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    • 5. 发明申请
    • PITCH PRODUCTION, FRACTIONATION AND HIGH SOFTENING POINT PITCH
    • 刨切生产,分岔和高NING点
    • WO2009074837A1
    • 2009-06-18
    • PCT/IB2007/003836
    • 2007-12-10
    • DTX TECHNOLOGIES LLCMALONE, Donald, P.
    • MALONE, Donald, P.
    • C10G9/00C10C1/19C10C3/00
    • C10G9/00C10C1/16C10C1/19C10C3/002
    • A process for thermally polymerizing a liquid hydrocarbon pitch precursor, or fractionating a crude pitch, by direct contact heating with an immiscible molten fluid, preferably molten metal, is disclosed. A crude pitch, which may contain water, contaminants and/or distillables, or a liquid hydrocarbon feed such as FCC slurry oil, is heated by direct contact heat exchange with molten fluid, preferably a molten metal bath, operating at a temperature of 100 to 6000C. The bath is maintained at a temperature and pressure sufficient to induce thermal polymerization of a pitch precursor and/or vaporize a desired amount of contaminants or volatile material from a crude pitch to produce a pitch product having a desired softening point. New pitch compositions having a high softening point are also produced.
    • 公开了一种通过与不混溶的熔融流体,优选熔融金属的直接接触加热来聚合液体烃沥青前体或分馏粗沥青的方法。 可能含有水,污染物和/或蒸馏物的粗沥青或液体烃进料如FCC浆料油通过与熔融流体(优选熔融金属浴)的直接接触热交换加热,其在100至 6000C。 保持浴的温度和压力足以引起沥青前体的热聚合和/或从粗沥青蒸发所需量的污染物或挥发性物质以产生具有所需软化点的沥青产物。 也产生具有高软化点的新沥青组合物。
    • 6. 发明申请
    • SINGLE STAGE PITCH PROCESS AND PRODUCT
    • 单级螺距工艺和产品
    • WO2017086985A1
    • 2017-05-26
    • PCT/US2015/061745
    • 2015-11-20
    • STONE, Richard
    • MALONE, Donald, P.LEE, Donald, M.
    • C10C3/02C10C1/19
    • C10C3/002C10C1/19C10G9/20C10G9/24C10G9/40C10G2400/02
    • A process and apparatus for making isotropic pitch are disclosed. A long tubular or pipe reactor operates at high velocity and high pressure to convert an aromatic rich liquid feed to pitch within minutes. The reactor may be heated by electric resistance or inductance heating, immersion in a salt bath or molten metal bath, or a conventional fired heater. The reactor effluent is flashed, and isotropic pitch may be recovered from the flash drum with adjustment of softening point by operating the flash drum at lower pressure or with stripping steam addition to the flash drum. Unconverted or partially converted material removed as a vapor from the flash drum may be cooled and condensed to recover this material for recycle. The thermal polymerization process makes such a small amount of gasoline that simple sequential condensation of flash drum vapor may be used to get a recycle gas oil boiling range fraction and subsequently a gasoline boiling range fraction with tolerable loss of gas oil material to the gasoline fraction, tolerable because gasoline production is such a small fraction of the product spectrum. Isotropic petroleum pitch may be made in a single step with an excellent coking value of 50 to 55 wt %. Thermal severity as measured by time and temperature in the tubular reactor is sufficient to convert at least 20 wt % of feed and any recycle material which may be present to isotropic pitch. Pressure is maintained sufficiently high, preferably above 500 psig, to suppress mesophase formation below a predetermined amount, e.g., produce isotropic pitch with less than 0.5 wt % mesophase.
    • 公开了一种制造各向同性沥青的方法和设备。 长管式或管式反应器在高速和高压下运行,在几分钟内将富含芳香烃的液体进料转化为沥青。 可以通过电阻或电感加热,浸入盐浴或熔融金属浴或常规燃烧加热器来加热反应器。 反应器流出物闪蒸,可以从闪蒸罐回收各向同性沥青,通过在较低的压力下操作闪蒸罐或通过向闪蒸罐添加汽提蒸汽来调节软化点。 未转化或部分转化的材料作为蒸汽从闪蒸罐中被除去,可以被冷却并冷凝以回收该材料以供再循环。 热聚合过程产生如此少量的汽油,使得闪蒸罐蒸汽的简单顺序冷凝可以用于获得循环瓦斯油沸程分数,并且随后使用汽油沸程分数,并且瓦斯油材料可容忍地损失到汽油分数中, 因为汽油产量只是产品范围的一小部分,所以可以忍受。 各向同性石油沥青可以在一个单一的步骤中制造,具有50-55wt%的优异结焦值。 通过管式反应器中的时间和温度测量的热严重性足以将至少20重量%的进料和任何可能存在的再循环材料转化为各向同性沥青。 保持足够高的压力,优选高于500psig,以将中间相的形成抑制到低于预定量,例如用低于0.5wt%的中间相产生各向同性沥青。
    • 8. 发明申请
    • PROCEDURE AND INSTALLATION FOR PLASMA HEAT TREATMENT OF A GAS MIXTURE
    • 气体混合物等离子体热处理的程序和安装
    • WO2012150871A1
    • 2012-11-08
    • PCT/RO2011/000018
    • 2011-06-14
    • FRÂNCU, Costin-MarianFRÂNCU, Bogdan-SabinDAN, Lucian-Victor
    • FRÂNCU, Costin-Marian
    • C10K1/00C10C1/19C10J3/84F23G5/027
    • B01D53/005B01J19/088B01J19/2405B01J2219/00006B01J2219/0869B01J2219/0871B01J2219/0883C10B53/00C10J2300/0946C10J2300/165C10K1/002C10K1/122C10K3/003C10K3/008F02C3/28F23G5/085F23G7/061F23G2202/20F23G2204/201Y02E20/12Y02P20/145
    • This invention relates to a process and installation for plasma heat treatment of a gas mixture for its use in thermal and electric power generation plants. According to the invention, the procedure consists in the feeding of a cylindrical reaction room with a gas mixture divided into at least two different flows, tangentially to the direction of a jet of plasma, so as to create a vortex around the jet of plasma, followed by the decrease of the primary gas speed by its expansion in a chamber with increased volume and area; cooling of the primary gas to a temperature of 800... 1000 ° C due to endothermic reactions, solidification and gravity separation from the cooled primary gas of vitrified inorganic particles; the cooling of the primary gas up to 60° C followed by its barbotage into a NaOH solution to remove unwanted chemical elements, resulting in a final gas mixture, and the transport of the final gas mixture thus obtained, to end user to produce heat energy and electricity. The installation corresponding to the procedure according to the invention consists of a reactor (1) formed of a cylindrical room (2) with an intake system (3) to treat gas and a plasma cannon (4), an expansion room (5) provided with a hydraulic lock (6), for the evacuation of vitrified materials and a discharge outlet (7) of the treated gas to a heat exchanger (8) for cooling the resulted gas, a scrubber (9) for chemical treatment of gas, a C0 2 analyzer (10) and a gas-moving system (11) for its delivery to the equipment (12) for producing cogeneration/trigeneration electricity.
    • 本发明涉及一种用于等离子体热处理的气体混合物的方法和装置,用于发电厂和发电厂。 根据本发明,该方法在于将圆柱形反应室与分成至少两个不同流的气体混合物进料,切向于等离子体射流的方向,从而在等离子体射流周围产生涡流, 其次是通过在具有增加的体积和面积的腔室中膨胀来降低初级气体速度; 由于吸热反应,玻璃化无机颗粒的冷却的初级气体的固化和重力分离,将一次气体冷却至800〜1000℃的温度; 将初级气体冷却至60℃,然后将其浸入NaOH溶液中以除去不需要的化学元素,导致最终的气体混合物,并将由此获得的最终气体混合物输送到最终用户以产生热能 和电力。 根据本发明的方法的安装包括由具有用于处理气体的进气系统(3)和具有等离子体炮(4)的圆柱形房间(2)形成的反应器(1),设置有膨胀室(5) 用于将玻璃化材料和玻璃化物质的排出口(7)排出到用于冷却所产生的气体的热交换器(8)的液压锁(6),用于化学处理气体的洗涤器(9) CO 2分析器(10)和用于输送到设备(12)的气体移动系统(11),用于产生热电联产/三次发电。