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    • 1. 发明申请
    • CATIONIC AZO-DYES
    • 阳离子偶氮染料
    • WO00027929A1
    • 2000-05-18
    • PCT/EP1999/008274
    • 1999-10-30
    • C09B44/02C09B67/22
    • C09B44/02C09B67/0046Y10S534/03
    • The invention relates to cationic azo-dyes of the general formula (I), in which R and R independently of each other are hydrogen, nitro, halogen, C1-C6-alkyl; R is hydrogen, C1-C6-alkyl, which can be interrupted by 1 or 2 non-adjoining oxy-, imino- or C1-C6-alkylimino groups or a rest (II); A and A independently of each other are oxy, imino or possibly substituted C1-C6-alkylimino; B and B independently of each other are C1-C6-alkylene, which can be interrupted by 1 or 2 non-adjoining oxy-, imino- or possibly substituted C1-C6-alkylimino groups or a rest (II); An is the equivalent of an anion; n is a number between 1 and 8; and K is the rest of a coupling component or a monoazo-dye II. The invention also relates to a method for producing said dyes, to their use for colouring and printing on natural or synthetic substrates and to mixtures thereof.
    • 阳离子,其中R <1>和R <2>独立地为氢,硝基,卤素,C1-C6烷基,R <3>为氢,C1-C6烷基被1或取代的通式(I)的偶氮染料 不相邻的2氧基,亚氨基,C1-C6烷基亚氨基或一个式的基团(II)可以被中断,一<1>和<2>独立地是氧,亚氨基或取代或未取代的C1-C6烷基亚氨基,B < 1>和B <2>独立地是C1-C6-亚烷基,其被1或2不相邻的氧,亚氨基,任选取代的C1-C6-烷基亚氨基或一个式的基团(II)可以被中断的 阴离子的当量,n是一个从1到8,且K是基团A偶合组分的或单偶氮染料II的,它们的制备方法,其用于染色使用和印刷天然或合成底物,以及它们的混合物。
    • 3. 发明申请
    • METHOD OF FORMING THIN FILM OF ORGANIC AMMONIUM/INORGANIC LAMELLAR PEROVSKITE COMPOUND
    • 有机氨/无机玻璃纤维素化合物薄膜的制备方法
    • WO01087896A1
    • 2001-11-22
    • PCT/JP2000/008943
    • 2000-12-15
    • C01G3/14C01G21/00C09B44/02C09B55/00C09B67/02C09B69/02C23C26/00C30B7/00C30B29/54C07F1/08C07F7/24B01J19/00
    • C30B29/54C30B7/00C30B7/005C30B29/52
    • A method by which a thin film of a lamellar perovskite compound can be formed while regulating the film thickness and structure on a monomolecular level and various lamellar perovskite compounds can be combined with each other on a monomolecular level. The method is for forming a compound represented by the chemical formula A2MX4 (wherein A is the molecule of an organic ammonium; M is a Group IV element or a transition metal; and X is a halogen, e.g., chlorine, bromine, or iodine) and having a superlattice structure comprising layers of molecules of the organic ammonium (A) and alternately stacked therewith layers of an inorganic halide (MX4). A monomolecular film of an amphiphatic organic-amine hydrohalogenate having a long-chain alkyl group is spread on an aqueous solution of both an inorganic halide (MX2) and a methylamine hydrohalogenate. This monomolecular film is allowed to stand as it is to thereby form on the aqueous solution a monomolecular film of a lamellar perovskite compound. This monomolecular perovskite film is transferred to a substrate by the Langmuir-Blodgett method. In this manner, such monomolecular perovskite films are stacked one by one.
    • 可以在单分子水平上调节膜厚度和结构的同时形成层状钙钛矿化合物的薄膜的方法,并且可以在单分子层级上彼此组合各种层状钙钛矿化合物。 该方法用于形成由化学式A2MX4表示的化合物(其中A是有机铵的分子; M是IV族元素或过渡金属; X是卤素,例如氯,溴或碘) 并且具有包含有机铵(A)分子层的超晶格结构,并交替层叠无机卤化物(MX4)层。 具有长链烷基的双键有机 - 胺基氢卤酸盐的单分子膜分散在无机卤化物(MX2)和氢甲基胺甲胺的水溶液中。 使该单分子膜原样放置,从而在水溶液中形成层状钙钛矿化合物的单分子膜。 通过Langmuir-Blodgett法将该单分子钙钛矿膜转移到底物上。 以这种方式,一个接一个堆叠这种单分子钙钛矿膜。