed, the alkanes are catalytically isomerized to form the isomerized products. The unreacted alkanes are adsorbed, and the isomerized products are collected. In a subsequent zone of the simulated moving bed, the unreacted alkanes are desorbed using a desorbent and may be catalytically isomerized to form additional isomerized products which are also separated and collected. The catalyst used in the simulated moving bed may be platinum on tungstated zirconia, and the adsorbent used in the simulated moving bed may be EU-1, ZSM-12, SAPO-5, Y-82, faujasite, erionite, zeolite beta exchanged with sodium, lithium, potassium, barium, calcium, strontium or combinations thereof, zeolite X exchanged with calcium and strontium, mordenite exchanged with sodium, lithium, potassium, barium, calcium, strontium, or combinations thereof.
摘要翻译：已经开发了通过使烷烃与用作异构化的催化剂的模拟移动床和用于烷烃的吸附剂使烷烃连续异构化以产生异构化产物的方法。烷烃可以是正丁烷，异构化产物2-甲基丙烷，烷烃可以是正戊烷，异构化产物2-甲基丁烷或2,2-二甲基丙烷，烷烃可以具有6个至约8个碳原子，没有多于一个甲基支链和具有相同数目的碳原子和至少两个甲基支链的异构化产物，或者反应物可以是前述烷烃与形成相应的异构化产物的混合物。在模拟移动床的区域中，烷烃被催化异构化以形成异构化产物。未反应的烷烃被吸附，收集异构化产物。在模拟移动床的随后区域中，未反应的烷烃使用解吸剂解吸，并且可以被催化异构化以形成也被分离和收集的另外的异构化产物。在模拟移动床中使用的催化剂可以是钨酸氧化锆上的铂，模拟移动床中使用的吸附剂可以是EU-1，ZSM-12，SAPO-5，Y-82，八面沸石，毛沸石，沸石β与钠，锂，钾，钡，钙，锶或其组合，与钙和锶交换的沸石X，与钠，锂，钾，钡，钙，锶或它们的组合交换的丝光沸石。

2. 发明授权

US5744645A Two-stage process for producing diisopropyl ether using catalytic distillation 失效
标题翻译：使用催化蒸馏生产二异丙醚的两阶段方法
公开(公告)号：US5744645A
公开(公告)日：1998-04-28
申请号：US625859
申请日：1996-04-01
申请人： Terry L. Marker , Gregory A. Funk , Paul T. Barger , Harold U. Hammershaimb
发明人： Terry L. Marker , Gregory A. Funk , Paul T. Barger , Harold U. Hammershaimb
IPC分类号： C07C41/05 , C07C41/42 , C07C41/00
CPC分类号： C07C41/06 , C07C29/04 , C07C41/42 , Y02P20/127
摘要： A process for the efficient production of diisopropyl ether where catalytic distillation is used to increase the yield of product beyond thermodynamic equilibrium limitations has been developed. In a hydration zone the propylene in a feedstock is reacted with water in the presence of a catalyst to effect hydration to produce an effluent stream containing at least water, unreacted propylene, and isopropyl alcohol, and then, in an etherification zone, at least a portion of the effluent stream is further reacted by catalytic distillation in the presence of a catalyst to effect reaction of propylene and isopropyl alcohol to form diisopropyl ether while concurrently separating an organic portion containing the diisopropyl ether and an aqueous portion, and collecting the organic portion containing the diisopropyl ether.
摘要翻译：已经开发了一种有效生产二异丙醚的方法，其中使用催化蒸馏来提高产物的产率超过热力学平衡限制。在水合区中，原料中的丙烯在催化剂存在下与水反应以进行水合以产生至少含有水，未反应的丙烯和异丙醇的流出物流，然后在醚化区中至少在催化剂存在下，通过催化蒸馏进一步使部分流出物流进行反应，以使丙烯和异丙醇反应形成二异丙醚，同时分离含有二异丙醚和水溶液部分的有机部分，收集含有二异丙醚。

3. 发明授权

US5618972A Process for continuous reaction and separation using fixed catalyst bed serially connected to simulated moving catalyst and adsorbent bed 失效
标题翻译：使用与模拟移动催化剂和吸附剂床连续连接的固定催化剂床的连续反应和分离方法
公开(公告)号：US5618972A
公开(公告)日：1997-04-08
申请号：US394995
申请日：1995-02-27
申请人： Gregory A. Funk , Hemant W. Dandekar , Simon H. Hobbs
发明人： Gregory A. Funk , Hemant W. Dandekar , Simon H. Hobbs
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , Y02P20/582
摘要： A two-stage process for effecting a chemical reaction has been developed. The reactants are contacted with a first stage fixed catalyst bed containing a solid catalyst or mixture of catalysts effective to catalyze the reaction and form a mixture of reactants and products. This reaction mixture and a desorbent are then contacted with a second stage simulated moving bed containing a solid or a mixture of solids effective to catalyze the reaction and to selectively adsorb at least one component from the reaction mixture. At least one product-containing stream is formed and collected. The process may be conducted in the liquid phase or in the vapor phase.
摘要翻译：已经开发了用于进行化学反应的两阶段方法。反应物与含有固体催化剂或有效催化反应并形成反应物和产物的混合物的催化剂混合物的第一阶段固定催化剂床接触。然后将该反应混合物和解吸剂与含有有效催化反应的固体或固体混合物的第二阶段模拟移动床接触，并从反应混合物中选择性吸附至少一种组分。形成并收集至少一种含有产物的流。该方法可以在液相或气相中进行。

4. 发明授权

US5811630A PSA process with reaction for reversible reactions 失效
标题翻译： PSA方法与可逆反应有反应
公开(公告)号：US5811630A
公开(公告)日：1998-09-22
申请号：US638705
申请日：1996-04-29
申请人： Hemant W. Dandekar , Gregory A. Funk
发明人： Hemant W. Dandekar , Gregory A. Funk
IPC分类号： C07C5/27 , C07C7/13 , C07C29/151 , C07C29/152 , C07C5/22 , B01D53/047 , C07C7/12 , C07C9/14
CPC分类号： C07C5/2772 , C07C5/2789 , C07C5/2791 , C07C7/13 , C12C11/02 , C07C2521/04 , C07C2521/06 , C07C2523/42 , C07C2527/126 , C07C2529/22
摘要： A process is disclosed for the production of a high octane product from a feed mixture comprising C.sub.5 -C.sub.6 normal paraffins in which an equilibrium reaction to produce mono and dimethyl branched paraffins is achieved by conducting the reaction and the product separation in a pressure swing adsorption and reaction zone containing a uniformly distributed adsorbent for the selective adsorption of normal paraffins and a catalyst for the equilibrium conversion of normal paraffins to mono and dimethyl branched paraffins. More specifically, the process achieves the isomerization of the normal paraffins by the reaction of the normal paraffins in the presence of hydrogen with the simultaneous removal of the mono and dimethyl branched paraffin product at the same temperature and pressure. In one embodiment, the passing of the feed mixture to the bed is terminated and the bed is purged with one of the reactants which in turn further reacts to displace heavier paraffin and enhance the overall product octane. The advantage of the present invention over the conventional process is the higher octane of the product produced and that this higher octane can be achieved at lower severity since the product is removed from the reaction zone as soon as it is produced. The lower operating severity provides longer catalyst life, and reduces the amount of heavy paraffins lost to side reactions such as cracking.
摘要翻译：公开了一种从包含C5-C6正构链烷烃的进料混合物生产高辛烷值产物的方法，其中通过在变压吸附中进行反应和产物分离来实现产生单和二甲基支链烷烃的平衡反应，反应区含有均匀分布的吸附剂，用于选择性吸附正构烷烃和用于将正链烷烃平衡转化为单和二甲基支链烷烃的催化剂。更具体地，该方法通过正链烷烃在氢气存在下的反应，同时在相同的温度和压力下同时除去单支和二甲基支链的石蜡产物，来实现正链烷烃的异构化。在一个实施方案中，将进料混合物通入床中止，并且用一种反应物吹扫床，反应物又进一步反应以置换较重的石蜡并增强总产物辛烷值。本发明优于常规方法的优点是所生产的产物中较高的辛烷值，并且可以在较低的苛刻度下实现更高的辛烷值，因为一旦生产产物就从反应区域中除去。较低的操作苛刻度提供更长的催化剂寿命，并且减少了副反应（例如开裂）所损失的重链烷烃的量。

5. 发明授权

US5744683A Process for continuous reaction and deparation using reactive chromatography 失效
标题翻译：使用反应层析连续反应和分离的方法
公开(公告)号：US5744683A
公开(公告)日：1998-04-28
申请号：US666713
申请日：1996-06-18
申请人： Hemant W. Dandekar , Gregory A. Funk , Simon H. Hobbs , Masami Kojima , Ralph D. Gillespie , Herman A. Zinnen , Charles P. McGonegal
发明人： Hemant W. Dandekar , Gregory A. Funk , Simon H. Hobbs , Masami Kojima , Ralph D. Gillespie , Herman A. Zinnen , Charles P. McGonegal
IPC分类号： C07C5/27 , C07C9/16 , C07C5/13 , C07C7/12
CPC分类号： C07C9/16 , C07C5/2791 , C07C2521/04 , C07C2523/42 , C07C2527/126 , C07C2529/44 , Y02P20/582
摘要： A process for the continuous isomerization of an alkane to produce an isomerized product through contacting the alkane with a simulated moving bed acting as a catalyst for isomerization and an adsorbent for the alkanes has been developed. The alkane may be n-butane and the isomerized product 2-methylpropane, the alkane may be n-pentane and the isomerized product 2-methylbutane or 2,2-dimethylpropane, the alkane may have from 6 up to about 8 carbon atoms with no more than one methyl branch and the isomerized product having the same number of carbon atoms and at least two methyl branches, or the reactant may be a mixture of the foregoing alkanes with the corresponding isomerized products being formed. In a zone of the simulated moving bed, the alkanes are catalytically isomerized to form the isomerized products. The unreacted alkanes are adsorbed, and the isomerized products are collected. In a first subsequent zone of the simulated moving bed, a large portion of the unreacted alkanes are desorbed using a desorbent. In a second subsequent zone of the simulated moving bed, residual adsorbed alkanes are desorbed using a mixture of desorbent and isomerized products, and the desorbed residual alkanes may be removed from the simulated moving bed or may be reacted to form additional isomerized products. The isomerized products are removed from the simulated moving bed and collected. The process may also be used to effect other chemical reactions with the concurrent separation of product.
摘要翻译：已经开发了通过使烷烃与用作异构化的催化剂的模拟移动床和用于烷烃的吸附剂使烷烃连续异构化以产生异构化产物的方法。烷烃可以是正丁烷，异构化产物2-甲基丙烷，烷烃可以是正戊烷，异构化产物2-甲基丁烷或2,2-二甲基丙烷，烷烃可以具有6个至约8个碳原子，没有多于一个甲基支链和具有相同数目的碳原子和至少两个甲基支链的异构化产物，或者反应物可以是前述烷烃与形成相应的异构化产物的混合物。在模拟移动床的区域中，烷烃被催化异构化以形成异构化产物。未反应的烷烃被吸附，收集异构化产物。在模拟移动床的第一后续区域中，大部分未反应的烷烃使用解吸剂解吸附。在模拟移动床的第二个随后的区域中，残余吸附的烷烃使用解吸剂和异构化产物的混合物解吸，并且解吸的残余烷烃可以从模拟的移动床中除去，或者可以反应形成另外的异构化产物。将异构化产物从模拟移动床上取出并收集。该方法也可用于通过产品的同时分离来实现其它化学反应。

6. 发明授权

US5675048A Dual regeneration zone solid catalyst alkylation process 失效
标题翻译：双再生区固体催化剂烷基化工艺
公开(公告)号：US5675048A
公开(公告)日：1997-10-07
申请号：US597047
申请日：1996-02-05
申请人： Scott Yu-Feng Zhang , Christopher David Gosling , Paul Alvin Sechrist , Gregory A. Funk
发明人： Scott Yu-Feng Zhang , Christopher David Gosling , Paul Alvin Sechrist , Gregory A. Funk
IPC分类号： B01J8/28 , B01J38/10 , B01J38/58 , C07C2/58 , C07C2/66 , C07C2/86 , C10G50/00 , C07C2/68
CPC分类号： B01J8/28 , B01J38/10 , B01J38/58 , C07C2/58 , C07C2/66 , C07C2/864 , C10G50/00 , Y02P20/584
摘要： Hydrocarbons are alkylated in a fluidized riser-reactor using a solid catalyst which is regenerated within the process by contact with hydrogen. The alkylation and regeneration steps are separated to prevent the admixture of hydrogen and any olefins present in the process. Two separate modes of regeneration are performed simultaneously on different portions of the catalyst: a partial liquid-phase hydrogenative regeneration at reaction conditions and a high temperature (complete) liquid-phase hydrogenative regeneration.
摘要翻译：碳氢化合物在使用固体催化剂的流化提升管 - 反应器中烷基化，所述固体催化剂在该方法中通过与氢接触而再生。分离烷基化和再生步骤以防止氢气与该方法中存在的任何烯烃的混合物。在催化剂的不同部分上同时进行两种分离的再生模式：在反应条件和高温（完全）液相氢化再生下的部分液相氢化再生。

7. 发明授权

US5504258A Two-stage process for producing diisopropyl ether using catalytic distillation 失效
标题翻译：使用催化蒸馏生产二异丙醚的两阶段方法
公开(公告)号：US5504258A
公开(公告)日：1996-04-02
申请号：US311993
申请日：1994-09-26
申请人： Terry L. Marker , Gregory A. Funk , Paul T. Barger , Harold U. Hammershaimb
发明人： Terry L. Marker , Gregory A. Funk , Paul T. Barger , Harold U. Hammershaimb
IPC分类号： C07C41/05 , C07C41/42 , C07C41/00
CPC分类号： C07C41/06 , C07C29/04 , C07C41/42 , Y02P20/127
摘要： A process for the efficient production of diisopropyl ether where catalytic distillation is used to increase the yield of product beyond thermodynamic equilibrium limitations has been developed. In a hydration zone the propylene in a feedstock is reacted with water in the presence of a catalyst to effect hydration to produce an effluent stream containing at least water, unreacted propylene, and isopropyl alcohol, and then, in an etherification zone, at least a portion of the effluent stream is further reacted by catalytic distillation in the presence of a catalyst to effect reaction of propylene and isopropyl alcohol to form diisopropyl ether while concurrently separating a propylene rich portion, a diisopropyl ether rich portion and an aqueous portion, and recovering the diisopropyl ether from the diisopropyl ether rich portion.
摘要翻译：已经开发了一种有效生产二异丙醚的方法，其中使用催化蒸馏来提高产物的产率超过热力学平衡限制。在水合区中，原料中的丙烯在催化剂存在下与水反应以进行水合以产生至少含有水，未反应的丙烯和异丙醇的流出物流，然后在醚化区中至少在催化剂存在下，通过催化蒸馏进一步反应出一部分流出物流，进行丙烯与异丙醇的反应，生成二异丙醚，同时分离富丙烯部分，富含二异丙醚的部分和水分，并回收二异丙基醚。

8. 发明授权

US5489732A Fluidized solid bed motor fuel alkylation process 失效
标题翻译：流化床固体床机油燃料烷基化工艺
公开(公告)号：US5489732A
公开(公告)日：1996-02-06
申请号：US323437
申请日：1994-10-14
申请人： Scott Y. Zhang , Christopher D. Gosling , Paul A. Sechrist , Gregory A. Funk
发明人： Scott Y. Zhang , Christopher D. Gosling , Paul A. Sechrist , Gregory A. Funk
IPC分类号： B01J8/28 , B01J38/10 , B01J38/58 , C07C2/58 , C07C2/66 , C07C2/86 , C10G50/00
CPC分类号： C10G50/00 , B01J38/10 , B01J38/58 , B01J8/28 , C07C2/58 , C07C2/66 , C07C2/864 , Y02P20/584
摘要： Hydrocarbons are alkylated in a fluidized riser-reactor using a solid catalyst which is regenerated within the process by contact with hydrogen. The alkylation and regeneration steps are separated to prevent the admixture of hydrogen and any olefins present in the process. Two separate modes of regeneration are performed simultaneously: a mild liquid-phase washing and a vapor-phase hot hydrogen stripping operation.
摘要翻译：碳氢化合物在使用固体催化剂的流化提升管 - 反应器中烷基化，所述固体催化剂在该方法中通过与氢接触而再生。分离烷基化和再生步骤以防止氢气与该方法中存在的任何烯烃的混合物。同时进行两种分离的再生模式：温和的液相洗涤和气相热氢提取操作。

9. 发明授权

US5220102A Process for separating normal olefins from non-normal olefins 失效
标题翻译：从正常烯烃分离正常烯烃的方法
公开(公告)号：US5220102A
公开(公告)日：1993-06-15
申请号：US895769
申请日：1992-06-09
申请人： Gregory A. Funk , James R. Lansbarkis , Anil R. Oroskar , Beth McCulloch
发明人： Gregory A. Funk , James R. Lansbarkis , Anil R. Oroskar , Beth McCulloch
IPC分类号： C07C7/13
CPC分类号： C07C7/13
摘要： A chromatographic process for separating linear olefins from mixtures with branched-chain olefins with a high silica zeolitic molecular sieve, e.g., silicalites, ZSM-5, etc., having low acid catalytic reactivity, which selectively adsorbs the normal olefins, and uses ketones as desorbents.
摘要翻译：使用具有低酸催化反应性的高硅沸石分子筛（例如硅沸石，ZSM-5等）从支链烯烃与混合物中分离线性烯烃的色谱法，其选择性吸附普通烯烃，并使用酮作为脱矿

10. 发明授权

US6036845A Modified riser-reactor reforming process with prereactor 失效
标题翻译：改进的提升管反应器重整过程与预反应器
公开(公告)号：US6036845A
公开(公告)日：2000-03-14
申请号：US72444
申请日：1998-05-04
申请人： Gregory A. Funk , Christopher D. Gosling , Paula L. Bogdan
发明人： Gregory A. Funk , Christopher D. Gosling , Paula L. Bogdan
IPC分类号： B01J23/14 , B01J23/40 , B01J23/96 , C10G35/10 , C10G35/14 , C10G35/04 , B01J23/90 , C10G35/06
CPC分类号： B01J23/40 , B01J23/14 , B01J23/96 , C10G35/10 , C10G35/14
摘要： A catalytic reforming process comprises a prereactor which provides an intermediate stream to a riser reactor with multiple catalyst injection points to obtain high aromatics yields from a naphtha feedstock. Product from the riser reactor typically is discharged into a fluidized-bed reforming reactor, in which the reforming reaction is completed and catalyst is separated from hydrogen and hydrocarbons. Hydrocarbons from the reactor are separated to recover an aromatized product. Catalyst is regenerated to remove coke and reduced for reuse in the reforming process.
摘要翻译：催化重整方法包括一个预反应器，该预反应器提供具有多个催化剂注入点的提升管反应器的中间物流，以获得来自石脑油原料的高芳族化合物产率。来自提升管反应器的产物通常被排放到流化床重整反应器中，其中重整反应完成并且催化剂与氢气和烃分离。将来自反应器的烃分离以回收芳构化产物。再生催化剂以除去焦炭并在重整过程中减少再利用。

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