基本信息:
- 专利标题: IMPROVED PROCESS FOR POLYMERISING PROPYLENE
- 专利标题(中):改进丙烯聚合方法
- 申请号:PCT/EP2011/069614 申请日:2011-11-08
- 公开(公告)号:WO2012062735A1 公开(公告)日:2012-05-18
- 发明人: PAAVILAINEN, Juha , LESKINEN, Pauli , HAKOLA, Sameli , SANDHOLZER, Daniel , GREIN, Christelle
- 申请人: BOREALIS AG , PAAVILAINEN, Juha , LESKINEN, Pauli , HAKOLA, Sameli , SANDHOLZER, Daniel , GREIN, Christelle
- 申请人地址: Wagramer Strasse 17-19 A-1220 Vienna AT
- 专利权人: BOREALIS AG,PAAVILAINEN, Juha,LESKINEN, Pauli,HAKOLA, Sameli,SANDHOLZER, Daniel,GREIN, Christelle
- 当前专利权人: BOREALIS AG,PAAVILAINEN, Juha,LESKINEN, Pauli,HAKOLA, Sameli,SANDHOLZER, Daniel,GREIN, Christelle
- 当前专利权人地址: Wagramer Strasse 17-19 A-1220 Vienna AT
- 代理机构: LUX, Berthold
- 优先权: EP10190992.7 20101112
- 主分类号: C08F10/06
- IPC分类号: C08F10/06 ; C08F2/00 ; C08F4/646
摘要:
Process for producing a propylene homopolymer, a propylene random copolymer or a heterophasic propylene polymer, which process comprises the steps of (a) prepolymerisation, (b) slurry phase polymerisation (c) gas phase polymerisation and optionally (d) one or two further gas phase polymerisation(s), whereby the process is performed in the presence of a catalyst system comprising (x) a Ziegler-Natta procatalyst and (y) an organometallic cocatalyst and (z) an external donor represented by formula (II) and/or (III) Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) (II) or R 3 nR 4 mSi(OR 5 )z (III) wherein R 1 and R 2 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms and R 3 and R 4 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms, R 5 is methyl or ethyl, z is 2 or 3, preferably 2, m is 0 or 1, n is 0 or 1, with the proviso that n + m +z = 4, the external donor being added in an amount of 3 to 30 wt%, based on the total amount of external donor added, to the prepolymerisation step and in an amount of 70 to 97 wt%, based on the total amount of external donor added, to the slurry polymerisation step.
摘要(中):
制备丙烯均聚物,丙烯无规共聚物或多相丙烯聚合物的方法,该方法包括以下步骤:(a)预聚合,(b)淤浆相聚合(c)气相聚合和任选地(d)一种或两种另外的气体 其中该方法在催化剂体系存在下进行,所述催化剂体系包括(x)齐格勒 - 纳塔前催化剂和(y)有机金属助催化剂和(z)由式(II)表示的外给体和/或 (III)Si(OCH 2 CH 3)3(NR 1 R 2)(II)或R 3 n R 4 m Si(OR 5)z(III)其中R 1和R 2可以相同或不同,表示具有1至12个碳原子的烃基,且R 3和R 4可以 相同或不同,表示具有1至12个碳原子的烃基,R 5是甲基或乙基,z是2或3,优选2,m是0或1,n是0或1,条件是n + + z = 4,外给体的添加量为3〜30重量%,基于外给体ad的总量 给予预聚合步骤,并且以浆料聚合步骤为基础,将加入的外用供体的总量计为70-97重量%。
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F10/00 | 只有1个碳—碳双键的不饱和脂族烃的均聚物或共聚物 |
--------C08F10/04 | .含有3个或4个碳原子的单体 |
----------C08F10/06 | ..丙烯 |