![一种从磷矿中富集回收稀土的方法](/CN/2007/1/35/images/200710178377.jpg)
基本信息:
- 专利标题: 一种从磷矿中富集回收稀土的方法
- 专利标题(英):Rare-earth enrichment recovery method from phosphorite
- 申请号:CN200710178377.6 申请日:2007-11-29
- 公开(公告)号:CN101451200B 公开(公告)日:2011-04-20
- 发明人: 龙志奇 , 黄小卫 , 王良士 , 彭新林 , 韩业斌 , 朱兆武 , 张顺利 , 崔大立 , 李红卫
- 申请人: 北京有色金属研究总院 , 有研稀土新材料股份有限公司
- 申请人地址: 北京市新街口外大街2号
- 专利权人: 北京有色金属研究总院,有研稀土新材料股份有限公司
- 当前专利权人: 乐山有研稀土新材料有限公司
- 当前专利权人地址: 北京市新街口外大街2号
- 代理机构: 北京北新智诚知识产权代理有限公司
- 代理人: 郭佩兰
- 主分类号: C01B25/222
- IPC分类号: C01B25/222 ; C22B59/00 ; C22B3/06 ; C22B3/44 ; C22B3/22
The invention discloses a method for enriching and recovering rare earth from phosphorite, which drives a large quantity of rare earth elements to be enriched into a phosphate system and be separated and recovered by inhibiting loss of the rare earth in phosphogypsum through optimizing the technological conditions and adding a calcium sulphate crystal seed and/or an active additive on the premiseof not changing the wet-method phosphate process. Compared with the prior art, the method controls proper technological conditions and particularly adds the calcium sulphate crystal seed and/or the active additive, can improve the crystalline morphology of the phosphogypsum, reduce the eutectic effect and the adsorption effect of phosphate rare earth and calcium sulphate, reduce enrichment of thephosphate rare earth and the calcium sulphate to the phosphogypsum, make the enrichment ratio of the rare earth in phosphate reach more than 80 percent, and be favorable for recovering the rare earthfrom the phosphate. Moreover, the method can meet the requirements of wet-method phosphate production, has simple technique and high content of rare earth in the phosphate, and can adopt proper technology to recover rare earth from the phosphate and realize effective combination of rare earth recovery technology and phosphorization technology.
公开/授权文献:
- CN101451200A 一种从磷矿中富集回收稀土的方法 公开/授权日:2009-06-10
IPC结构图谱:
C | 化学;冶金 |
--C01 | 无机化学 |
----C01B | 非金属元素;其化合物 |
------C01B25/00 | 磷;其化合物 |
--------C01B25/16 | .磷的含氧酸;其盐类 |
----------C01B25/18 | ..磷酸 |
------------C01B25/22 | ...用含磷酸盐物料与酸反应制备,如湿法 |
--------------C01B25/222 | ....与硫酸,以硫酸为主要成分的酸的混合物或反应中形成它的化合物混合物,如二氧化硫,水和氧的混合物 |