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    • 2. 发明申请
    • PATTERNED STAMP MANUFACTURING METHOD, PATTERNED STAMP AND IMPRINTING METHOD
    • 图案印花制造方法,图案印花和印花方法
    • WO2016102185A1
    • 2016-06-30
    • PCT/EP2015/079048
    • 2015-12-09
    • KONINKLIJKE PHILIPS N.V.
    • VAN BRAKEL, RemcoVERSCHUUREN, Marcus Antonius
    • G03F7/00
    • G03F7/0002G03F7/0046G03F7/11G03F7/2012G03F7/70241H01L21/0274
    • A method of manufacturing a patterned stamp (100) for patterning a contoured surface (10) is disclosed. The method comprises applying a layer (115) of a pliable material precursor over a master (50) carrying an inverse pattern (52) to form a desired pattern (112) in said layer; curing the pliable material precursor to form a pliable stamp layer (120) comprising said desired pattern; providing an intermediate stamp structure by adhering a porous pliable support layer (130) to the pliable stamp layer; releasing the intermediate stamp structure from the master; forcing the intermediate stamp structure onto the contoured surface with said pattern of features facing the contoured surface; forming the patterned stamp by filling the porous pliable support layer with a filler material to reduce the pliability of the support layer; and removing the patterned stamp from the contoured surface. A corresponding patterned stamp, imprinting method and imprinted article are also disclosed.
    • 公开了一种用于图形化轮廓表面(10)的图案化印模(100)的制造方法。 该方法包括在承载逆图案(52)的主机(50)上施加柔性材料前体层(115)以在所述层中形成期望的图案(112); 固化柔性材料前体以形成包含所述期望图案的柔性印模层(120); 通过将多孔柔性支撑层(130)粘附到柔性印模层上来提供中间印模结构; 从主人释放中间邮票结构; 将中间印章结构强制到具有面向轮廓表面的所述特征图案的轮廓表面上; 通过用填充材料填充多孔柔性支撑层来形成图案化的印模,以降低支撑层的柔韧性; 并从轮廓表面去除图案化的印模。 还公开了相应的图案印记,印记方法和印记制品。
    • 3. 发明申请
    • STEREOLITHOGRAPHIC METHOD AND COMPOSITION
    • 立体成像方法和组合
    • WO2016071811A1
    • 2016-05-12
    • PCT/IB2015/058385
    • 2015-10-30
    • DWS S.R.L.
    • HAGIWARA, TsuneoIKETANI, Satoshi
    • B29C67/00A61K6/08A61C13/00C08B37/16C08G83/00G03F7/00
    • A61C13/0013A61C13/0004A61C13/087A61K6/0052A61K6/083A61K6/09B29C64/135B33Y10/00B33Y70/00C08B37/0015C08F290/062C08F290/068C08G83/007C08L5/16G03F7/0037G03F7/027G03F7/029G03F7/0388G03F7/2012C08L75/14
    • The invention concerns a method for producing a three-dimensional object, in particular an artificial tooth, by stereolithography wherein a liquid photocurable resin composition is cured by light. Said photocurable resin composition contains, based on the total weight of the photocurable resin composition, (i) from 90 to 99.9% by weight of a radical polymerizable organic compound (A) selected from radical polymerizable monomers, oligomers, pre-polymers and mixtures thereof; and (ii) from 0.1 to 10% by weight of a photosensitive radical polymerization initiator (B). Said radical polymerizable organic compound (A) comprises, based on the weight of the radical polymerizable organic compound (A), from 0.5 to 20% by weight of a polyrotaxane compound comprising a polymer chain selected from polyethylene glycol (PEG), polypropylene glycol (PPG), polyethylene glycol - polypropylene glycol (PEG- PPG) block copolymer or polydimethylsiloxane (PDMS), onto which the cyclodextrin ring(s) is/are slipped and wherein the cyclodextrin is derivatized with at least a radical polymerizable group. The invention also concerns a relative liquid photocurable resin composition and articles produced thereby.
    • 本发明涉及通过立体光刻法制造三维物体,特别是人造牙齿的方法,其中液态光固化树脂组合物用光固化。 所述光固化性树脂组合物含有基于光固化性树脂组合物的总重量,(i)90〜99.9重量%的选自自由基聚合性单体,低聚物,预聚物及其混合物的自由基聚合性有机化合物(A) ; 和(ii)0.1〜10重量%的光敏自由基聚合引发剂(B)。 所述自由基聚合性有机化合物(A)以自由基聚合性有机化合物(A)的重量为基准,含有0.5〜20重量%的聚轮烷化合物,该聚轮烷化合物含有选自聚乙二醇(PEG),聚丙二醇 PPG),聚乙二醇 - 聚丙二醇(PEG-PPG)嵌段共聚物或聚二甲基硅氧烷(PDMS),其上环糊精环被滑移,并且其中环糊精被至少可自由基聚合的基团衍生化。 本发明还涉及相对液体光固化性树脂组合物和由此制备的制品。
    • 4. 发明申请
    • LIQUID PLATEMAKING PROCESS
    • 液体平板印刷工艺
    • WO2013176797A1
    • 2013-11-28
    • PCT/US2013/036558
    • 2013-04-15
    • MACDERMID PRINTING SOLUTIONS, LLC
    • VEST, Ryan, W.
    • G03F7/00G03F7/26
    • G03F7/40G03F7/2012
    • A method of making a relief printing element in a liquid photopolymer platemaking process is described. The method comprises the steps of: (a) selectively exposing the liquid photopolymer to actinic radiation through a negative to crosslink and cure portions of the liquid photopolymer; and (b) reclaiming uncured portions of the liquid photopolymer to be reused in the platemaking process. The step of reclaiming uncured portions of the liquid photopolymer comprises (i) heating the printing element to decrease the viscosity of the uncured liquid photopolymer; and (ii) removing uncured liquid photopolymer from the surface of the relief image printing element so that recovery of uncured liquid photopolymer from the surface of the relief image printing element is enhanced.
    • 描述了在液体光聚合物制版工艺中制备凸版印刷元件的方法。 该方法包括以下步骤:(a)通过负极将液体光聚合物选择性地暴露于光化辐射以交联和固化液态光聚合物的一部分; 和(b)回收在制版过程中待再利用的液体光聚合物的未固化部分。 回收液态光聚合物的未固化部分的步骤包括(i)加热印刷元件以降低未固化的液体光聚合物的粘度; 和(ii)从浮雕图像印刷元件的表面除去未固化的液体光聚合物,从而提高了从浮雕图像打印元件的表面回收未固化的液体光聚合物。
    • 5. 发明申请
    • METHOD OF PRODUCING A RELIEF IMAGE FROM A LIQUID PHOTOPOLYMER RESIN
    • 从液体光催化剂树脂生产缓冲图像的方法
    • WO2011152922A1
    • 2011-12-08
    • PCT/US2011/031343
    • 2011-04-06
    • MACDERMID PRINTING SOLUTIONS LLCVEST, RyanJOHNSON, Deborah
    • VEST, RyanJOHNSON, Deborah
    • G03F7/26
    • G03F7/2012G03F7/0017Y10T428/12389Y10T428/24612
    • A method of producing a relief image from a liquid photopolymerizable resin, said method comprising the steps of; a) placing a coverfilm onto an exposure glass; b) casting a liquid photopolymerizable resin layer onto the coverfilm; c) laminating a substrate to a backside of the liquid photopolymerizable resin layer as the liquid photopolymerizable resin layer is being cast onto the coverfilm; d) placing an image or film negative on top of the substrate; and e) exposing the liquid photopolymerizable resin layer through the image or film negative from the backside of the liquid photopolymerizable resin layer to selectively crosslink and cure the photopolymerizable resin layer and form a cured relief image, wherein said depth of the cured relief image is less than the height of the cast liquid photopolymerizable resin.
    • 一种从液体光聚合树脂制备浮雕图像的方法,所述方法包括以下步骤: a)将覆盖膜放置在曝光玻璃上; b)将液体光聚合树脂层浇铸到覆盖膜上; c)当液态光聚合性树脂层被浇铸到覆盖膜上时,将基材层压到液体光聚合树脂层的背面; d)将图像或薄膜负片放置在基板的顶部; 和e)使液体光聚合性树脂层从液态光聚合性树脂层的背面通过图像或薄膜负片曝光,以选择性地交联并固化光聚合树脂层并形成固化的浮雕图像,其中固化浮雕图像的深度较小 比铸液光聚合树脂的高度高。
    • 6. 发明申请
    • METHODS AND APPARATUS FOR USE IN PHOTOPOLYMER PLATE MANUFACTURE
    • 用于光刻胶板制造的方法和装置
    • WO2003014832A1
    • 2003-02-20
    • PCT/GB2002/003697
    • 2002-08-09
    • HOLT, Paul, MayoDINCHEVA, Maria, Peneva
    • HOLT, Paul, MayoDINCHEVA, Maria, Peneva
    • G03F7/12
    • G03F7/2024G03F7/0012G03F7/12G03F7/16G03F7/2012G03F7/2032G03F7/38G03F7/40
    • The invention provides a photopolymer package for use in making a hand stamp plate, the package consisting of a sachet containing a photocurable liquid polymer, the walls of the sachet being formed of material capable of being released from the cured photopolymer. Methods for the formation of the package and the hand stamp plate are also provided. The invention eliminates the requirement for the use of a backing layer in the package and thereby offers significant advantages over the prior art in terms of cost and efficiency. The invention describes how that sachet can be inserted in a holding device to expose it to UV radiation to produce the printed surface. The invention describes a novel method for spraying the sachet with a liquid to enable it to be dry post-exposed in a new type of exposure unit. It describes how this exposure unit benefits from the simplicity of the sachet concept to require no movable upper lid. This unit combines the post exposure process with the exposure process without the requirement for a water bath.
    • 本发明提供一种用于制造手印板的光聚合物包装,该包装由含有可光固化的液体聚合物的小袋组成,小袋的壁由能够从固化的光聚合物中释放的材料形成。 还提供了形成包装和手印板的方法。 本发明消除了在封装中使用背衬层的要求,从而在成本和效率方面优于现有技术。 本发明描述了该小袋可以如何插入保持装置以将其暴露于UV辐射以产生印刷表面。 本发明描述了一种用液体喷洒小袋的新方法,以使其能够在新型曝光单元中暴露后干燥。 它描述了这种曝光单元如何从简单的小袋概念中获益,不需要可移动的上盖。 该单元将曝光后处理与曝光过程相结合,而不需要水浴。