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    • 8. 发明申请
    • FUNCTIONALIZED SEMICONDUCTOR NANOPARTICLES AND METHOD FOR THE MANUFACTURE THEREOF
    • WO2019211319A1
    • 2019-11-07
    • PCT/EP2019/061138
    • 2019-05-01
    • UNIVERSITEIT VAN AMSTERDAMUNIVERSITEIT TWENTE
    • NIE, HuiNEWELL, KaterinaPAULUSSE, Jos Marie Johannes
    • C09K11/66C09K11/59C09K11/02
    • Method for manufacturing fluoro(hydro)carbon-substituted silicon or germanium quantum dots which comprises the steps of: - reacting a Zintl salt or intermetallic compound of post- transition metals or metalloids of silicon or germanium with a halogen-containing oxidizing agent to form halide-terminated silicon or germanium quantum dots, - reacting the halide-terminated silicon or germanium quantum dots with a fluoro(hydro)carbon agent selected from the group of metal-fluoro (hydro)carbon compounds of the formula MRq, wherein M is a metal selected from Group 1, 2, 4, 11, 12, 13, or 14 of the periodic table of elements, q is an integer which corresponds to the valence of the metal, and R is CFnHm- fluoro/hydro-carbon, wherein n is 1 or 2, m is 0 or 1, and the total of n and m is 2, wherein each R may be the same or different, metal-fluoro (hydro)carbon halide compounds of the formula NQaRp wherein N is a metal selected from Group 1, 2, 4, 11, 12, 13, or 14 of the periodic table of elements, Q is a halogen selected from F, Cl, Br, or I, wherein each Q may be the same or different, a and p are integers in the range of 1- 3, and the total of a and p corresponds to the valence of the metal, and R is as defined above, and metal-fluoro (hydro)carbon compounds of the formula CuR2Li, wherein R is as defined above, to form fluoro(hydro)carbon-substituted silicon or germanium quantum dots. The method makes it possible to obtain quantum dots with a tailored emission spectrum with high quality in a stable process. The particles obtained by this process are also claimed.