基本信息:
- 专利标题： 一种纳米Cu-有机配合物/Ag复合材料的制备方法和应用
- 专利标题（英）：Preparation method and application of nano Cu-organic complex/Ag composite
- 申请号：CN201510862981.5 申请日：2015-11-30
- 公开(公告)号：CN105327714A 公开(公告)日：2016-02-17
- 发明人： 匡芮 , 石敬民 , 郑鲁沂 , 迟颜辉 , 陈雪雪 , 张程程
- 申请人： 山东师范大学
- 申请人地址： 山东省济南市历下区文化东路88号
- 专利权人： 山东师范大学
- 当前专利权人： 山东师范大学
- 当前专利权人地址： 山东省济南市历下区文化东路88号
- 代理机构： 济南圣达知识产权代理有限公司
- 代理人： 曹丽
- 主分类号： B01J31/22
- IPC分类号： B01J31/22 ; C07C211/52 ; C07C209/18 ; C07D303/04 ; C07D301/12 ; B01D53/02
The invention relates to a preparation method and application of a nano Cu-organic complex/Ag composite and belongs to the technical field of metal organic complexes, material science, nano materials, chemical industry, catalyzing and the like. Nano Cu-organic complex crystals with the grain size of 40 nm to 50 nm are adopted for loading nano-silver, due to the fact that the nano Cu-organic complex crystals comprise a large number of unsaturated loca, Ag+ can be selectively adsorbed, during UV-irradiation, Ag particles generated by in-situ reduction of Ag+ are anchored in the nano Cu-organic complex crystals, and therefore the composite is prepared. The cost of preparation raw materials is low, the process is simple and easy to operate, and reaction energy consumption is low. The composite can efficiently catalyze and reduce an aromatic nitrocompound into aromatic amine, and can catalyze phenylethylene oxide into styrene oxide.
公开/授权文献:
- CN105327714B 一种纳米Cu-有机配合物/Ag复合材料的制备方法和应用 公开/授权日：2017-11-07
IPC结构图谱:
| B | 作业；运输 |
| --B01 | 一般的物理或化学的方法或装置 |
| ----B01J | 化学或物理方法，例如，催化作用、胶体化学；其有关设备 |
| ------B01J31/00 | 包含氢化物，配位配合物或有机化合物的催化剂 |
| --------B01J31/02 | .含有机化合物或金属氢化物 |
| ----------B01J31/22 | ..有机配合物 |