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1. 发明专利

BR0000978A 未知
公开(公告)号：BR0000978A
公开(公告)日：2000-10-10
申请号：BR0000978
申请日：2000-02-29
申请人： AIR PROD & CHEM , WILLIAM EAMON CARROLL , FRANCIS JOSEPH WALLER
发明人： RAMPRASAD DORAI
IPC分类号： B01J23/42 , B01J23/44 , C07B61/00 , C07C227/02 , C07C229/06 , C07C229/08 , C07C229/12 , C07C211/63 , A61K7/48

2. 发明授权

US06610628B2 Polymer network/carbon layer on monolith support and monolith catalytic reactor 失效
标题翻译：聚合物网/碳层在整体支撑和整体催化反应器上
公开(公告)号：US06610628B2
公开(公告)日：2003-08-26
申请号：US09867959
申请日：2001-05-30
申请人： Andrew Francis Nordquist , Frederick Carl Wilhelm , Francis Joseph Waller , Reinaldo Mario Machado
发明人： Andrew Francis Nordquist , Frederick Carl Wilhelm , Francis Joseph Waller , Reinaldo Mario Machado
IPC分类号： B01J3106
CPC分类号： C07C209/36 , B01J21/18 , B01J23/44 , B01J35/04 , B01J35/10 , B01J35/1009 , B01J35/1014 , B01J37/0219 , B01J37/084 , C07C211/46
摘要： The present invention relates to an improved monolith catalytic reactor and a monolith support. The improvement in the support resides in a polymer network/carbon coating applied to the surface of a porous substrate and a catalytic metal, preferably a transition metal catalyst applied to the surface of the polymer network/carbon coating. The monolith support has from 100 to 800 cells per square inch and a polymer network/carbon coating with surface area of from 0.1 to 15 m2/gram as measured by adsorption of N2 or Kr using the BET method.
摘要翻译：本发明涉及一种改进的整体催化反应器和整料载体。载体的改进在于施加到多孔基材表面的聚合物网络/碳涂层和催化金属，优选应用于聚合物网络/碳涂层表面的过渡金属催化剂。整体式载体具有100至800个/平方英寸的单体和通过使用BET法吸附N 2或Kr测量的表面积为0.1至15m 2 / g的聚合物网络/碳涂层。

3. 发明授权

US06329549B1 Dimethyl ether for methyl group attachment on a carbon adjacent to an electron withdrawing group 有权
标题翻译：甲基的二甲醚连接在与吸电子基团相邻的碳上
公开(公告)号：US06329549B1
公开(公告)日：2001-12-11
申请号：US09544672
申请日：2000-04-06
申请人： Francis Joseph Waller , Gene Everad Parris
发明人： Francis Joseph Waller , Gene Everad Parris
IPC分类号： C07C5142
CPC分类号： C07C67/343 , C07B37/04 , C07C69/54
摘要： A process for methylating an alpha carbon adjacent to an electron withdrawing group includes reacting dimethyl ether with a molecule containing the alpha carbon and the electron withdrawing group to substitute a methyl group on the alpha carbon. The process can be conducted in a vapor phase and can be represented by Equation I: R(CH2)nCH2-EWG+CH3OCH3→R(CH2)nCH(CH3)-EWG+CH3OH (I) where EWG is the electron withdrawing group, and R is H when n is 0, 1 or 2, and R is alkyl, EWG or aryl when n>2. For example, the molecule reacted with dimethyl ether can be acetic acid, propionic acid, methyl acetate, methyl propionate, acetonitrile, propionitrile and acetone. The process is catalyzed by an acid catalyst containing a Lewis acid functionality. When the electron withdrawing group is an acid, a methyl ester can be formed by esterifying the electron withdrawing group with methanol liberated from dimethyl ether. When the process is conducted in the presence of an oxidant, such as oxygen, an &agr;,&bgr;-unsaturated bond can be formed in the molecule according to Equation II: R(CH2)nCH(CH3)-EWG+½O2→R(CH2)nC(═CH2)-EWG+H2O (II) where EWG is the electron withdrawing group, and R is H when n is 0, 1 or 2, and R is alkyl, EWG or aryl when n>2.
摘要翻译：用于甲基化与吸电子基团相邻的α碳的方法包括使二甲醚与含有α碳和吸电子基团的分子反应以取代α碳上的甲基。该方法可以在气相中进行，并且可以由式I表示：其中EWG是吸电子基团，当n是0,1或2时R是H，当n> 2时R是烷基，EWG或芳基。例如，与二甲醚反应的分子可以是乙酸，丙酸，乙酸甲酯，丙酸甲酯，乙腈，丙腈和丙酮。该方法由含有路易斯酸官能团的酸催化剂催化。当吸电子基团是酸时，可以通过用从二甲醚中释出的甲醇酯化吸电子基团而形成甲酯。当该方法在诸如氧的氧化剂存在下进行时，可以根据式II在分子中形成α，β-不饱和键：其中EWG是吸电子基团，当n为0时，R为H ，1或2，当n> 2时，R为烷基，EWG或芳基。

4. 发明授权

US07572879B2 Fluorinated alkyl substituted-thieno[3,4-b]thiophene monomers and polymers therefrom 有权
标题翻译：氟化烷基取代噻吩并[3,4-b]噻吩单体及其聚合物
公开(公告)号：US07572879B2
公开(公告)日：2009-08-11
申请号：US11418317
申请日：2006-05-05
申请人： Steffen Zahn , Gauri Sankar Lal , William Franklin Burgoyne, Jr. , Kristen Elaine Minnich , Andrew Francis Nordquist , Lloyd Mahlon Robeson , Francis Joseph Waller
发明人： Steffen Zahn , Gauri Sankar Lal , William Franklin Burgoyne, Jr. , Kristen Elaine Minnich , Andrew Francis Nordquist , Lloyd Mahlon Robeson , Francis Joseph Waller
IPC分类号： C08G73/24 , C08G75/00 , C08F4/80
CPC分类号： C07D495/04 , C08G61/126 , C08G2261/146 , C08G2261/3243 , C08L25/12 , C08L25/18 , C08L27/12 , C08L33/02 , C08L35/00 , C08L65/00 , H01B1/127 , H01G11/48 , H01L51/0036 , Y02E60/13 , C08L2666/06 , C08L2666/04
摘要： Partially and fully fluorinated alkyl substituted thienothiophene monomers (and polymers thereof) wherein the monomers are represented by the formula: wherein R is a partially or fully fluorinated primary, secondary or tertiary alkyl having from 1 to 8 carbon atoms; and X and X′ are independently selected from the group consisting of H, F, Cl, Br, I, MgCl, —COR″, —C≡CH, and a polymerizable cyclic pi-conjugated carbon-ring structure optionally comprising S, N or O heteroatoms; wherein R′ is a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms, and R″ is H or a primary, or tertiary alkyl having from 1 to 6 carbon atoms.
摘要翻译：部分和完全氟化的烷基取代的噻吩并噻吩单体（及其聚合物），其中单体由下式表示：其中R是具有1至8个碳原子的部分或完全氟化的伯，仲或叔烷基; 并且X和X'独立地选自H，F，Cl，Br，I，MgCl，-COR“，-C≡CH，以及任选地包含S的可聚合环状π-共轭碳环结构， N或O杂原子; 其中R'是具有1至6个碳原子的伯，仲或叔烷基，R“是H或具有1至6个碳原子的伯或叔烷基。

5. 发明授权

US07569158B2 Aqueous dispersions of polythienothiophenes with fluorinated ion exchange polymers as dopants 有权
标题翻译：具有氟化离子交换聚合物作为掺杂剂的聚噻吩并噻吩的水分散体
公开(公告)号：US07569158B2
公开(公告)日：2009-08-04
申请号：US11240573
申请日：2005-10-03
申请人： Francis Joseph Waller , John Bartram Dickenson , Xuezhong Jiang , Roy Daniel Bastian
发明人： Francis Joseph Waller , John Bartram Dickenson , Xuezhong Jiang , Roy Daniel Bastian
IPC分类号： H01B1/12
CPC分类号： H01L51/0037 , B82Y30/00 , C08G61/126 , C08J2367/00 , C08L27/12 , C08L65/00 , C08L2201/50 , H01L51/0021 , H01L51/0541 , H01L51/4253 , H01L51/5088 , Y02E10/549 , C08L2666/02 , C08L2666/04
摘要： Compositions are provided comprising aqueous dispersions of polythienothiophenes and colloid-forming polymeric acids. Films from invention compositions are useful as hole injection layers in organic electronic devices, including electroluminescent devices, such as, for example, organic light emitting diodes (OLED) displays, as hole extraction layers in organic optoelectronic devices, such as organic photovoltaic devices, and in combination with metal nanowires or carbon nanotubes in applications such as drain, source, or gate electrodes in thin film field effect transistor.
摘要翻译：提供了包含聚噻吩并噻吩和胶体形成聚合酸的水分散体的组合物。来自发明组合物的薄膜可用作有机电子器件中的空穴注入层，包括诸如有机发光二极管（OLED）显示器之类的电致发光器件，作为有机光电器件如有机光伏器件中的空穴提取层，以及与诸如薄膜场效应晶体管中的漏极，源极或栅电极的金属纳米线或碳纳米管结合使用。

6. 发明授权

US07332223B2 Polymers comprising thieno [3,4-b]thiophene and methods of making and using the same 有权
标题翻译：包含噻吩并[3,4-b]噻吩的聚合物及其制备和使用方法
公开(公告)号：US07332223B2
公开(公告)日：2008-02-19
申请号：US11394906
申请日：2006-03-31
申请人： Gregory A. Sotzing , Francis Joseph Waller , Lloyd Mahlon Robeson
发明人： Gregory A. Sotzing , Francis Joseph Waller , Lloyd Mahlon Robeson
IPC分类号： B32B27/06 , C08G75/00
CPC分类号： C08G61/123 , C08G61/126 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T428/31533
摘要： This invention presents polymers and copolymers comprising repeating units of thieno[3,4-b]thiophene. Water-borne dispersions of such polymers and copolymers can be cast by conventional methods to provide uniform, thin films which possess utility in numerous electroactive applications including electrochromic displays, optically transparent electrodes and antistatic coatings. The compositions of this invention can be doped with conventional p-dopants or n-dopants. The invention also presents an aqueous process for preparing such compositions of matter.
摘要翻译：本发明提供了包含噻吩并[3,4-b]噻吩重复单元的聚合物和共聚物。这种聚合物和共聚物的水分散体可以通过常规方法浇铸以提供均匀的薄膜，其在许多电活性应用中具有实用性，包括电致变色显示器，光学透明电极和抗静电涂层。本发明的组合物可掺杂常规的p-掺杂剂或n-掺杂剂。本发明还提供了用于制备这种物质组合物的水性方法。

7. 发明授权

US07118692B2 Substituted thienothiophene monomers and conducting polymers 失效
标题翻译：取代的噻吩并噻吩单体和导电聚合物
公开(公告)号：US07118692B2
公开(公告)日：2006-10-10
申请号：US10958068
申请日：2004-10-04
申请人： Andrew Francis Nordquist , William Franklin Burgoyne, Jr. , Steffen Zahn , Francis Joseph Waller
发明人： Andrew Francis Nordquist , William Franklin Burgoyne, Jr. , Steffen Zahn , Francis Joseph Waller
IPC分类号： H01B1/12
CPC分类号： H01B1/127 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： Thienothiophenes compositions comprising a C3-8 secondary or tertiary alkyl group are disclosed. The thienothiophenes may be represented by the formula: where R is C3-8 secondary or tertiary alkyl, e.g., isopropyl, tert-butyl, tert-pentyl, isopentyl, and 2-ethylhexyl, X and X′ are independently selected from the group consisting of H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, Mgl, Sn(R′)3, (where R′ is C1-6 alkyl or —OC1-6 alkyl), boronic acid, boronic ester, —CH═CHR″ (where R″ is H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″, —COR′″ (where R′″ is H or C1-6 alkyl), —C≡CH, and polymerizable aromatic rings such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth.
摘要翻译：公开了包含C 3-8仲仲或叔烷基的噻吩并噻吩类组合物。噻吩并噻吩可以由下式表示：其中R是C 3-8仲仲或叔烷基，例如异丙基，叔丁基，叔戊基，异戊基和2-乙基己基，X和X 独立地选自H，卤素原子（例如F，Cl，Br和I），MgCl，MgBr，Mg1，Sn（R'）3（其中R' 是C 1-6烷基或-OC 1-6烷基），硼酸，硼酸酯，-CH-CHR“（其中R”是H或C C 1-6烷基），-OC 1-6烷基，-COOC 1-6烷基，-S-COR“ - ， - COR''（其中R“'是H或C 1-6烷基），-C≡CH，以及可聚合的芳环如苯基，萘，吡咯，二噻吩，噻吩并噻吩，噻吩和等等。

8. 发明授权

US5895823A Process for the preparation of aqueous solutions of betaine 失效
标题翻译：制备甜菜碱水溶液的方法
公开(公告)号：US5895823A
公开(公告)日：1999-04-20
申请号：US16549
申请日：1998-01-30
申请人： Dorai Ramprasad , William Eamon Carroll , Francis Joseph Waller
发明人： Dorai Ramprasad , William Eamon Carroll , Francis Joseph Waller
IPC分类号： B01J23/42 , B01J23/44 , C07B61/00 , C07C227/02 , C07C229/12 , C07C229/00
CPC分类号： C07C227/02
摘要： Betaine is produced by the oxidation of a choline salt in the presence of a supported noble metal catalyst at temperatures from about 20.degree. C. to 100.degree. C. and pressures from atmospheric to about 100 psi. This process is advantageous over prior processes for the production of betaine in that no amine halocarboxylate contaminants are produced by this reaction.
摘要翻译：甜菜碱通过在负载的贵金属催化剂存在下在约20℃至100℃的温度和从大气压至约100psi的压力下氧化胆碱盐产生。该方法优于用于生产甜菜碱的现有方法，因为该反应不产生胺卤代羧酸盐污染物。

9. 发明授权

US5892110A Heterogeneous catalyst for the production of acetic anhydride from methyl acetate 失效
标题翻译：用于从乙酸甲酯生产乙酸酐的非均相催化剂
公开(公告)号：US5892110A
公开(公告)日：1999-04-06
申请号：US651138
申请日：1996-05-21
申请人： Dorai Ramprasad , Francis Joseph Waller
发明人： Dorai Ramprasad , Francis Joseph Waller
IPC分类号： B01J31/02 , B01J31/16 , B01J31/20 , C07C51/56
CPC分类号： B01J31/20 , B01J31/165 , C07C51/56 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , B01J31/0268 , Y02P20/584
摘要： This invention relates to a process for producing acetic anhydride by the reaction of methyl acetate, carbon monoxide, and hydrogen at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that contains an insoluble polymer having pendant quaternized phosphine groups, some of which phosphine groups are ionically bonded to anionic Group VIII metal complexes, the remainder of the phosphine groups being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for consecutive runs without loss in activity. Bifunctional catalysts for use in carbonylating dimethyl ether are also provided.
摘要翻译：本发明涉及一种通过在高温和高压下，在烷基卤和异种双官能催化剂存在下，通过乙酸甲酯，一氧化碳和氢气的反应制备乙酸酐的方法，所述催化剂含有具有季铵化膦基团的不溶性聚合物，其中一些膦基离子键合到阴离子VIII族金属络合物，其余的膦基键合到碘化物上。与现有技术方法相比，无需促进剂（助催化剂）来实现催化反应，并且通过过滤容易地将产物与催化剂分离。催化剂可以循环使用，连续运行而不会损失活性。还提供了用于羰基化二甲醚的双功能催化剂。

10. 发明授权

US5744636A Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst 失效
标题翻译：使用多相催化剂从二甲醚生产亚乙基二乙酸酯的方法
公开(公告)号：US5744636A
公开(公告)日：1998-04-28
申请号：US651130
申请日：1996-05-21
申请人： Dorai Ramprasad , Francis Joseph Waller
发明人： Dorai Ramprasad , Francis Joseph Waller
IPC分类号： C07C67/293 , C07C67/00
CPC分类号： C07C67/37 , C07C67/36 , Y02P20/582 , Y02P20/584
摘要： This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.
摘要翻译：本发明涉及通过二甲醚，乙酸，氢气和一氧化碳在升高的温度和压力下在烷基卤和对氢化稳定的非均相双功能催化剂存在下反应生产亚乙基双乙酸酯的方法，具有侧链季铵化杂原子的不溶性聚合物，其中一些杂原子与阴离子VIII族金属络合物离子键合，其余杂原子键合到碘化物上。与现有技术方法相比，无需促进剂（助催化剂）来实现催化反应，并且通过过滤容易地将产物与催化剂分离。催化剂可循环连续运行3次而不损失活性。

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