基本信息:
- 专利标题: BOOTSTRAP SYNTHESIS OF BORANES
- 专利标题(中):BORTSTRAP合成硼
- 申请号:PCT/US2007020028 申请日:2007-09-13
- 公开(公告)号:WO2008039312A3 公开(公告)日:2008-05-08
- 发明人: THORN DAVID L , TUMAS WILLIAM
- 申请人: LOS ALAMOS NAT SECURITY LLC , THORN DAVID L , TUMAS WILLIAM
- 专利权人: LOS ALAMOS NAT SECURITY LLC,THORN DAVID L,TUMAS WILLIAM
- 当前专利权人: LOS ALAMOS NAT SECURITY LLC,THORN DAVID L,TUMAS WILLIAM
- 优先权: US84703106 2006-09-22
- 主分类号: C01B35/14
- IPC分类号: C01B35/14
摘要:
Metal hydride materials react with BZ 3 compounds in the presence of ligand to form BH 3 -L compounds. A compound of the formula HBZ 2 is prepared from a compound of the formula BZ 3 by reacting a first amount of a compound of the formula HBZ 2 with a metal hydride material "MH" and a compound "L" to form a material of the formula BH 3 -L, and then reacting the BH 3 -L thus formed with a compound of the formula BZ 3 to form HBZ 2 in a second amount greater than the first amount of HBZ 2 . Z is selected from alkoxy, aryloxy, amido, arylamido, doubly substituted alkoxy, doubly substituted aryloxy, doubly substituted amido, doubly substituted arylamido, alkoxy-amido, and aryloxy-arylamido. When Z is bidentate, then HBZ 2 has a ring structure. "L" is selected from ethers, aromatic ethers, amines, aromatic amines, heterocyclic nitrogen compounds, sulfides, aromatic sulfides, and heterocyclic sulfur compounds. "L" becomes a ligand in the BH 3 -L material.
摘要(中):
金属氢化物材料在配体存在下与BZ 3化合物反应形成BH 3 SUB化合物。 式HBZ SUB 2的化合物由式BZ SUB 3的化合物通过使第一量的式HBZ SUB 2的化合物 与金属氢化物材料“MH”和化合物“L”反应以形成式BH 3 -L的材料,然后如此反应BH <3> -L> 以比第一量的HBZ 2 / HB更大的第二量形成式BZ 3的化合物以形成HBZ 2。 Z选自烷氧基,芳氧基,酰氨基,芳基酰胺基,双取代的烷氧基,双取代的芳氧基,双取代的酰胺基,双取代的芳基酰胺基,烷氧基 - 酰胺基和芳氧基 - 芳基酰胺基。 当Z是双齿时,则HBZ 2 SUB>具有环状结构。 “L”选自醚,芳族醚,胺,芳族胺,杂环氮化合物,硫化物,芳族硫化物和杂环硫化合物。 “L”成为BH <3> SUB-L材料中的配体。
IPC结构图谱:
C | 化学;冶金 |
--C01 | 无机化学 |
----C01B | 非金属元素;其化合物 |
------C01B35/00 | 硼;其化合物 |
--------C01B35/08 | .含硼和氮、磷、氧、硫、硒或碲的化合物 |
----------C01B35/14 | ..含硼和氮、磷、硫、硒或碲的化合物 |