发明申请
WO2014097245A1 PROCESS FOR THE PREPARATION OF (CO) POLYMERS OF CONJUGATED DIENES IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A BIS-IMINO-PYRIDINE COMPLEX OF COBALT
审中-公开
基本信息:
- 专利标题: PROCESS FOR THE PREPARATION OF (CO) POLYMERS OF CONJUGATED DIENES IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A BIS-IMINO-PYRIDINE COMPLEX OF COBALT
- 专利标题(中):在含有BIS-IMINO-吡啶复合物的催化体系存在下制备(CO)聚合物的方法
- 申请号:PCT/IB2013/061193 申请日:2013-12-20
- 公开(公告)号:WO2014097245A1 公开(公告)日:2014-06-26
- 发明人: MASI, Francesco , RICCI, Giovanni , SOMMAZZI, Anna , LEONE, Giuseppe , CALDARARO, Maria
- 申请人: VERSALIS S.P.A.
- 申请人地址: Piazza Boldrini 1 I-20097 San Donato Milanese IT
- 专利权人: VERSALIS S.P.A.
- 当前专利权人: VERSALIS S.P.A.
- 当前专利权人地址: Piazza Boldrini 1 I-20097 San Donato Milanese IT
- 代理机构: ZUMSTEIN, Angela
- 优先权: ITMI2012A002206 20121220
- 主分类号: C08F36/06
- IPC分类号: C08F36/06 ; C08F136/06
摘要:
Process for the preparation of (co) polymers of conjugated dienes which comprises polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one bis-imino-pyridine complex of cobalt having general formula (I) : wherein : R 2 and R 3 , equal to or different from each other, represent a hydrogen atom; or they are selected from linear or branched C 1 -C 20 preferably C 1 -C 15 , alkyl groups, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; R 1 and R 4 , different from each other, represent a hydrogen atom; or they are selected from linear or branched C 1 -C 20 preferably C 1 -C 15 , alkyl groups, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; arylalkyl groups; or R 1 and R 2 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R 3 and R 4 , can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R 5 , R 6 and R 7 , equal to or different from each other, represent a hydrogen atom, or they are selected from linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, optionally halogenated, cycloalkyl groups optionally substituted; aryl groups optionally substituted; arylalkyl groups; or R 5 and R 6 , can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, -sulfur, nitrogen, silicon, phosphorous, selenium; or R 6 and R 7 , can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 - C 20 , preferably C 1 -C 15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; X 1 and X 2 , equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, -OCOR 8 groups or -OR 8 groups wherein R 8 is selected from linear or branched C 1 -C 20 / preferably C 1 -C 15 , alkyl groups.
摘要(中):
制备共轭二烯的(共)聚合物的方法,其包括在包含至少一种具有通式(I)的钴的二亚氨基 - 吡啶络合物的催化体系存在下聚合至少一种共轭二烯:其中:R2和 R 3彼此相同或不同,表示氢原子; 或者它们选自直链或支链C 1 -C 20,优选C 1 -C 15烷基,任选卤代的环烷基,任选取代的芳基,任选取代的芳基; R1和R4彼此不同,表示氢原子; 或者它们选自直链或支链C 1 -C 20,优选C 1 -C 15烷基,任选卤代的环烷基,任选取代的芳基,任选取代的芳基; 芳基烷基; 或者R 1和R 2可以任选地彼此结合形成与其结合的其它原子一起,含有3至6个碳原子的饱和的,不饱和的或芳族的,任选地被直链或支链C1- C20,优选C1-C15烷基,所述循环任选地含有其它杂原子,例如氧,硫,氮,硅,磷,硒; 或R 3和R 4可以任选地彼此结合形成与它们所结合的其它原子一起形成含有3-6个碳原子的饱和的,不饱和的或芳族的,任选被直链或支链C1 -C 20,优选C 1 -C 15烷基,所述循环任选地含有其它杂原子,例如氧,硫,氮,硅,磷,硒; R 5,R 6和R 7彼此相同或不同,表示氢原子,或它们选自直链或支链C 1 -C 20,优选C 1 -C 15烷基,任选卤代的环烷基任选取代; 任选取代的芳基; 芳基烷基; 或者R 5和R 6可以任选地彼此结合形成与它们所连接的其它原子一起形成含有3-6个碳原子的饱和的,不饱和的或芳族的,任选被直链或支链C1 -C 20,优选C 1 -C 15烷基,所述循环任选地含有其它杂原子,例如氧,硫,氮,硅,磷,硒; 或R6和R7可以任选地彼此结合形成与其结合的其它原子一起,含有3至6个碳原子的饱和,不饱和或芳族的环,任选被直链或支链C1 -C 20,优选C 1 -C 15烷基,所述循环任选地含有其它杂原子,例如氧,硫,氮,硅,磷,硒; X 1和X 2彼此相同或不同,表示卤素原子,例如氯,溴,碘; 或者它们选自直链或支链C 1 -C 20,优选C 1 -C 15烷基,-OCOR 8基团或-OR 8基团,其中R 8选自直链或支链C 1 -C 20,优选C 1 -C 15烷基。
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F36/00 | 具有1个或更多的不饱和脂族基化合物的均聚物或共聚物,至少有1个不饱和脂族基具有两个或更多的碳—碳双键 |
--------C08F36/02 | .只有两个碳—碳双键的基团 |
----------C08F36/04 | ..共轭的 |
------------C08F36/06 | ...丁二烯 |