![脱除环氧丙烷反应混合物中的醛类的方法](/CN/2016/1/23/images/201610115263.jpg)
基本信息:
- 专利标题: 脱除环氧丙烷反应混合物中的醛类的方法
- 专利标题(英):Method for removing aldehydes in epoxypropane reaction mixture
- 申请号:CN201610115263.6 申请日:2016-03-01
- 公开(公告)号:CN105906584A 公开(公告)日:2016-08-31
- 发明人: 陈惠华 , 胡文林 , 刘丰
- 申请人: 江苏怡达化学股份有限公司
- 申请人地址: 江苏省无锡市江阴市西石桥球庄1号
- 专利权人: 江苏怡达化学股份有限公司
- 当前专利权人: 江苏怡达化学股份有限公司
- 当前专利权人地址: 江苏省无锡市江阴市西石桥球庄1号
- 代理机构: 北京德恒律治知识产权代理有限公司
- 代理人: 章社杲; 卢军峰
- 主分类号: C07D303/04
- IPC分类号: C07D303/04 ; C07D301/32
The invention relates to a method for removing aldehydes in an epoxypropane reaction mixture. The method comprises carrying out primary aldehyde removal on an epoxypropane reaction mixture through an aldehyde-free resin tank so that aldehyde content is reduced and epoxypropane product purity is guaranteed, orderly removing water and unreacted propylene, feeding the materials containing epoxypropane and methanol into an epoxypropane refining tower, carrying out extraction on methanol in the middle section of the tower through desalinized water containing ethanolamine or hydrazine hydrate, simultaneously removing residual aldehyde in the epoxypropane product, separating the separated aqueous solution through a methanol tower, feeding the aqueous solution into a membrane separation device, further removing residual aldehydes and impurities, returning the methanol as circulation methanol at a penetration side to a reaction system and returning aldehyde-containing methanol at a retentate side to a collection tank. The method utilizes less devices, reduces a disposable investment, does not need hydrogen in a separation and recovery process, does not increase a safety risk, is safe and reliable in use and reduces later waste water treatment energy consumption.
公开/授权文献:
- CN105906584B 脱除环氧丙烷反应混合物中的醛类的方法 公开/授权日:2018-07-06
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07D | 杂环化合物 |
------C07D303/00 | 杂环化合物,含三元环,含有1个氧原子作为仅有的杂环原子 |
--------C07D303/02 | .含环氧乙烷环的化合物 |
----------C07D303/04 | ..除环氧原子外,仅含氢和碳原子 |