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1. 发明申请

WO2017106146A1 SUPERCRITICAL WATER UPGRADING PROCESS TO PRODUCE HIGH GRADE COKE 审中-公开
标题翻译：超临界水升级工艺生产高品质焦炭
公开(公告)号：WO2017106146A1
公开(公告)日：2017-06-22
申请号：PCT/US2016/066294
申请日：2016-12-13
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： CHOI, Ki-Hyouk , ALABDULLAH, Mohammad A. , AL-SHAFEI, Emad N. , ALANZI, Massad S. , ALOTAIBI, Bandar K. , ALSOLAMI, Bandar H. , ALSOMALI, Ali M.
IPC分类号： C10G31/06 , C10G31/08 , C10G33/00 , C10G55/04 , C10G9/00 , C10G21/00 , C07C4/04 , C07C7/00 , C07C7/10 , C10G21/14 , C10G69/06 , B01D11/04 , C10G31/10 , C10G45/26 , C10L9/08 , C10G67/04 , B01J3/00 , C10L5/00 , C10B57/00 , C10G49/00 , C10G47/32
CPC分类号： C10B57/06 , B01D11/0403 , B01D11/0415 , B01D11/0488 , B01J3/008 , C10B55/00 , C10B57/045 , C10G9/005 , C10G21/003 , C10G21/14 , C10G31/06 , C10G31/08 , C10G31/10 , C10G45/26 , C10G47/32 , C10G49/007 , C10G49/18 , C10G55/04 , C10G67/0454 , C10G69/06 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2300/206 , C10G2300/4006 , C10G2300/4012 , C10G2300/42
摘要： Embodiments of a process for producing high grade coke from crude oil residue include at least partially separating, in a solvent extraction unit, the crude oil residue into a deasphalted oil (DAO)-containing stream and an asphaltene containing-stream, producing a pressurized, heated DAO-containing stream, where the pressurized, heated DAO-containing stream, mixing a supercritical water stream with the pressurized, heated DAO-containing stream to create a combined feed stream, introducing the combined feed stream to an upgrading reactor system operating at supercritical temperature and pressure to yield one or more upgrading reactor output streams comprising upgraded product and a slurry mixture, where the slurry mixture comprises sulfur and one or more additional metals. The process also may include calcining the slurry mixture at a temperature of from 700°C to 1900°C to produce a product stream comprising the high grade coke.
摘要翻译：由原油残余物生产高级焦炭的方法的实施方案包括在溶剂萃取单元中至少部分地将原油残余物分离成含脱沥青油（DAO）的物流和沥青质产生加压的加热的含DAO的料流，其中加压加热的含DAO的料流将超临界水流与加压的加热的含DAO的料流混合以产生组合的料流，将组合的料流涉及在超临界温度和压力下操作的升级反应器系统，以产生包含升级产物和淤浆混合物的一个或多个升级反应器输出流，其中淤浆混合物包含硫和一种或多种另外的金属。该方法还可以包括在700℃至1900℃的温度下煅烧浆料混合物以产生包含高级焦炭的产物料流。

2. 发明申请

WO2017106088A1 SUPERCRITICAL WATER UPGRADING PROCESS TO PRODUCE PARAFFINIC STREAM FROM HEAVY OIL 审中-公开
标题翻译：超临界水升级工艺生产重油中的石油馏分
公开(公告)号：WO2017106088A1
公开(公告)日：2017-06-22
申请号：PCT/US2016/066129
申请日：2016-12-12
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： CHOI, Ki-Hyouk , ALABDULLAH, Mohammad A. , PUNETHA, Ashok K. , AL-SHAFEI, Emad N.
IPC分类号： C10G51/02 , C10G9/36 , C10G47/32 , C10G49/00 , C10G65/10
CPC分类号： C10G51/023 , C10G9/36 , C10G47/32 , C10G49/007 , C10G65/10 , C10G75/00 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2400/00 , C10G2400/10
摘要： Embodiments of a process for producing paraffins from a petroleum-based composition comprising long chain aromatics comprise mixing a supercritical water stream with a pressurized, heated petroleum-based composition to create a combined feed stream, introducing the combined feed stream to a first reactor through an inlet port of the first reactor, where the first reactor operates at supercritical pressure and temperature, cracking at least a portion of the long chain aromatics in the first reactor to form a first reactor product, and then introducing the first reactor product to a second reactor through an upper inlet port of the second reactor operating at supercritical pressure and temperature, where the second reactor is a downflow reactor comprising an upper inlet port, a lower outlet port, and a middle outlet port are provided. The middle outlet product passing out of the middle outlet port comprises paraffins and short chain aromatics.
摘要翻译：由包含长链芳族化合物的基于石油的组合物生产链烷烃的方法的实施方案包括将超临界水流与加压的，加热的基于石油的组合物混合以产生组合进料流，将组合的进料流原料流通过第一反应器的入口进入第一反应器，其中第一反应器在超临界压力和温度下操作，在第一反应器中裂化至少一部分长链芳族化合物以形成第一反应器产物，然后引入将第一反应器产物通过在超临界压力和温度下操作的第二反应器的上部入口连接到第二反应器，其中第二反应器是包括上部入口端口，下部出口端口和中间出口端口的下流式反应器。从中间出口流出的中间出口产品包含石蜡和短链芳烃。

3. 发明申请

WO2016009333A1 UPGRADING HYDROGEN DEFICIENT STREAMS USING HYDROGEN DONOR STREAMS IN A HYDROPYROLYSIS PROCESS 审中-公开
标题翻译：在氢解过程中使用氢离子流增加氢气缺乏流
公开(公告)号：WO2016009333A1
公开(公告)日：2016-01-21
申请号：PCT/IB2015/055295
申请日：2015-07-13
申请人： SABIC GLOBAL TECHNOLOGIES B.V.
发明人： NARAYANASWAMY, Ravichander , RAMAMURTHY, Krishna Kumar , SREENIVASAN, P. S.
IPC分类号： C10G47/32 , C10G1/06 , C10G1/08 , C10G1/10 , C10G3/00
CPC分类号： C10G1/10 , C10G1/06 , C10G1/08 , C10G3/50 , C10G47/32 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P30/20
摘要： Disclosed is a method for producing olefins and aromatic compounds from a hydrogen lean carbon containing feed, the method comprising hydropyrolyzing the hydrogen lean carbon containing feed in the presence of a hydrogen donor feed under reaction conditions sufficient to produce a product comprising olefins and aromatic compounds or a hydrocarbonaceous stream, wherein the hydrocarbonaceous stream is further processed into olefins and aromatic compounds, wherein the olefins and aromatic compounds from (i) or the hydrocarbonaceous stream from (ii) are each obtained by hydrogenation of the hydrogen lean carbon containing feed with the hydrogen donor feed and cracking of carbonaceous compounds comprised in the hydrogenated feed, and wherein the hydrogen donor feed comprises a compound that donates hydrogen to carbonaceous compounds in the hydrogen lean feed.
摘要翻译：公开了一种从含贫氢碳的进料中生产烯烃和芳族化合物的方法，该方法包括在氢供体进料存在下，在足以产生包含烯烃和芳族化合物的产物的反应条件下，加氢热解含贫碳原料的进料，或烃流，其中烃流进一步加工成烯烃和芳族化合物，其中来自（i）的烯烃和芳族化合物或来自（ii）的烃物流各自通过含氢贫碳的进料与氢气氢化而获得供体进料和包含在氢化进料中的含碳化合物的裂解，并且其中氢供体进料包含向氢气进料中的碳质化合物提供氢气的化合物。

4. 发明申请

WO2015094948A1 PRODUCTION OF UPGRADED PETROLEUM BY SUPERCRITICAL WATER 审中-公开
标题翻译：通过超级水生产升级石油
公开(公告)号：WO2015094948A1
公开(公告)日：2015-06-25
申请号：PCT/US2014/069954
申请日：2014-12-12
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： CHOI, Ki-hyouk , LEE, Joo-hyeong , GARHOUSH, Mohammad, S. , ALSHAREEF, Ali, H.
IPC分类号： C10G49/00 , C10G47/32 , C10G47/02 , B01D11/04 , B01J13/00 , C10G49/18
CPC分类号： C10G55/00 , B01D11/0407 , B01J3/008 , C10G47/02 , C10G47/32 , C10G49/18 , C10G2300/202 , C10G2300/206 , C10G2300/308 , C10G2300/4006
摘要： A method for upgrading a petroleum feedstock using a supercritical water petroleum upgrading system includes introducing the petroleum feedstock, water and an auxiliary feedstock. The method includes operating the system to combine the petroleum feedstock and the water to form a mixed petroleum feedstock and introducing separately and simultaneously into a lower portion of an upflowing supercritical water reactor. The auxiliary feedstock is introduced such that a portion of a fluid contained within the upflowing reactor located proximate to the bottom does not lack fluid momentum. An embodiment of the method includes operating the supercritical water petroleum upgrading system such that the upflowing reactor product fluid is introduced into an upper portion of a. downflowing supercritical water reactor. The supercritical water petroleum upgrading system includes the upflowing supercritical water reactor and optionally a downflowing supercritical water reactor.
摘要翻译：使用超临界水石油改质系统升级石油原料的方法包括引入石油原料，水和辅助原料。该方法包括操作该系统以组合石油原料和水以形成混合石油原料，并将其分开并同时引入向上流动的超临界水反应器的下部。引入辅助原料使得包含在靠近底部的向上流动的反应器内的流体的一部分不会流体动量。该方法的一个实施例包括操作超临界水石油改质系统，使得向上流动的反应器产物流体被引入到上部。下流超临界水反应堆。超临界水汽提升系统包括向上流动的超临界水反应堆和任选的向下流动的超临界水反应堆。

5. 发明申请

WO2014140175A1 GRAVITATIONAL COLLISION ENHANCED UPGRADING OF HEAVY OILS 审中-公开
标题翻译：重力碰撞增强重油
公开(公告)号：WO2014140175A1
公开(公告)日：2014-09-18
申请号：PCT/EP2014/054959
申请日：2014-03-13
申请人： FLUID OIL LIMITED
发明人： ELLINGSEN, Olav
IPC分类号： C10G47/30 , C10G47/32 , C10G9/32 , C10G11/18
CPC分类号： C10G47/32 , C10G9/32 , C10G11/182 , C10G47/30 , C10G55/06
摘要： The present invention relates to gravitational collision enhanced upgrading of heavy oils, It thus describes a thermodynamic cracking process for heavy oil, extra heavy oil and bituem as well as a thermodynamic cracking unit for carrying out the process.
摘要翻译：本发明涉及重油的重力碰撞增强升级，因此描述了重油，超重油和沥青的热力学裂解过程以及用于进行该过程的热力学裂解装置。

6. 发明申请

WO2022251084A1 INTEGRATED SLURRY HYDROPROCESSING PROCESS AND SYSTEM 审中-公开
公开(公告)号：WO2022251084A1
公开(公告)日：2022-12-01
申请号：PCT/US2022/030444
申请日：2022-05-22
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： CHOI, Ki-Hyouk
IPC分类号： C10G47/04 , B01J3/00 , C10G47/32 , C10G49/04 , C10G49/18 , C10G51/04 , C10G45/16 , C10G47/26 , B01J23/28
摘要： An integrated catalytic process for upgrading a feed oil comprises the steps of introducing a catalyst precursor solution to a supercritical water (SCW) process unit, where the catalyst precursor solution comprises a catalyst precursor dissolved in liquid water; introducing a feed water to the SCW process unit; introducing the feed oil to the SCW process unit; treating the catalyst precursor solution, the feed water, and the feed oil in the SCW process unit to produce a SCW effluent, where the catalyst precursor is converted to catalyst particles; separating the SCW effluent in a separator unit to produce a SCW distillate product, a SCW residue product; introducing the SCW residue product to a slurry hydroprocessing unit, where the SCW residue product comprises the catalyst particles; treating the SCW residue product and the hydrogen gas in the slurry hydroprocessing unit to produce a product gas stream and an upgraded oil product.

7. 发明申请

WO2022146512A1 SYSTEMS AND PROCESSES FOR TREATING DISULFIDE OIL 审中-公开
公开(公告)号：WO2022146512A1
公开(公告)日：2022-07-07
申请号：PCT/US2021/052363
申请日：2021-09-28
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： FATHI, Mazin M. , CHOI, Ki-Hyouk
IPC分类号： C10G31/06 , C10G31/08 , C10G47/32 , C10G49/18 , B01J3/00
摘要： A process for treating a disulfide oil composition that includes combining a supercritical water stream, a hydrogen stream, and a disulfide oil composition in a mixing device to create a combined disulfide feed stream; introducing the combined disulfide feed stream into a supercritical water hydrogenation reactor operating at a temperature greater than a critical temperature of water and a pressure greater than a critical pressure of water; and at least partially converting the combined disulfide feed stream to an upgraded disulfide product.

8. 发明申请

WO2021241897A1 코크스 제조 부산물을 이용한 중질유분의 경질화 방법 审中-公开
公开(公告)号：WO2021241897A1
公开(公告)日：2021-12-02
申请号：PCT/KR2021/005313
申请日：2021-04-27
申请人： 한국화학연구원 , 재단법인 포항산업과학연구원
发明人： 박선영 , 안치웅 , 김규태 , 강기혁 , 서휘민 , 강나래 , 서필원 , 김준우 , 고동준
IPC分类号： C10G47/32 , C10G47/02 , C10G67/04 , C10G21/00 , C10B53/08
摘要： 본 발명은 코크스 제조 부산물을 이용한 중질유분의 경질화 방법에 관한 것으로서, 상세하게는 중질유분에 코크스 제조 부산물을 혼합하여 혼합 용액을 제조하는 단계; 및 상기 혼합 용액을 수소화 촉매 하에 수소화 반응 시키는 단계;를 포함하는 것으로서, 코크스 제조 부산물을 수소공여체로 활용함으로써, 코크 생성량을 저감시키고 첨가되는 수소분압을 현저히 감소시킬 수 있어, 경제적이며 효과적인 중질유분의 경질화 방법을 제공한다.

9. 发明申请

WO2021086762A1 ENHANCED HYDROPROCESSING PROCESS WITH AMMONIA AND CARBON DIOXIDE RECOVERY 审中-公开
公开(公告)号：WO2021086762A1
公开(公告)日：2021-05-06
申请号：PCT/US2020/057248
申请日：2020-10-24
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： KOSEOGLU, Omer, Refa
IPC分类号： C10G49/18 , C10G49/22 , C10G45/00 , C10G47/32 , B01D53/14 , C02F1/00 , C10K1/00
摘要： A process for capturing carbon dioxide includes the steps of mixing a hydrogen stream and a feedstock stream to produce a mixed stream, wherein the feedstock stream includes hydrocarbons, reacting the hydrocarbons and the hydrogen in the primary reactor of the hydroprocessing unit to produce a hydroprocessing product stream and a carbon dioxide stream, wherein the hydroprocessing product stream includes light products, wherein the hydroprocessing unit is further configured to produce ammonium bisulfide, collecting the ammonium bisulfide in the water to produce a sour water, processing the sour water in the waste water unit to produce an ammonia stream, a hydrogen sulfide stream, and a stripped water stream, introducing the ammonia stream to a carbon dioxide recovery system, and separating carbon dioxide from the carbon dioxide stream using the ammonia in the ammonia stream to produce a carbon dioxide product.

10. 发明申请

WO2018009808A1 SUPERCRITICAL WATER SEPARATION PROCESS 审中-公开
标题翻译：超临界水分离过程
公开(公告)号：WO2018009808A1
公开(公告)日：2018-01-11
申请号：PCT/US2017/041116
申请日：2017-07-07
申请人： APPLIED RESEARCH ASSOCIATES, INC.
发明人： COPPOLA, Edward, N. , RED, Charles, Jr. , NANA, Sanjay , PELT, Kenneth, D. , WAHLGREN, Jocelyn, Marie
IPC分类号： C10G49/18 , C10G47/32 , C10L9/08
摘要： A supercritical water separation process and system is disclosed for the removal of metals, minerals, particulate, asphaltenes, and resins from a contaminated organic material. The present invention takes advantage of the physical and chemical properties of supercritical water to effect the desired separation of contaminants from organic materials and permit scale-up. At a temperature and pressure above the critical point of water (374°C, 22.1 MPa), nonpolar organic compounds become miscible in supercritical water (SCW) and polar compounds and asphaltenes become immiscible. The process and system disclosed continuously separates immiscible contaminants and solids from the supercritical water and clean oil product solution. The present invention creates a density gradient that enables over 95% recovery of clean oil and over 99% reduction of contaminants such as asphaltenes and particulate matter depending on the properties of the contaminated organic material.
摘要翻译：公开了一种用于从受污染的有机材料中去除金属，矿物，颗粒，沥青质和树脂的超临界水分离方法和系统。本发明利用超临界水的物理和化学性质来实现期望的污染物与有机材料的分离并允许放大。在高于水临界点（374℃，22.1MPa）的温度和压力下，非极性有机化合物在超临界水（SCW）和极性化合物中混溶，沥青质变得不混溶。所公开的方法和系统连续地将不混溶的污染物和固体从超临界水和干净的油产品溶液中分离出来。本发明创造了一种密度梯度，其能够根据污染的有机材料的特性实现超过95％的清洁油回收和超过99％的污染物例如沥青质和颗粒物质的减少。

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