
基本信息:
- 专利标题: 一种高熔体流动性高刚性抗冲聚丙烯的制备方法
- 专利标题(英):Preparation method of high-melt fluidity high-rigidity antishock polypropylene
- 申请号:CN201210424321.5 申请日:2012-10-30
- 公开(公告)号:CN103788256A 公开(公告)日:2014-05-14
- 发明人: 毕福勇 , 宋文波 , 杨光 , 张晓萌 , 魏文骏 , 郭梅芳 , 张师军
- 申请人: 中国石油化工股份有限公司 , 中国石油化工股份有限公司北京化工研究院
- 申请人地址: 北京市朝阳区朝阳门北大街22号
- 专利权人: 中国石油化工股份有限公司,中国石油化工股份有限公司北京化工研究院
- 当前专利权人: 中国石油化工股份有限公司,中国石油化工股份有限公司北京化工研究院
- 当前专利权人地址: 北京市朝阳区朝阳门北大街22号
- 代理机构: 北京聿宏知识产权代理有限公司
- 代理人: 吴大建; 卢绮琴
- 主分类号: C08F10/06
- IPC分类号: C08F10/06 ; C08F4/646
The invention discloses a method of high-melt fluidity high-rigidity antishock polypropylene. The method is characterized by comprising the following steps: 1) under the effect of hydrogen and a Ziegler-Natta catalyst of a trialkoxyl silicane-containing compounds external electron donor, propylene or propylene and alpha-alkene are polymerized to obtain a polymer A; 2) a dialkoxysilanes compound external electron donor is added for premixing with the polymer A; 3)under the premixed material in the step 2) and hydrogen, propylene and alpha-alkene are polymerized to obtain a polymer B with melt mass flux rate of 0.01-30g/min; the antishock polypropylene comprising the polymer A and the polymer B can be finally obtained, the melt mass flux rate is 20-1000g/10min, and preferably is 20-100g/10min. The provided method has the advantages of easy operation, convenient operation and easy industrial production, so that high performance polypropylene with high melt mass flux rate, high rigidity and high antishock strength is prepared, and the high-melt fluidity high-rigidity antishock polypropylene has wide application and prospect.
公开/授权文献:
- CN103788256B 一种高熔体流动性高刚性抗冲聚丙烯的制备方法 公开/授权日:2016-08-17
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F10/00 | 只有1个碳—碳双键的不饱和脂族烃的均聚物或共聚物 |
--------C08F10/04 | .含有3个或4个碳原子的单体 |
----------C08F10/06 | ..丙烯 |