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1. 发明申请

WO2010065462A3 TOLUENE AND STYRENE DERIVED TELOMER DISTRIBUTIONS AND BROMINATED FLAME RETARDANTS PRODUCED THEREFROM 审中-公开
标题翻译：甲苯和苯乙烯衍生的端粒分布和由此产生的溴化阻燃剂
公开(公告)号：WO2010065462A3
公开(公告)日：2010-07-29
申请号：PCT/US2009066121
申请日：2009-11-30
申请人： ALBEMARLE CORP , LAYMAN WILLIAM J , KOLICH CHARLES H , MACK ARTHUR G , ANDERSON STEVEN A , MCCARNEY JONATHAN P , WANG JUNZUO
发明人： LAYMAN WILLIAM J , KOLICH CHARLES H , MACK ARTHUR G , ANDERSON STEVEN A , MCCARNEY JONATHAN P , WANG JUNZUO
IPC分类号： C07C15/12 , C07C25/22 , C08K5/03
CPC分类号： C09K21/12 , C07C2/72 , C07C15/12 , C07C17/12 , C07C25/18 , C08L25/18
摘要： This invention relates to novel and useful toluene and styrene derived telomer distributions, such distributions being desirable substrates for the preparation of brominated flame retardants.
摘要翻译：本发明涉及新的和有用的甲苯和苯乙烯衍生的调聚物分布，这种分布是制备溴化阻燃剂的理想基质。

2. 发明申请

WO01055061A1 ALKYLATION PROCESS 审中-公开
标题翻译：烷基化方法
公开(公告)号：WO01055061A1
公开(公告)日：2001-08-02
申请号：PCT/FI2001/000085
申请日：2001-01-29
IPC分类号： B01J21/16 , B01J37/30 , C07B37/02 , C07B61/00 , C07C2/66 , C07C2/72 , C07C15/02 , C07C45/69 , C07C2/58 , C01B33/40
CPC分类号： C07C45/69 , B01J21/16 , C07B37/02 , C07C2/72 , C07C2521/16 , C07C15/02 , C07C15/44
摘要： This invention concerns an alkylation process. According to the process a side-chain of a substituted aromatic compound is alkylated by reacting the aromatic compound with an alkylating agent in the presence of a catalyst. According to the invention, the catalyst comprises a restructured smectite clay to which basic ions are incorporated by ion-exchange.
摘要翻译：本发明涉及烷基化方法。根据该方法，通过在催化剂存在下使芳族化合物与烷基化剂反应，将取代的芳族化合物的侧链烷基化。根据本发明，催化剂包括通过离子交换引入碱性离子的重组蒙脱石粘土。

3. 发明申请

WO1991016284A1 PROCESS FOR PRODUCING ALKENYLBENZENE AND DERIVATIVE THEREOF 审中-公开
标题翻译：生产亚苄基苯及其衍生物的方法
公开(公告)号：WO1991016284A1
公开(公告)日：1991-10-31
申请号：PCT/JP1991000542
申请日：1991-04-23
申请人： TEIJIN LIMITED , SHIMADA, Keizo , SUMITANI, Koji , ITOH, Seiji
发明人： TEIJIN LIMITED
IPC分类号： C07C02/72
CPC分类号： B01J23/04 , C07C2/72 , C07C2523/04 , C07C15/44
摘要： A process for producing efficiently alkenylbenzene, which comprises reacting alkylbenzene with 1,3-butadiene in the presence of a catalyst prepared by the dispersion treatment of an alkali metal with an inorganic potassium salt in the substantial absence of oxygen and water.
摘要翻译：一种有效生产烯基苯的方法，其包括在基本上不存在氧和水的情况下通过碱金属与无机钾盐的分散处理制备的催化剂的存在下使烷基苯与1,3-丁二烯反应。

4. 发明申请

WO2010065462A2 TOLUENE AND STYRENE DERIVED TELOMER DISTRIBUTIONS AND BROMINATED FLAME RETARDANTS PRODUCED THEREFROM 审中-公开
标题翻译： TOLUENE和STYRENE衍生的TELOMER分布和生产的火焰阻燃剂
公开(公告)号：WO2010065462A2
公开(公告)日：2010-06-10
申请号：PCT/US2009/066121
申请日：2009-11-30
申请人： ALBEMARLE CORPORATION , LAYMAN, William, J. , KOLICH, Charles, H. , MACK, Arthur, G. , ANDERSON, Steven, A. , MCCARNEY, Jonathan, P. , WANG, Junzuo
发明人： LAYMAN, William, J. , KOLICH, Charles, H. , MACK, Arthur, G. , ANDERSON, Steven, A. , MCCARNEY, Jonathan, P. , WANG, Junzuo
IPC分类号： C07C15/12 , C07C25/22 , C08K5/03
CPC分类号： C09K21/12 , C07C2/72 , C07C15/12 , C07C17/12 , C07C25/18 , C08L25/18
摘要： This invention relates to novel and useful toluene and styrene derived telomer distributions, such distributions being desirable substrates for the preparation of brominated flame retardants.
摘要翻译：本发明涉及新型和有用的甲苯和苯乙烯衍生的调聚物分布，这种分布是制备溴化阻燃剂的理想底物。

5. 发明申请

WO02014241A3 METHOD FOR SIDE CHAIN ALKYLATION OR ALKENYLATION 审中-公开
标题翻译：工艺侧OR -ALKENYLIERUNG
公开(公告)号：WO02014241A3
公开(公告)日：2002-06-27
申请号：PCT/EP2001/009296
申请日：2001-08-10
IPC分类号： B01J23/04 , C07B61/00 , C07C2/72 , C07C7/04 , C07C7/20 , C07C15/107 , C07C2/54
CPC分类号： B01J23/04 , C07C2/72 , C07C2523/04 , C07C2527/08 , C07C2527/232 , Y10S585/95
摘要： The invention relates to a method for reducing the formation of polymers during the side chain alkylation or side chain alkenylation of alkylaromatic compounds by reacting olefins or diolefins in the presence of an alkali metal catalyst; and the ensuing distillation for preparing the alkylated or alkenylated compound. The alkali metal in the catalyst is situated on an inorganic carrier, and the catalyst is mechanically separated from the reaction mixture after the reaction and before distillation.
摘要翻译：在用于通过与在碱金属催化剂的存在下烯烃或二烯烃，和随后的蒸馏获得烷基化或烯基化化合物反应减少侧链或侧烷基芳族化合物在聚合物的形成方法，所述碱金属是存在于催化剂中的无机载体上和催化剂在反应后分离并从反应混合物机械蒸馏之前。

6. 发明申请

WO1988004955A1 CATALYST SYSTEM AND PROCEDURE FOR SELECTIVE ALKYLATION OF TOLUENE 审中-公开
标题翻译：催化剂体系和选择性烷基化方法
公开(公告)号：WO1988004955A1
公开(公告)日：1988-07-14
申请号：PCT/FI1987000174
申请日：1987-12-29
申请人： NESTE OY , KNUUTTILA, Pekka , LAHTINEN, Leila , HALME, Erkki , KOSKIMIES, Salme
发明人： NESTE OY
IPC分类号： B01J23/04
CPC分类号： B01J27/232 , B01J23/10 , B01J23/78 , C07C2/72 , C07C2523/04 , C07C2523/10 , C07C2527/232 , C07C15/02
摘要： Catalyst system for selective alkylation of toluene with propylene. The catalyst system contains metallic sodium on a K2CO3 carrier and transition metal oxide, which advantageously is CeO2, Dy2O3 or Fe2O3, as promotor. The invention also concerns a procedure for selective alkylation of toluene with propylene in the presence of a catalyst system.
摘要翻译：用丙烯选择性烷基化甲苯的催化剂体系。催化剂体系在K2CO3载体和过渡金属氧化物上含有金属钠，有利的是CeO 2，Dy 2 O 3或Fe 2 O 3作为助催化剂。本发明还涉及在催化剂体系存在下用丙烯选择性烷基化甲苯的方法。

7. 发明申请

WO2012061272A3 SYNTHESIS OF A C5 OR C6 CONJUGATED LINEAR DIENE. 审中-公开
标题翻译： C5或C6共轭线性二烯的合成。
公开(公告)号：WO2012061272A3
公开(公告)日：2012-07-12
申请号：PCT/US2011058538
申请日：2011-10-31
申请人： UNIV NORTH CAROLINA , BROOKHART MAURICE , FINDLATER MICHAEL , GUIRONNET DAMIEN , LYONS THOMAS WARREN
发明人： BROOKHART MAURICE , FINDLATER MICHAEL , GUIRONNET DAMIEN , LYONS THOMAS WARREN
IPC分类号： C07C5/42 , C07C11/173 , C07C13/20 , C07C15/06 , C07C15/08
CPC分类号： C07C2/72 , C07C2/52 , C07C5/321 , C07C5/42 , C07C5/52 , C07C2101/16 , C07C2531/22 , C07C2601/16 , C07C11/12 , C07C13/20 , C07C15/08 , C07C15/06
摘要： A method of making a C5 or C6 conjugated linear diene compound is carried out by: (a) reacting a C5 or C6 linear monoene with a hydrogen acceptor in the presence of a hydrogen transfer catalyst to produce a C5 or C6 conjugated linear diene.
摘要翻译：通过以下步骤进行制备C5或C6共轭线性二烯化合物的方法：（a）在氢转移催化剂存在下使C5或C6直链单烯与氢受体反应，生成C5或C6共轭线型二烯。

8. 发明申请

WO0214241A2 METHOD FOR SIDE CHAIN ALKYLATION OR ALKENYLATION 审中-公开
标题翻译：侧链烷基化或烷基化的方法
公开(公告)号：WO0214241A2
公开(公告)日：2002-02-21
申请号：PCT/EP0109296
申请日：2001-08-10
申请人： BASF AG , STEINBRENNER ULRICH , BOEHLING RALF , ZEHNER PETER
发明人： STEINBRENNER ULRICH , BOEHLING RALF , ZEHNER PETER
IPC分类号： B01J23/04 , C07B61/00 , C07C2/72 , C07C7/04 , C07C7/20 , C07C15/107 , C07C2/00
CPC分类号： B01J23/04 , C07C2/72 , C07C2523/04 , C07C2527/08 , C07C2527/232 , Y10S585/95
摘要： The invention relates to a method for reducing the formation of polymers during the side chain alkylation or side chain alkenylation of alkylaromatic compounds by reacting olefins or diolefins in the presence of an alkali metal catalyst; and the ensuing distillation for preparing the alkylated or alkenylated compound. The alkali metal in the catalyst is situated on an inorganic carrier, and the catalyst is mechanically separated from the reaction mixture after the reaction and before distillation.
摘要翻译：在用于通过与在碱金属催化剂的存在下烯烃或二烯烃，和随后的蒸馏获得烷基化或烯基化化合物反应减少侧链或侧烷基芳族化合物在聚合物的形成方法，所述碱金属是存在于催化剂中的无机载体上并且在反应之后和蒸馏之前将催化剂与反应混合物机械分离。

9. 发明申请

WO00009261A1 DISPERSION AND STABILIZATION OF REACTIVE ATOMS ON THE SURFACE OF METAL OXIDES 审中-公开
标题翻译：金属氧化物表面活性物质的分散和稳定性
公开(公告)号：WO00009261A1
公开(公告)日：2000-02-24
申请号：PCT/US1999/017980
申请日：1999-08-12
IPC分类号： B01J21/10 , B01J23/02 , B01J23/04 , B01J27/06 , B01J35/02 , B01J35/10 , B01J37/22 , B01J37/24 , C01B13/14 , C01F5/02 , C01F11/02 , C07B61/00 , C07C2/10 , C07C2/72 , C07C5/13 , C07C5/22 , C07C5/25 , C07C9/16 , C07C11/10 , C07C15/02 , C07C17/10 , B01J23/32 , B01J23/58 , B01J23/60 , B01J23/70 , B01J27/10 , B01J27/12 , B01J27/125 , B01J27/128 , B01J27/135 , B01J27/138 , C07C2/64 , C07C2/66 , C07C2/68 , C07C5/23
CPC分类号： B01J27/138 , B01J21/10 , B01J23/02 , B01J23/04 , B01J27/06 , B01J35/002 , B01J35/023 , B01J35/10 , B01J35/1019 , B01J35/1023 , B01J37/0238 , B01J37/033 , B01J37/10 , B01J37/22 , B01J37/24 , B82Y30/00 , C01B13/14 , C01B13/145 , C01F5/02 , C01F11/02 , C01P2002/60 , C01P2002/88 , C01P2004/64 , C01P2006/12 , C01P2006/22 , C07C2/10 , C07C2/72 , C07C5/2512 , C07C17/10 , C07C2521/10 , C07C2523/04 , C07C11/10 , C07C11/107 , C07C19/01 , C07C19/075 , C07C19/07
摘要： Particulate metal oxide compositions having reactive atoms stabilized on particulate surfaces and methods for reacting the compositions with saturated and unsaturated species are provided. The preferred particulate metal oxides of the compositions are nanocrystalline MgO and CaO with an average crystallite size of up to about 20 nm. The preferred reactive atoms of the compositions are atoms of the halogens and Group I metals. In one embodiment, chlorine atoms are stabilized on the surface of nanocrystalline MgO thus forming a composition which is capable of halogenating compounds, both saturated and unsaturated, in the absence of UV light and elevated reaction temperatures.
摘要翻译：提供了具有在颗粒表面上稳定的反应性原子的颗粒状金属氧化物组合物和使组合物与饱和和不饱和物质反应的方法。组合物的优选的颗粒状金属氧化物是平均微晶尺寸高达约20nm的纳米晶体MgO和CaO。组合物的优选的反应性原子是卤素和第I族金属的原子。在一个实施方案中，氯原子在纳米晶体MgO的表面上稳定，从而形成一种组合物，其能够在不存在UV光和升高的反应温度的情况下卤化饱和和不饱和化合物。

10. 发明申请

WO1998029371A1 PROCESSES FOR PRODUCING ALKENYL-SUBSTITUTED AROMATIC HYDROCARBONS 审中-公开
标题翻译：生产烷基取代芳香烃的方法
公开(公告)号：WO1998029371A1
公开(公告)日：1998-07-09
申请号：PCT/JP1997004802
申请日：1997-12-24
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , YAMAMOTO, Michio , SUZUKAMO, Gohfu
发明人： SUMITOMO CHEMICAL COMPANY, LIMITED
IPC分类号： C07C15/40
CPC分类号： B01J23/04 , B01J21/16 , B01J23/007 , C07C2/72 , C07C2521/04 , C07C2523/04 , C07C2531/12 , C07C15/40
摘要： A process for producing alkenyl-substituted aromatic hydrocarbons which comprises alkenylating an alkyl-substituted aromatic hydrocarbon having a hydrogen atom at the alpha -position of the side chain with a conjugated diene, wherein use is made of a catalyst obtained by the action of an alkali metal compound and either an alkali metal or an alkali metal hybride on a metal oxide selected between alumina and hydrotalcite by heating in a specific temperature range; and another process for producing an alkenyl-substituted aromatic hydrocarbon, characterized by conducting the reaction in the presence of an alkylaminopyridine represented by formula (1) (wherein R1 represents hydrogen or C1-6 alkyl and R2 represents C1-6 alkyl) using a catalyst comprising sodium metal, potassium metal, or an alloy thereof, a catalyst having any of these supported on a support of an inorganic compound, or a catalyst obtained by the action of an alkali metal compound and either an alkali metal or an alkali metal hybride on a metal oxide selected among alumina, alkaline earth oxides, hydrotalcite, silica-alumina, and zeolite by heating in a temperature range of 70 to 700 DEG C.
摘要翻译：一种制备烯基取代的芳族烃的方法，其包括在共轭二烯的侧链的α-位上使具有氢原子的烷基取代的芳族烃链烯基化，其中使用由碱的作用获得的催化剂金属化合物和通过在特定温度范围内加热而选择在氧化铝和水滑石之间的金属氧化物上的碱金属或碱金属混合物; 和另一种制备烯基取代的芳族烃的方法，其特征在于使用催化剂在式（1）表示的烷基氨基吡啶存在下进行反应（其中R 1表示氢或C 1-6烷基，R 2表示C 1-6烷基）包括金属钠，金属钾或其合金，其中任一种负载在无机化合物的载体上的催化剂，或通过碱金属化合物和碱金属或碱金属混合物的作用获得的催化剂选自氧化铝，碱土金属氧化物，水滑石，二氧化硅 - 氧化铝和沸石的金属氧化物，在70〜700℃的温度范围内加热。

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