基本信息:
- 专利标题： 以金属有机框架为模板的双金属磷化合物的制备方法和所得到的双金属磷化合物及其应用
- 专利标题（英）：Preparation method of bi-metal phosphorus compound with MOF (metal-organic framework) as template, obtained bi-metal phosphorus compound and application of bi-metal phosphorus compound
- 申请号：CN201910519811.5 申请日：2019-06-17
- 公开(公告)号：CN110182775A 公开(公告)日：2019-08-30
- 发明人： 王壹 , 田兴智 , 覃慧 , 罗军 , 严伟 , 刘渊 , 成刚
- 申请人： 贵阳学院
- 申请人地址： 贵州省贵阳市龙洞堡见龙洞路103号
- 专利权人： 贵阳学院
- 当前专利权人： 贵阳学院
- 当前专利权人地址： 贵州省贵阳市龙洞堡见龙洞路103号
- 代理机构： 北京超凡宏宇专利代理事务所
- 代理人： 李双艳
- 主分类号： C01B25/08
- IPC分类号： C01B25/08 ; C01B25/45 ; H01G11/24 ; H01G11/30 ; H01G11/86
The invention provides a preparation method of a bi-metal phosphorus compound with an MOF (metal-organic framework) as a template, the obtained bi-metal phosphorus compound and an application of the bi-metal phosphorus compound. The preparation method comprises steps as follows: nickel salt, vanadic salt and a polybasic carboxylic acid compound react to obtain Ni-V-MOF; then, Ni-V-MOF and a phosphorus source react to obtain the bi-metal phosphorus compound. The provided bi-metal phosphorus compound can keep the framework structure of a precursor Ni-V-MOF, the structure collapse problem of an inside structure in a large current and long circulation test can be solved, electrolyte penetration is facilitated, contact of an electrolyte with an electrode material is increased, a shorter ion transmission distance is realized, the stability of the whole electrode structure is guaranteed, and more excellent rate capability and circulation performance are realized.