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1. 发明申请

WO1993009147A1 HIGH ACTIVITY POLYETHYLENE CATALYSTS PREPARED WITH ALKOXYSILANE REAGENTS 审中-公开
标题翻译：用烷基化试剂制备的高活性聚乙烯催化剂
公开(公告)号：WO1993009147A1
公开(公告)日：1993-05-13
申请号：PCT/US1992009526
申请日：1992-11-05
申请人： MOBIL OIL CORPORATION
发明人： MOBIL OIL CORPORATION , NOWLIN, Thomas, Edward , MINK, Robert, I.
IPC分类号： C08F04/44
CPC分类号： C08F10/02 , B01J31/0274 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/38 , C08F210/16 , Y02P20/52 , C08F4/6365 , C08F4/6565
摘要： There is disclosed a highly active catalyst composition for polymerizing alpha-olefins prepared by treating a support with an organomagnesium composition and contacting the thus formed solid support, containing magnesium, with a silane compound of the empirical formula R xSiR y wherein Si is silicon atom; x is 1, 2, 3, or 4 and y is 0, 1, 2, or 3, provided that x+y is 4; R is Rw-O- wherein O is oxygen and Rw is hydrocarbyl of 1 to 10 carbon atoms; and R is halogen or hydrocarbyl of 1 to 10 carbon atoms, or hydrogen and a transition metal compound, e.g., a tetravalent titanium compound. This catalyst is particularly useful for the production of linear low density polyethylene polymers. Also disclosed are methods of preparing polymers with the catalyst composition and the resulting polymers.
摘要翻译：公开了一种用于聚合α-烯烃的高活性催化剂组合物，其通过用有机镁组合物处理载体并使由此形成的含镁的固体载体与经验式R 1 x SiR 2 y的硅烷化合物接触而制备其中Si是硅原子; x为1,2,3或4，y为0,1,2或3，条件是x + y为4; R 1是Rw-O-，其中O是氧，R w是1至10个碳原子的烃基; 和R 2是卤素或1-10个碳原子的烃基，或氢和过渡金属化合物，例如四价钛化合物。该催化剂特别可用于生产线性低密度聚乙烯聚合物。还公开了使用催化剂组合物和所得聚合物制备聚合物的方法。

2. 发明申请

WO02038620A1 METHOD FOR PRODUCING A CATALYST FOR HOMO- OR CO-POLYMERIZATION OF ETHYLENE 审中-公开
标题翻译：乙烯共聚合催化剂生产方法
公开(公告)号：WO02038620A1
公开(公告)日：2002-05-16
申请号：PCT/KR2001/001905
申请日：2001-11-09
IPC分类号： C08F4/656 , C08F4/64 , C08F10/00 , C08F10/02 , C08F110/02
CPC分类号： C08F10/02 , C08F110/02 , C08F4/651 , C08F4/6365 , C08F4/6493 , C08F4/6465 , C08F2500/18 , C08F2500/12
摘要： The present invention provides a method for producing a new catalyst of high catalytic activity and superior catalyst morphology for homo- or co-polymerization of ethylene, or more particularly a method for producing a titanium solid complex catalyst supported on a carrier containing magnesium, wherein said catalyst of high polymerization activity is capable of producing polymers of high bulk density.
摘要翻译：本发明提供了一种制备催化活性高的催化剂和乙烯均聚或共聚的优异催化剂形态的方法，更具体地说，涉及一种负载在含镁载体上的钛固体络合物催化剂的制备方法，其中所述具有高聚合活性的催化剂能够生产高堆积密度的聚合物。

3. 发明申请

WO00012573A1 PROPYLENE RANDOM COPOLYMER, PROPYLENE RESIN COMPOSITION, FILM OF THESE, AND MULTILAYERED PROPYLENE RESIN LAMINATE 审中-公开
标题翻译：丙烯随机共聚物，丙烯树脂组合物，这些薄膜和多层丙烯树脂层压板
公开(公告)号：WO00012573A1
公开(公告)日：2000-03-09
申请号：PCT/JP1999/004657
申请日：1999-08-30
IPC分类号： B32B27/32 , C08F10/06 , C08F210/06 , C08F210/16 , C08J5/18 , C08L23/10 , C08L23/14
CPC分类号： C08J5/18 , B32B27/32 , C08F10/06 , C08F210/06 , C08F210/16 , C08J2323/14 , C08L23/10 , C08L23/14 , C08L2205/02 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , C08F4/6541 , C08F4/6365 , C08F4/6492 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08F2500/03 , C08F2500/26 , C08F2500/20 , C08F2500/15
摘要： (1) A propylene/ethylene random copolymer having specific properties; (2) a resin composition comprising the random copolymer and a nucleator; (3) a resin composition comprising the random copolymer and a propylene polymer; a film of any of these; and a multilayered propylene resin laminate which has an outermost layer made of a specific propylene polymer, has excellent heat sealability, and combines slipping properties with antiblocking properties.
摘要翻译：（1）具有特定性质的丙烯/乙烯无规共聚物; （2）包含无规共聚物和成核剂的树脂组合物; （3）包含无规共聚物和丙烯聚合物的树脂组合物; 任何一部电影; 和具有由特定的丙烯聚合物构成的最外层的多层丙烯树脂层压体，具有优异的热封性，并且具有防滑性能的滑动性。

4. 发明申请

WO99004901A1 HIGH ACTIVITY CATALYST PREPARED WITH ALKOXYSILANES 审中-公开
标题翻译：用烷氧基硅烷制备的高活性催化剂
公开(公告)号：WO99004901A1
公开(公告)日：1999-02-04
申请号：PCT/US1998/014242
申请日：1998-07-09
IPC分类号： C08F4/658 , B01J21/08 , B01J31/02 , B01J31/12 , B01J31/14 , C08F4/02 , C08F4/58 , C08F4/64 , C08F10/00 , C08F10/02 , C08F210/16
CPC分类号： B01J31/143 , B01J21/08 , B01J31/0274 , B01J31/122 , B01J31/128 , C08F10/00 , C08F10/02 , C08F210/16 , Y02P20/52 , C08F4/6565 , C08F210/14 , C08F2500/12 , C08F2500/03 , C08F4/6365
摘要： An ethylene-alpha-olefin copolymerization catalyst is prepared by impregnating a silica calcined at elevated temperature sequentially with an organomagnesium compound such as dialkylmagnesium compound, a silane compound which is free of hydroxyl groups, such as tetraethyl orthosilicate. A transition metal component such as titanium tetrachloride is then incorporated into the support. Unexpectedly, the calcination temperature of the silica used to prepare the catalyst precursors has a strong influence on polymer product properties. By increasing the calcination temperature of the silica from 600 DEG to 700 DEG C or higher temperatures, a catalyst precursor when activated produces ethylene/1-hexene copolymers with narrower molecular weight distributions (MWD) as manifested by a decrease of resin MFR values of SIMILAR 3-4 units. Activation of this catalyst precursor with a trialkylaluminum compound results in a catalyst system which is effective for the production of ethylene copolymers.
摘要翻译：乙烯-α-烯烃共聚催化剂是通过用有机镁化合物如二烷基镁化合物，不含羟基的硅烷化合物如原硅酸四乙酯依次浸渍在高温下煅烧的二氧化硅来制备的。然后将过渡金属组分如四氯化钛加入到载体中。出乎意料的是，用于制备催化剂前体的二氧化硅的煅烧温度对聚合物产物性能有很大的影响。通过将二氧化硅的煅烧温度从600℃升高至700℃或更高的温度，当活化时催化剂前体产生具有较窄分子量分布（MWD）的乙烯/ 1-己烯共聚物，其表现为SIMILAR的树脂MFR值的降低 3-4个单位。这种催化剂前体与三烷基铝化合物的活化导致催化剂体系对生产乙烯共聚物是有效的。

5. 发明申请

WO01018075A1 PROCESS FOR PRODUCING alpha -OLEFIN POLYMER 审中-公开
标题翻译：生产α-烯烃聚合物的方法
公开(公告)号：WO01018075A1
公开(公告)日：2001-03-15
申请号：PCT/JP1999/004867
申请日：1999-09-08
IPC分类号： C08F4/651 , C08F4/654 , C08F4/658 , C08F10/06 , C08F110/06 , C08F10/00
CPC分类号： C08F10/06 , C08F110/06 , C08F4/6465 , C08F4/6365 , C08F2500/12
摘要： A process for producing an alpha -olefin polymer having excellent moldability, i.e., a heightened ME. The process comprises polymerizing an alpha -olefin using a Ziegler-Natta catalyst, characterized in that the polymerization is conducted at 92 DEG C or higher under such conditions that the hydrogen/ alpha -olefin molar ratio during polymerization and the melt flow rate of the obtained alpha -olefin polymer as measured at 230 DEG C under a load of 2.16 kg (MFR, g/10 min) satisfy the following general formula (I): log(MFR)>/=1.5xlog(hydrogen/ alpha -olefin)+4.5.
摘要翻译：一种生产具有优异成型性的α-烯烃聚合物的方法，即增加的ME。该方法包括使用齐格勒 - 纳塔催化剂聚合α-烯烃，其特征在于在聚合期间的氢/α-烯烃摩尔比和所得到的熔体流动速率的条件下聚合在92℃或更高温度下进行在230℃，2.16kg（MFR，g / 10min）的负荷下测定的α-烯烃聚合物满足以下通式（I）：log（MFR）> / = 1.5xlog（氢/α-烯烃）+ 4.5。

6. 发明申请

WO00026259A1 COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：WO00026259A1
公开(公告)日：2000-05-11
申请号：PCT/EP1999/008018
申请日：1999-10-22
IPC分类号： C08F4/651 , C07C69/38 , C07C69/63 , C08F4/654 , C08F4/658 , C08F10/00 , C08F10/06
CPC分类号： C08F10/06 , C07C69/63 , C08F4/6365 , C08F4/651
摘要： The present invention relates to catalyst components for the polymerization of olefins, and to the catalyst obtained therefrom, particularly suitable for the stereospecific polymerization of olefins, comprising Ti, Mg, halogen and an electron donor compound selected from heteroatom containing esters of malonic acids (heteroatom containing malonates). Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及用于烯烃聚合的催化剂组分和由其获得的催化剂，特别适用于包含Ti，Mg，卤素和选自含杂原子的丙二酸酯（杂原子）的电子给体化合物的烯烃的立体有择聚合含有丙二酸酯）。当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

7. 发明申请

WO00020473A1 PROPYLENE-BASED RANDOM COPOLYMERS AND PROPYLENE-BASED RESIN COMPOSITIONS, FILMS THEREOF AND PROPYLENE-BASED RESIN LAMINATES 审中-公开
标题翻译：基于丙烯的随机共聚物和基于丙烯的树脂组合物，其膜和基于丙烯的树脂层压板
公开(公告)号：WO00020473A1
公开(公告)日：2000-04-13
申请号：PCT/JP1999/005478
申请日：1999-10-05
IPC分类号： B32B27/32 , C08F10/06 , C08F210/06 , C08F210/16 , C08J5/18 , C08L23/10 , C08L23/14
CPC分类号： C08J5/18 , B32B27/32 , C08F10/06 , C08F210/06 , C08F210/16 , C08J2323/14 , C08L23/10 , C08L23/14 , C08L2205/02 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , C08F4/6492 , C08F4/6365 , C08F4/6541 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08F2500/03 , C08F2500/26 , C08F2500/20 , C08F2500/15
摘要： (1) Random copolymers of propylene, ethylene and 1-butene having specific properties; (2) resin compositions comprising random copolymers of propylene, ethylene and 1-butene having specific properties and a nucleating agent; (3) resin compositions of random copolymers of propylene, ethylene and 1-butene having specific properties and a propylene-based polymer; films with the use thereof; and multilayered laminates of propylene-based resins having a propylene-based polymer as the outermost layer which achieve excellent heat-sealing properties and have favorable stripping and antiblocking properties.
摘要翻译：（1）具有特定性质的丙烯，乙烯和1-丁烯的无规共聚物; （2）包含具有特定性质的丙烯，乙烯和1-丁烯的无规共聚物和成核剂的树脂组合物; （3）具有特定性质的丙烯，乙烯和1-丁烯的无规共聚物的树脂组合物和丙烯类聚合物; 使用电影; 以及具有丙烯类聚合物作为最外层的丙烯类树脂的多层层压体，其具有优异的热封性能并且具有良好的剥离和防粘连性能。

8. 发明申请

WO1988005056A1 CATALYST COMPONENT FOR ZIEGLER-NATTA CATALYSTS AND METHOD FOR POLYMERIZING 'alpha'-OLEFINS 审中-公开
标题翻译： ZIEGLER-NATTA催化剂的催化组分和聚合α-烯烃的方法
公开(公告)号：WO1988005056A1
公开(公告)日：1988-07-14
申请号：PCT/FI1987000167
申请日：1987-12-10
申请人： NESTE OY , LUCIANI, Luciano , LÖFGREN, Barbro
发明人： NESTE OY
IPC分类号： C08F04/64
CPC分类号： C08F10/04 , C08F4/6365
摘要： A catalyst component for use in unsupported Ziegler-Natta catalyst compositions for the polymerization of alpha-olefins having at least 3 carbon atoms. The catalyst component is obtained by treating an organomagnesium compound without chlorine with solid silane compounds containing one or two hydroxyl groups and then with titanium halide compounds. The treatment of organomagnesium compound is carried out by first treating with the solid silane compound in a temperature of 60-110°C and thereafter with titanium halide compound optionally together with an electron donor compound. An unsupported catalyst composition, which comprises the above mentioned catalyst component together with a cocatalyst and optionally an external donor compound and a process for polymerization of alpha-olefins containing at least 3 carbon atoms with the use of the catalyst component are also claimed.

9. 发明申请

WO01044313A1 PREPARATION METHOD OF SUPPORTED CATALYST FOR POLYMERIZATION OF ETHYLENE AND CO-POLYMERIZATION OF ETHYLENE/ALPHA-OLEFIN 审中-公开
标题翻译：用于乙烯聚合和乙烯/丙烯酸共聚合的支持催化剂的制备方法
公开(公告)号：WO01044313A1
公开(公告)日：2001-06-21
申请号：PCT/KR2000/001456
申请日：2000-12-13
IPC分类号： C08F4/654 , C08F4/68 , C08F10/02
CPC分类号： C08F10/02 , C08F4/6367 , C08F4/6365
摘要： A preparation method of catalyst for polymerization of ethylene and co-polymerization of ethylene and alpha-olefin is provided. The preparation method of catalyst of the present invention comprises a) producing a carrier by reacting organic magnesium compound of MgPh2.nMgCl2.mR2O (wherein Ph=phenyl, n=0.37 SIMILAR 0.7, m>/=1, R2O=ether) with organic chlorine compound and silicon compound at -20 SIMILAR 80 DEG C, wherein the molar ratio of organic chlorine compound to Mg is 0.5 or more, and the molar ratio of silicon compound to Mg is 0.001 or more; b) treating said magnesium containing carrier with titanium compound.
摘要翻译：提供了一种用于乙烯聚合和乙烯与α-烯烃共聚的催化剂的制备方法。本发明催化剂的制备方法包括：a）通过使MgPh2.nMgCl2.mR2O（其中Ph =苯基，n = 0.37〜0.7，m≥1，R2O =乙醚）的有机镁化合物与有机物氯化合物和硅化合物，其中有机氯化合物与Mg的摩尔比为0.5以上，硅化合物与Mg的摩尔比为0.001以上; b）用钛化合物处理所述含镁载体。

10. 发明申请

WO01021676A1 CATALYST FOR POLYETHYLENE GIVING AN IMPROVED SHORT CHAIN BRANCHING DISTRIBUTION 审中-公开
标题翻译：聚乙烯催化剂改善短链分配
公开(公告)号：WO01021676A1
公开(公告)日：2001-03-29
申请号：PCT/GB2000/003536
申请日：2000-09-14
IPC分类号： B01J31/02 , B01J31/12 , B01J31/14 , B01J37/02 , B01J37/06 , C08F4/654 , C08F4/656 , C08F4/658 , C08F10/02
CPC分类号： B01J31/143 , B01J31/0274 , B01J31/122 , B01J37/0203 , B01J37/0205 , C08F10/02 , C08F4/6365
摘要： The present invention provides a catalyst composition for polymerising ethylene with a superior activity, productivity, and giving, in particular, copolymers with an improved narrower short chain branching distribution, and especially an improved cling development in PIB formulated films. Said catalyst composition for the (co-)polymerisation of ethylene, optionally with an alpha olefin of 3 to 10 carbon atoms, comprises a catalyst precursor and an organoaluminium cocatalyst, wherein the catalyst precursor comprises i) a catalyst carrier material, having from 0.3 to 1.2 mmoles of OH groups per gram of catalyst carrier, more preferably from 0.3 to 0.8, ii) a dialkylmagnesium compound of the formula RMgR , where R and R are the same or different C2-C12 alkyl groups, in an amount comprised between 1.1 and 2.4 mmoles of dialkylmagnesium per gram of catalyst carrier, preferably between 1.3 and 2.4, more preferably between 1.3 and 1.8, iii) a tetraalkyl orthosilicate, in which the alkyl group contains from 2 to 6 carbon atoms, in an amount comprised between 0.4 and 1.6 mmoles of tetraalkyl orthosilicate per gram of catalyst carrier, more preferably between 0.6 and 1.3, and iv) a titanium compound in an amount comprised between 1.3 to 2.4 mmoles per gram of catalyst carrier, more preferably between 1.3 and 1.8.
摘要翻译：本发明提供了一种聚合乙烯的催化剂组合物，其具有优异的活性，生产率，特别是具有改进的较窄的短链支化分布的共聚物，特别是PIB配制的膜中的改进的粘附显影。用于乙烯（任选与3-10个碳原子的α-烯烃）（共））聚合的所述催化剂组合物包括催化剂前体和有机铝助催化剂，其中催化剂前体包括i）催化剂载体材料，其具有0.3至每克催化剂载体为1.2毫摩尔OH基，更优选为0.3至0.8，ii）式RMgR 1的二烷基镁化合物，其中R和R 1为相同或不同的C 2 -C 12烷基，每克催化剂载体包含1.1-2.4毫摩尔二烷基镁，优选在1.3和2.4之间，更优选在1.3和1.8之间的量，iii）其中烷基含有2至6个碳原子的原硅酸四烷基酯，每克催化剂载体含有0.4-1.6毫摩尔原硅酸四烷基酯，更优选在0.6至1.3之间，和iv）钛化合物，其量为每克催化剂载体1.3-2.4毫摩尔 r，更优选在1.3和1.8之间。

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