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    • 2. 发明申请
    • DYE DIFFUSION THERMAL TRANSFER PRINTING
    • DYE扩散热转印
    • WO1995028287A1
    • 1995-10-26
    • PCT/GB1995000674
    • 1995-03-27
    • ZENECA LIMITEDBRADBURY, Roy
    • ZENECA LIMITED
    • B41M05/38
    • B41M5/388C09B33/06
    • A thermal transfer sheet comprising a substrate having a coating comprising a dye of formula (1), wherein Y is -H, alkyl, alkoxy, -NHCOalkyl, NHCOaryl, -NHSO2alkyl or -NHSO2aryl; ring A is unsubstituted apart from the -N=N-, -Y and -N and R each independently is alkyl; R is -H, alkyl, aryl, -SO2alkyl, -Salkyl, -Saryl, halogen, pyridyl or R O(CH2)n- in which R is alkyl, acyl, aryl and n is from 1 to 10; R is -CN, -NO2, -SCN or -COOalkyl; and R is a group of formula (2), in which: Z is -H, alkyl, alkoxy, -NHCOalkyl, -NHCOaryl, -NHSO2alkyl or -NHSO2aryl; ring B is unsubstituted apart from the -N=N-, -Z and -N and R each independently is -H or alkyl; R independently is any of the groups defined for R ; R independently is any of the groups defined for R ; L is bridging group; or R is alkyl, provided that when R is alkyl R is pyridyl or R O(CH)n-.
    • 一种热转印片,其包含具有包含式(1)染料的涂层的基底,其中Y为-H,烷基,烷氧基,-NHCO烷基,NHCO芳基,-NHSO2烷基或-NHSO2芳基; 除了-N = N-,-Y和-N <基团之外,环A是未取代的,或者可以被1至3个取代基取代; R 1和R 2各自独立地是烷基; R 3是-H,烷基,芳基,-SO 2烷基,-S烷基, - 芳基,卤素,吡啶基或R 6 O(CH 2)n - ,其中R 6是烷基,酰基,芳基和n是 从1到10; R 4是-CN,-NO 2,-SCN或-COO烷基; 和R 5是式(2)的基团,其中:Z是-H,烷基,烷氧基,-NHCO烷基,-NHCO芳基,-NHSO 2烷基或-NHSO 2芳基; 除了-N = N-,-Z和-N <基团之外,环B是未取代的,或者可以被1至3个取代基取代; R 7和R 8各自独立地为-H或烷基; R 9独立地是为R 4定义的任何基团; R 10独立地是为R 3定义的任何基团; L为桥接基团; 或R 5为烷基,条件是当R 5为烷基时,R 3为吡啶基或R 6 O(CH)n - 。
    • 4. 发明申请
    • AZO DYES
    • WO2013087400A2
    • 2013-06-20
    • PCT/EP2012073572
    • 2012-11-26
    • HUNTSMAN ADV MAT SWITZERLAND
    • MUELLER ALEXANDERHILDEBRAND RAINERDALLE-NOGARE SIRO
    • C09B33/06C09B67/00D06P1/06D06P3/06D06P3/24D06P3/32
    • D06P1/06C09B33/06C09B67/0041C09B67/0046D06P1/0096D06P1/02
    • The present invention relates to dyes of formula (1), wherein each of the residues D1 and D2 represents a radical of formula (2), wherein Ar1 represents the tetravalent radical of a carbocylic or heterocyclic aromatic compound, R1, R2 and R3 are each independently of the other hydrogen, C1-C12alkyl, C1-C12alkoxy, halogen, -OH, -CN, -NO2, -CF3, -SO3H, -NHCOR4, -COOR5, -CONR6R7, -SO2NR8R9, -NR10SO2R11, -SO2R13- or -ZCH2CH2Q, wherein Z is -O-, -SO2-, -NR12-, -CONH- or -NHCO-, Q represents -OH, C1-C12alkyl, -SO2R13-, -NHR14-, -OCH2CH2OH, -SO2CH2CH2OH or -NHCH2CH2OH, R4 is C1-C12alkyl, R5, R6, R7, R8, R9, R10, R12, R13 and R14 are each independently of the others hydrogen or C1-C12alkyl, and R11 is C1-C122alkyl, with the proviso that at least one of the residues D1 and D2 is a radical of formula (2) wherein R3 is -COOR5, -SO2NR8R9, -SO2R13- or -ZCH2CH2Q, dichromatic and trichromatic mixtures containing these dyes and the use of these dyes for dyeing or printing hydroxyl group-containing or nitrogen-containing fibre materials.
    • 本发明涉及式(1)的染料,其中残基D1和D2各自表示式(2)的基团,其中Ar1表示碳环或杂环芳族化合物的四价基团,R 1,R 2和R 3各自为 独立于其它氢,C1-C12烷基,C1-C12烷氧基,卤素,-OH,-CN,-NO2,-CF3,-SO3H,-NHCOR4,-COOR5,-CONR6R7,-SO2NR8R9,-NR10SO2R11,-SO2R13-或 -ZCH 2 CH 2 Q,其中Z是-O - , - SO 2 - , - NR 12 - , - CONH-或-NHCO-,Q表示-OH,C 1 -C 12烷基,-SO 2 R 13 - , - NHR 14 - , - OCH 2 CH 2 OH,-SO 2 CH 2 CH 2 OH或 - NHCH 2 CH 2 OH,R 4是C 1 -C 12烷基,R 5,R 6,R 7,R 8,R 9,R 10,R 12,R 13和R 14各自独立地是氢或C 1 -C 12烷基,R 11是C 1 -C 12烷基,条件是至少 残基D1和D2之一是式(2)的基团,其中R3是-COOR5,-SO2NR8R9,-SO2R13-或-ZCH2CH2Q,含有这些染料的二色和三色混合物,以及这些染料用于染色或印刷羟基的用途 包含或 含氮纤维材料。