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基本信息:
- 专利标题: 一种芳香胺的连续重氮化生产工艺
- 专利标题(英):Continuous diazotization production process of aromatic amine
- 申请号:CN201210355219.4 申请日:2012-09-21
- 公开(公告)号:CN103664683A 公开(公告)日:2014-03-26
- 发明人: 何旭斌 , 陶建国 , 孟明 , 朱敬鑫 , 杨伟军 , 李建勋 , 黄洪松
- 申请人: 浙江龙盛集团股份有限公司 , 浙江龙盛染料化工有限公司 , 浙江龙盛化工研究有限公司
- 申请人地址: 浙江省绍兴市上虞市道墟镇
- 专利权人: 浙江龙盛集团股份有限公司,浙江龙盛染料化工有限公司,浙江龙盛化工研究有限公司
- 当前专利权人: 浙江龙盛集团股份有限公司,浙江龙盛染料化工有限公司,浙江龙盛化工研究有限公司
- 当前专利权人地址: 浙江省绍兴市上虞市道墟镇
- 代理机构: 杭州天正专利事务所有限公司
- 代理人: 黄美娟; 冷红梅
- 主分类号: C07C245/20
- IPC分类号: C07C245/20
The invention provides a continuous diazotization production process of aromatic amine. The process is as follows: by utilizing a multistage serially connected diazotization reaction kettle, throwing a powdery aromatic amine raw material into a stock bin of a feeding system, integrally weighing the feeding system and the solid raw material through a weighing device, continuously and stably adding the aromatic amine into the diazotization reaction kettle through an automatic feeder, calculating the feeding dosage of the aromatic amine raw material within a unit time through a difference method, continuously and stably adding nitrosyl sulfuric acid and sulfuric acid into the diazotization reaction kettle according to a feeding molar ratio of the aromatic amine, the sulfuric acid and the nitrosyl sulfuric acid of 1:(1-5): (1.01-1.10) through a liquid metering and adjusting device, stirring and controlling the temperature to 0-40 DEG C to carry out a diazotization reaction. By adopting the continuous diazotization production process disclosed by the invention, industrial large-scale production becomes possible, the traditional intermittent dosing method of raw materials is improved, the reaction raw material proportion, the reaction temperature and the reaction time are accurately controlled to improve the diazonium salt yield, stabilize the diazonium salt quality and reduce the color differences between lots.
公开/授权文献:
- CN103664683B 一种芳香胺的连续重氮化生产工艺 公开/授权日:2018-05-11
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C245/00 | 含有至少具有1个氮—氮重键的至少两个氮原子的链的化合物 |
--------C07C245/20 | .重氮化合物 |