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1. 发明授权

US06696610B2 Continuous preparation of monoethanolamine, diethanolamine and triethanolamine 失效
标题翻译：连续制备单乙醇胺，二乙醇胺和三乙醇胺
公开(公告)号：US06696610B2
公开(公告)日：2004-02-24
申请号：US10227831
申请日：2002-08-27
申请人： Werner Peschel , Axel Hildebrandt , Bernd Bessling
发明人： Werner Peschel , Axel Hildebrandt , Bernd Bessling
IPC分类号： C07C21304
CPC分类号： C07C213/04 , Y02P20/127 , C07C215/08 , C07C215/12
摘要： A continuous process for the preparation of monoethanolamine, diethanolamine and triethanolamine by reacting ammonia and ethylene oxide in liquid phase in the presence of water as catalyst in a pressure column is proposed, where, as a result of the heat of the reaction, some of the ammonia evaporates, condenses at the head of the column and is again charged to the column, the reaction mixture at the bottom end of the pressure column is drawn off and then separated, the pressure column is constructed as a reactive distillation column (I) with evaporator at the bottom (S) and where, by means of inputting energy via the evaporator at the bottom (S), the weight ratio of monoethanolamine to diethanolamine to triethanolamine is controlled and, via the ratio of ammonia to ethylene oxide in the feed to the reactive distillation column (I), the ammonia proportion in the bottom product from the reactive distillation column (I) is controlled.
摘要翻译：提出了一种连续的制备单乙醇胺，二乙醇胺和三乙醇胺的方法，其中在水作为催化剂存在下，在压力塔中使氨和环氧乙烷在液相中反应，其中作为反应热的结果，氨蒸发，在塔头冷凝，再次加入塔中，抽出压力塔底端的反应混合物，然后分离，将压力塔构建为反应蒸馏塔（I），与蒸发器在底部（S），并且其中通过在底部（S）处的蒸发器输入能量，控制单乙醇胺与二乙醇胺与三乙醇胺的重量比，并且通过进料中氨与环氧乙烷的比例反应蒸馏塔（I），来自反应蒸馏塔（I）的塔底产物中的氨比例被控制。

2. 发明授权

US06605192B1 Method for producing highly pure monoethylene glycol 有权
标题翻译：高纯度单乙二醇生产方法
公开(公告)号：US06605192B1
公开(公告)日：2003-08-12
申请号：US09787616
申请日：2001-03-20
申请人： Gerhard Theis , Till Adrian , Bernd Bessling , Hans Hasse , Frans Vansant
发明人： Gerhard Theis , Till Adrian , Bernd Bessling , Hans Hasse , Frans Vansant
IPC分类号： B01D338
CPC分类号： C07C29/80 , Y10S203/20 , C07C31/202
摘要： A process for the distillative recovery of high purity monoethylene glycol from the hydrolysis, product of ethylene oxide by pressure dewatering, preferably in a battery, vacuum dewatering and subsequent purifying distillation, wherein during the vacuum dewatering an aqueous stream is withdrawn which contains-monoethylene glycol in a concentration below 1% by weight, preferably below 0.1% by weight, medium boilers and low boilers. The withdrawn aqueous stream is, optionally after further workup, removed from the system.
摘要翻译：一种从水解中回收高纯度单乙二醇的方法，通过压力脱水，优选在电池中进行蒸馏产物，真空脱水和随后的纯化蒸馏，其中在真空脱水期间，取出含有单乙二醇的水流浓度低于1重量％，优选低于0.1重量％，中等锅炉和低锅炉。取出的水流，任选地在进一步后处理之后，从体系中除去。

3. 发明授权

US06362386B1 Method and device for obtaining isobutenes from conjugated hydrocarbons 有权
标题翻译：从共轭烃获得异丁烯的方法和装置
公开(公告)号：US06362386B1
公开(公告)日：2002-03-26
申请号：US09446532
申请日：1999-12-28
申请人： Bernd Bessling , Jean Werner Knab , Wolfgang Brox , Bernd Lohe
发明人： Bernd Bessling , Jean Werner Knab , Wolfgang Brox , Bernd Lohe
IPC分类号： C07C700
CPC分类号： C07C7/14891 , Y02P20/127 , C07C11/09
摘要： A process for isolating isobutene from a hydrocarbon mixture by a) combining the C4-hydrocarbon mixture with a primary C3- or C4-alkanol; b) reacting the isobutene in the C4-hydrocarbon mixture with the primary C3- or C4-alkanol in the presence of a heterogeneous catalyst to give the corresponding tertiary ether of isobutene, c) separating the resultant reaction mixture into the relatively low-boiling, unetherified C4-hydrocarbons and the relatively higher-boiling tertiary ether of isobutene with the aid of a distillation column, where the C4-hydrocarbons are taken off at the top, and the tertiary ether of isobutene obtained at the bottom is transferred into a reactor, d) cleaving this ether into isobutene and the corresponding primary C3- or C4-alkanol, e) distilling this mixture from d) in a further distillation column, and taking off the isobutene as the top product, which comprises carrying out step a) in a zone (4C) containing reactive internals and containing the catalyst for carrying out step b) arranged in such a way that the zone (4C) is integrated into a distillation column (4), that a reactive distillation takes place in this zone (4C), and that the C3- or C4-alkanol is fed to the distillation column above the zone (4C) and the C4-hydrocarbon mixture is fed to the distillation column below the zone (4C).
摘要翻译：一种从烃混合物中分离异丁烯的方法，其方法是将C4-烃混合物与一种C 3 - 或C 4 - 链烷醇组合; b）使C 4 - 烃混合物中的异丁烯与C 3- 的非均相催化剂，得到相应的异丁烯叔乙醚，c）借助于蒸馏塔将所得反应混合物分离成相对低沸点的未乙醚化的C4烃和相对较高沸点的异丁烯叔醚，其中在顶部取出C4烃，将底部获得的异丁烯的叔醚转移到反应器中，d）将该醚切割成异丁烯和相应的初级C3-或C4-链烷醇，e）蒸馏该混合物从另一个蒸馏塔中除去异丁烯作为顶部产物，其包括在含有反应性内件的区域（4C）中进行步骤a）并含有用于承载的催化剂排出步骤b）以使得区域（4C）整合到蒸馏塔（4）中的方式排列，在该区域（4C）中进行反应蒸馏，并且将C3-或C4-链烷醇进料至将区域（4C）上方的蒸馏塔和C4-烃混合物进料到区域（4C）下方的蒸馏塔。

4. 发明授权

US6028215A Process for preparing esters of carboxylic acids 失效
标题翻译：制备羧酸酯的方法
公开(公告)号：US6028215A
公开(公告)日：2000-02-22
申请号：US109767
申请日：1998-07-06
申请人： Bernd Bessling , Bernd Lohe , Rudiger Welker , Walter Disteldorf , Jean Werner Knab
发明人： Bernd Bessling , Bernd Lohe , Rudiger Welker , Walter Disteldorf , Jean Werner Knab
IPC分类号： B01J31/08 , B01D3/00 , B01D3/14 , B01J8/04 , B01J19/24 , B01J19/32 , C07B61/00 , C07C67/08 , C07C67/54 , C07C69/14 , C07C69/16
CPC分类号： C07C67/08 , B01D3/009 , B01D3/14 , B01J19/32 , B01J8/0453 , C07C67/54 , B01J2208/00814 , Y02P20/127
摘要： A process for preparing esters from alcohol and carboxylic acid by a) feeding a mixture, comprising at least alcohol and/or carboxylic acid as educts, into a distillation column with separated sections containing reactive and conventional internals, wherein the reactive internals are arranged below the inlet of the mixture and conventional internals are arranged above the inlet of the mixture, b) reaction of the alcohol and the carboxylic acid in the reactive internals in presence of a catalyst, c) distillative separation of the evolving reaction mixture into the higher boiling ester and a lower boiling azeotrope containing alcohol, water and ester, wherein the ester accumulates in the bottom and the azeotrope is removed overhead, d) separation of the azeotrope in a phase separator in an aqueous phase and in an organic phase and the organic phase to be returned to the top of the column, wherein in step b) a heterogenous catalyst is utilized and in step c) the ester is taken off above the bottom as pure product between further conventional internals which differ in their arrangement from those in step a) and which are arranged above the inlet of a circulating evaporator.
摘要翻译：一种由醇和羧酸制备酯的方法，其方法是：a）将含有至少醇和/或羧酸的混合物作为离子液体进料到具有包含反应性和常规内部物质的分离部分的蒸馏塔中，其中反应性内部件布置在混合物入口和常规内件布置在混合物入口的上方，b）在催化剂存在下，醇和羧酸在反应性内件中的反应，c）将放出的反应混合物蒸馏分离成高沸点酯和含有醇，水和酯的低沸点共沸物，其中酯积聚在底部，共沸物在塔顶除去，d）将相分离器中的共沸物在水相和有机相中分离，并将有机相分离成返回到塔的顶部，其中在步骤b）中使用异种催化剂，并且在步骤c）中，将酯从t上方取出他作为在其布置方式与步骤a）中不同的另外的常规内件之间的纯产品底部，并且布置在循环蒸发器的入口上方。

5. 发明授权

US07241365B2 Material for a facility for the production of anhydrous formic acid 有权
标题翻译：用于生产无水甲酸的设备的材料
公开(公告)号：US07241365B2
公开(公告)日：2007-07-10
申请号：US10181814
申请日：2001-01-24
申请人： Heinz Auer , Bernd Bessling , Hans Hammer , Hans Hasse , Friedrich Sauer , Maximilian Vicari , Gerhard Wagner , Till Adrian
发明人： Heinz Auer , Bernd Bessling , Hans Hammer , Hans Hasse , Friedrich Sauer , Maximilian Vicari , Gerhard Wagner , Till Adrian
IPC分类号： B01D3/34 , C07C53/06 , C22C19/05 , C22C30/00
CPC分类号： C22C38/44 , C07C51/09 , C07C51/44 , C07C51/48 , C22C14/00 , C22C38/001 , C22C38/42 , C07C53/02
摘要： The invention relates to an apparatus and a process for the preparation of anhydrous or substantially anhydrous formic acid. This apparatus is constructed partly or entirely of substantially zirconium-free materials. The extractant employed is a liquid of the general formula I where the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1–C4-alkyl group. The apparatus has a synthesis reactor (6), a hydrolysis reactor (1), three distillation devices (2,4,5) and an extraction device (3).
摘要翻译：本发明涉及一种制备无水或基本无水甲酸的装置和方法。该装置部分或完全由基本上不含锆的材料构成。所用的萃取剂是通式I的液体，其中基团R 1和R 2是烷基，环烷基，芳基或芳烷基，或R 1， / O 2和R 2共同与N原子一起形成杂环的5或6元环，并且只有一个基团是芳基，并且其中R 3 氢或C 1 -C 4 - 烷基。该装置具有合成反应器（6），水解反应器（1），三个蒸馏装置（2,4,5）和提取装置（3）。

6. 发明授权

US06867329B2 Waste water treatment in a method for producing formic acid which is free of water 有权
标题翻译：用于生产不含水的甲酸的方法中的废水处理
公开(公告)号：US06867329B2
公开(公告)日：2005-03-15
申请号：US10181455
申请日：2001-01-12
申请人： Heinz Auer , Bernd Bessling , Hans Hammer , Hans Hasse , Friedrich Sauer , Maximilian Vicari , Till Adrian
发明人： Heinz Auer , Bernd Bessling , Hans Hammer , Hans Hasse , Friedrich Sauer , Maximilian Vicari , Till Adrian
IPC分类号： B01J14/00 , C07C27/02 , C07C51/09 , C07C51/44 , C07C51/48 , C07C53/02
CPC分类号： C07C51/445 , B01J14/00 , B01J2219/00006 , C07C51/09 , C07C51/44 , C07C51/48 , C07C53/02
摘要： The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is prepared by hydrolysis of methyl formate and is freed from water in the subsequent work-up. The process has the special feature that steam, which is employed for the hydrolysis of methyl formate and for heating a distillation column serving for work-up, is also used as stripping steam for waste-water stripping. The stripped waste water is produced during work-up.
摘要翻译：本发明涉及获得无水或基本上无水的甲酸的方法，其中首先通过甲酸甲酯的水解制备甲酸水溶液，并在随后的后处理中从水中除去。该方法的特点是，用于水解甲酸甲酯和加热用于后处理的蒸馏塔的蒸汽也用作废水汽提的汽提蒸汽。被处理的废水在处理过程中产生。

7. 发明授权

US06833057B1 Pure ethylene oxide distillation process 有权
标题翻译：纯环氧乙烷蒸馏工艺
公开(公告)号：US06833057B1
公开(公告)日：2004-12-21
申请号：US09341921
申请日：1999-07-21
申请人： Bernd Bessling , Hans Hasse , Jürgen Plückhan , Thomas Mayer , Heinz Auer
发明人： Bernd Bessling , Hans Hasse , Jürgen Plückhan , Thomas Mayer , Heinz Auer
IPC分类号： B01D338
CPC分类号： C07D301/32 , Y10S203/20
摘要： In a process for purification of ethylene oxide by distillation an aqueous mixture comprising ethylene oxide, formaldehyde and at least 5% by weight of water is introduced via a feed into a distillation apparatus comprising at least one distillation column, the mixture being introduced at a height above the bottom of at least 8 theoretical stages, the ethylene oxide is taken off at the top and in the bottom phase a mixture is obtained which contains less than 5% by weight of ethylene oxide.
摘要翻译：在通过蒸馏纯化环氧乙烷的方法中，将包含环氧乙烷，甲醛和至少5重量％的水的含水混合物通过进料引入到包含至少一个蒸馏塔的蒸馏装置中，混合物在高度在至少8个理论阶段的底部之上，环氧乙烷在顶部被除去，在底部，获得含有小于5重量％的环氧乙烷的混合物。

8. 发明授权

US6123812A Process for distilling ethylene oxide 失效
标题翻译：蒸馏环氧乙烷的方法
公开(公告)号：US6123812A
公开(公告)日：2000-09-26
申请号：US68549
申请日：1998-05-18
申请人： Bernd Bessling , Sebastian Zeck , Jurgen Pluckhan , Thomas Mayer , Ulrich Loffler , Gunter Spiegel , Rubens Ballenweg , Gerhard Brudi , Klaus Gieselberg , Lutz Hilprecht , Winfried Terjung , Heinz Auer , Axel Werner Polt , Stephan Scholl
发明人： Bernd Bessling , Sebastian Zeck , Jurgen Pluckhan , Thomas Mayer , Ulrich Loffler , Gunter Spiegel , Rubens Ballenweg , Gerhard Brudi , Klaus Gieselberg , Lutz Hilprecht , Winfried Terjung , Heinz Auer , Axel Werner Polt , Stephan Scholl
IPC分类号： B01D3/00 , B01D3/16 , C07D301/32 , C07D303/02 , C07D303/04 , B01D3/34 , B01D3/42
CPC分类号： C07D301/32 , B01D3/16 , Y10S203/20
摘要： A process for distilling ethylene oxide out of a mixture including ethylene oxide in a column at an absolute pressure of from 2 to 10 bar and a temperature of 20 to 180.degree. C. by withdrawing pure ethylene oxide in the liquid or gaseous state overhead or via a sidestream in the rectifying section of the column includes effecting the distillation in a column having on its inside a plurality of successive zones of structured sheet-metal packing or dumped beds of packing elements, these zones being assigned one or more extinguishing systems on the outside of the column.
摘要翻译： PCT No.PCT / EP96 / 04818 Sec。 371日期1998年5月18日 102（e）日期1998年5月18日PCT提交1996年11月5日PCT公布。公开号WO97 / 19069 日期：1997年5月29日一种通过在液体或气体中抽出纯的环氧乙烷从绝对压力为2-10巴和温度为20至180℃的混合物中蒸馏出环氧乙烷的方法，状态塔顶馏出物或通过塔的整流段中的侧流，包括在其内部进行蒸馏，该塔在其内部具有多个连续的结构化金属片状填料区域或填料元件的倾倒层，这些区域被分配一个或多个灭火剂系统在外面的列。

9. 发明授权

US06841700B2 Method for producing anhydrous formic acid 有权
标题翻译：无水甲酸生产方法
公开(公告)号：US06841700B2
公开(公告)日：2005-01-11
申请号：US10181462
申请日：2001-01-12
申请人： Heinz Auer , Bernd Bessling , Hans Hammer , Hans Hasse , Friedrich Sauer , Maximilian Vicari , Till Adrian
发明人： Heinz Auer , Bernd Bessling , Hans Hammer , Hans Hasse , Friedrich Sauer , Maximilian Vicari , Till Adrian
IPC分类号： C07C51/09 , C07C51/44 , C07C51/48 , C07C53/02
CPC分类号： C07C51/44 , C07C51/09 , C07C51/48 , C07C53/02
摘要： The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is produced by hydrolysis of methyl formate, with the methanol content in the methyl formate having been reduced in advance. The process according to the invention has the special feature that—before the hydrolysis of the methyl formate—the methanol content of the methanol-containing methyl formate is reduced in a distillation column, this distillation column simultaneously being employed for other separation functions during work-up of the formic acid.
摘要翻译：本发明涉及获得无水或基本上无水的甲酸的方法，其中首先通过甲酸甲酯的水解产生水性甲酸，甲酸甲酯中的甲醇含量预先减少。根据本发明的方法具有以下特征：在甲酸甲酯的水解之前，甲醇的甲酸甲酯的甲醇含量在蒸馏塔中还原，该蒸馏塔同时用于工作期间的其它分离功能，的甲酸。

10. 发明授权

US06838579B2 Utilization of an extracting agent as antifoaming agent in the production of anhydrous formic acid 有权
标题翻译：提取剂作为消泡剂在无水甲酸生产中的应用
公开(公告)号：US06838579B2
公开(公告)日：2005-01-04
申请号：US10181460
申请日：2001-01-24
申请人： Heinz Auer , Bernd Bessling , Hans Hammer , Hans Hasse , Friedrich Sauer , Maximilian Vicari , Gerhard Wagner , Till Adrian
发明人： Heinz Auer , Bernd Bessling , Hans Hammer , Hans Hasse , Friedrich Sauer , Maximilian Vicari , Gerhard Wagner , Till Adrian
IPC分类号： C07C51/56 , C07C51/09 , C07C51/44 , C07C51/48 , C07C53/02
CPC分类号： C07C51/44 , C07C51/09 , C07C51/48 , C07C53/02
摘要： The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid in which, during the work-up, a compound of the general formula I where the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1-C4-alkyl group, is employed simultaneously as extractant for formic acid and as antifoam for a distillation process.
摘要翻译：本发明涉及获得无水或基本上无水的甲酸的方法，其中在后处理过程中，将基团R 1和R 2分别为烷基，环烷基，芳基或芳烷基或R 1和R 2共同形成的通式Ⅰ化合物与N原子一起形成杂环的5或6元环，并且只有一个基团是芳基，并且其中R 3是氢或C 1 -C 4 - 烷基，同时被用作甲酸的萃取剂酸和消泡剂用于蒸馏过程。

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