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    • 4. 发明申请
    • FIBRE-REACTIVE AZO DYES, THEIR PREPARATION AND THEIR USE
    • 纤维反应性AZO染色及其制备及其使用
    • WO2004013235A1
    • 2004-02-12
    • PCT/EP2003/007636
    • 2003-07-15
    • CIBA SPECIALTY CHEMICALS HOLDING, INC.TZIKAS, AthanassiosMÜLLER, BernhardROENTGEN, Georg
    • TZIKAS, AthanassiosMÜLLER, BernhardROENTGEN, Georg
    • C09B62/507
    • C09B62/4411
    • Reactive dyes of formula (I), wherein A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, Q 1 , and Q 2 are each independently of the other hydrogen or unsubstituted or substituted C 1 ,-C 4 alkyl, (Q 3 ) n denotes n substituents selected from the group C 1 ,-C 4 alkyl, C 1 -C 4 alkoxy, halogen and sulfo, X is halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C 1 -C 4 alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C 1 -C 4 alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, Y is vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, k is a number 2, 3, 4, 5 or 6, m is a number 0 or 1, and n is a number 0, 1 or 2, with the proviso that when A denotes a monoazo chromophore it is not directly linked to the triazinyl radical through a hydroxynaphthalenesulfonic acid coupling component and does not denote a radical of formula (II), are suitable for dyeing cellulosic or nitrogen-containing fibre materials.
    • 式(I)的活性染料,其中A是单偶氮,多偶氮,金属络合物偶氮,蒽醌,酞菁,甲az或二恶嗪发色团的基团,Q1和Q2各自独立地为另一个氢或未取代或取代的C 1 - C4烷基,(Q3)n表示选自C1,-C4烷基,C1-C4烷氧基,卤素和磺基的n个取代基,X是卤素,3-羧基吡啶-1-基,3-氨基甲酰基吡啶-1-基,羟基, 在烷基部分未被取代或取代的未取代或未取代的苯氧基部分中未取代或取代的苯氧基,在烷基部分未取代或取代的未取代或取代的C1-C4烷硫基,未取代或取代的氨基或可含有或不含有其他杂原子的N-杂环,Y 是乙烯基或基团-CH 2 -CH 2 -U,U是在碱性条件下可除去的基团,k是数字2,3,4,5或6,m是数字0或1,n是数字0, 1或2,条件是当A表示单偶氮发色团时,它不直接连接到三嗪基r 通过羟基萘磺酸偶联组分,不表示式(II)的基团,适用于染色纤维素或含氮纤维材料。
    • 10. 发明申请
    • IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS
    • 有机化合物的改善或有关
    • WO1986000632A1
    • 1986-01-30
    • PCT/EP1985000305
    • 1985-06-25
    • SANDOZ AGBAUMANN, WernerVAN DIEST, JosephEICHENBERGER, HerbertOPPLIGER, Max
    • SANDOZ AG
    • C09B62/507
    • C09B62/507
    • A monoazo or disazo compound in metal-free form or in 1:1 or 1:2 metal complex form which in the metal-free form corresponds to formula (I): CH2=CH-SO2-W1-D - N = N - K-(W2-Z)n in which D is the radical of a diazo component, K is the radical of a coupling component, W1 is a direct bond or a divalent bridging group, W2 is a divalent bridging group, n is an integer 1 to 4, Z is a water solubilising protonable amine group, a quaternary ammonium group, a hydrazinium group or a ternary sulphonium group, which compound is in free basic, salt form or acid addition salt form formed by the addition of dilute aqueous organic or mineral acids, can be used for dyeing or printing fibers, threads or textile material particularly containing or consisting of natural or synthetic polyamides, cotton, polyacrylonitrile, leather or fibre blends such as cotton-polyester, polyester-wool and polyacrylonitrile-wool.
    • 无金属形式的单偶氮或双偶氮化合物或无金属形式的1:1或1:2金属络合物形式对应于式(I):CH 2 = CH-SO 2 -W 1 -D-N = N- K-(W2-Z)n,其中D是重氮组分的基团,K是偶合组分的基团,W1是直接键或二价桥连基团,W2是二价桥连基团,n是整数 如图1至图4所示,Z是水溶性质子化胺基,季铵基,肼基或三元锍基,该化合物是游离碱,盐形式或酸加成盐形式,通过加入稀有机有机水或 无机酸可用于染色或印花纤维,丝线或纺织材料,特别是含有或由天然或合成聚酰胺,棉,聚丙烯腈,皮革或纤维混合物如棉 - 聚酯,聚酯 - 羊毛和聚丙烯腈 - 羊毛组成的组合物。