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1. 发明申请

WO01062719A1 SELECTIVE OXIDATION OF SULFIDES BY THE USE OF AN OXIDANT SYSTEM CONSISTING OF LITHIUM MOLIBDENATE NIOBATE AND HYDROGEN PEROXIDE 审中-公开
标题翻译：通过使用含有锂离子二氧化碳和过氧化氢的氧化剂系统来选择性氧化硫化物
公开(公告)号：WO01062719A1
公开(公告)日：2001-08-30
申请号：PCT/KR2001/000252
申请日：2001-02-22
IPC分类号： C07B45/04 , C07C315/02 , C07C317/08 , C07C317/14 , C07C317/18
CPC分类号： C07B45/04 , C07C315/02 , C07C317/14 , C07C317/08 , C07C317/18
摘要： The present invention relates to a process for selective oxidation of a sulfide by the use of lithium molibdenate niobate (LiNbMoO6) - hydrogen peroxide oxidant system to the corresponding sulfoxide or sulfone compound within a few hours under the condition of controlling the amount of hydrogen peroxide in the presence of alcohol solvent. The process for oxidizing a sulfide according to the present invention has economic advantage in view of the application for industrial use as well as in a laboratory scale because the process is carried out under mild condition, comprising of simple procedure, and the reactants are easy to handle. In particular, allylic sulfides having double bond(s) of high electron density by alkyl substitution or extended conjugation, which are apt to be attacked by electrophilic oxidants, can be subjected to selective oxidation to sulfones or sulfoxides without oxidation of the double bond(s), according to the present invention.
摘要翻译：本发明涉及在控制过氧化氢的量的条件下，在几小时内使用铌酸铌酸锂（LiNbMoO 6） - 过氧化氢氧化剂体系对硫化物进行选择性氧化的方法酒精溶剂的存在。根据本发明的氧化硫化物的方法鉴于工业应用以及实验室规模具有经济优势，因为该方法在温和条件下进行，包括简单的步骤，并且反应物容易处理。特别地，易于被亲电子氧化剂侵蚀的通过烷基取代或延伸共轭具有高电子密度双键的烯丙基硫化物可以在不氧化双键的情况下进行选择性氧化成砜或亚砜），根据本发明。

2. 发明申请

WO00015585A1 METHOD FOR CONDENSATION OF AROMATIC DERIVATIVE(S) AND A SULPHINIC DERIVATIVE 审中-公开
标题翻译：芳香衍生物（S）和硫代衍生物的浓缩方法
公开(公告)号：WO00015585A1
公开(公告)日：2000-03-23
申请号：PCT/FR1999/002134
申请日：1999-09-08
IPC分类号： C07C315/04 , C07B45/04 , C07C315/00 , C07C317/14 , C07C317/22 , C07C317/36 , C07C317/40 , C07C319/20 , C07C323/65
CPC分类号： C07C315/00 , C07B45/04 , C07C319/20 , C07C317/14 , C07C317/22 , C07C317/36 , C07C317/40 , C07C323/65
摘要： The invention concerns a method for the condensation of aromatic derivative(s) or a sulphinic derivative by a perhalogenated, advantageously perfluorinated, carbon atom. Said method is characterised in that it consists in subjecting said sulphinic derivative and said aromatic derivative to the action of a strong acid whereof the pKa is not more than 0. The invention is applicable to organic synthesis.
摘要翻译：本发明涉及通过全卤代，有利地全氟化的碳原子缩合芳族衍生物或亚磺酸衍生物的方法。所述方法的特征在于它包括使所述亚磺酰衍生物和所述芳族衍生物受到pKa不大于0的强酸的作用。本发明适用于有机合成。

3. 发明申请

WO2017007672A1 SUBSTITUTED BENZOTRIAZOLE PHENOLS 审中-公开
标题翻译：取代的苯并噻唑酚
公开(公告)号：WO2017007672A1
公开(公告)日：2017-01-12
申请号：PCT/US2016/040348
申请日：2016-06-30
申请人： 3M INNOVATIVE PROPERTIES COMPANY
发明人： VOLP, Kelly A. , SCHULTZ, Nathan E. , LI, Fuming B.
IPC分类号： C07D249/20
CPC分类号： C07D249/20 , C07B41/04 , C07B43/04 , C07B45/04 , C07B45/06 , C07B51/00 , C07D403/12
摘要： Benzotriazole phenols with substituents either ortho to the phenol hydroxyl group and/or para to the phenol hydroxyl group can be prepared from the unsubstitued benzotriazole phenol by coupling reactions. The ortho substituent group can be a simple alkoxy or amino group, or the ortho substituent group can be a linking group, linking the benzotriazole phenol to another benzotriazole phenol group.
摘要翻译：可以通过偶联反应从未取代的苯并三唑苯酚制备苯酚羟基的邻位和/或酚羟基对位的苯并三唑酚。邻位取代基可以是简单的烷氧基或氨基，或邻位取代基可以是连接基团，将苯并三唑酚与另一苯并三唑酚基连接。

4. 发明申请

WO2006137473A1 芳香族スルホン酸化合物の製造法审中-公开
标题翻译：生产芳香磺酸化合物的方法
公开(公告)号：WO2006137473A1
公开(公告)日：2006-12-28
申请号：PCT/JP2006/312485
申请日：2006-06-22
申请人：日産化学工業株式会社 , 吉本卓司 , 小野豪 , 加藤拓
发明人：吉本卓司 , 小野豪 , 加藤拓
IPC分类号： C07C303/04 , C07C309/38 , C07C309/42
CPC分类号： C07C303/04 , C07B45/04 , C07D215/26 , C07C309/38 , C07C309/42
摘要： A process for producing an aromatic sulfonic acid compound, comprising sulfonating a compound having at least one aromatic ring with the use of any of compounds of the formula (1) as a sulfonating agent. This provides a process for producing an aromatic sulfonic acid compound usable in thin films for electronic device usage. A-SO 3 H (1) wherein A is formula (2) or (3): (2) (3) wherein Q is hydroxyl, etc.; and each of R 1 to R 4 and each of R 5 to R 10 independently represent hydrogen, a halogen, a sulfonate group, carboxyl, hydroxyl, thiol, amino, etc., provided that with respect to the substituents of R 1 to R 4 and R 5 to R 10 , any two adjacent substituents may form -CH 2 CH 2 CH 2 -, -CH 2 CH 2 O-, etc. and thus form a 5-membered or 6-membered ring with carbon atoms bonded thereto.
摘要翻译：一种制备芳族磺酸化合物的方法，其包括使用任何式（1）的化合物磺化具有至少一个芳环的化合物作为磺化剂。这提供了可用于电子器件使用的薄膜中的芳族磺酸化合物的制备方法。 A-SO 3 H（1）其中A为式（2）或（3）：（2）（3）其中Q为羟基等; R 1至R 4中的每一个和R 5至R 10各自独立地表示氢，卤素，磺酸酯基，羧基，羟基，硫醇，氨基等，条件是相对于R 1至R 4和R 5的取代基，任何两个相邻的取代基可以形成-CH 2 CH 2 CH 2 CH 2 - ， - -CH 2 O 2 O 2等，因此形成与其键合的碳原子的5元或6元环。

5. 发明申请

WO0137629A8 HIGH SURFACE MICROPOROUS MATERIALS WHICH ARE ACTIVE IN OXIDATION REACTIONS. TIQ-6 AND METIQ-6 审中-公开
标题翻译：在氧化反应中活性高的高表面微孔材料。 TIQ-6和METIQ-6
公开(公告)号：WO0137629A8
公开(公告)日：2003-02-06
申请号：PCT/ES0000456
申请日：2000-11-24
申请人： CONSEJO SUPERIOR INVESTIGACION , UNIV VALENCIA POLITECNICA , CORMA CANOS AVELINO , FORNES SEGUI VICENTE , DIAZ MORALES URBANO , DOMINE MARCELO EDUARDO
发明人： CORMA CANOS AVELINO , FORNES SEGUI VICENTE , DIAZ MORALES URBANO , DOMINE MARCELO EDUARDO
IPC分类号： B01J29/89 , B01J31/02 , B01J35/10 , B01J37/00 , C01B37/00 , C01B39/00 , C01B39/08 , C01B39/46 , C01B39/48 , C07B41/02 , C07B41/06 , C07B41/08 , C07B43/00 , C07B45/04 , C07B61/00 , C07C37/08 , C07C39/02 , C07C45/29 , C07C47/02 , C07C49/04 , C07C51/23 , C07C53/08 , C07C315/00 , C07C317/02 , C07D301/12 , C07D487/22
CPC分类号： B01J31/0231 , B01J29/89 , B01J31/0212 , B01J31/0274 , B01J31/0275 , B01J31/38 , B01J2231/72 , C01B37/005 , C01B39/085 , C01B39/48 , C07B41/02 , C07B41/06 , C07B41/08 , C07B43/00 , C07B45/04 , C07D301/12 , Y10S423/23
摘要： The invention relates to a microporous material formed by oxygen, silicon, germanium, aluminum, boron, gallium, zirconium and/or titanium known as TIQ-6, to a method for preparing said material and to its applications as catalyst in oxidation reactions. The TIQ-6 preparation method is based on the synthesis of a gel containing titanium and/or zirconium, hydrothermal treatment thereof under controlled conditions and treatment of the resulting laminar material with an organic compound solution, preferably having a long hydrocarbonated chain containing a proton accepting group. This swollen material is subjected to a specific treatment involving agitation, ultrasound or any other method known in prior art with the purpose of obtaining a delaminated solid with a high outer surface. The invention also relates to a material having similar characteristics as that of TIQ-6 but additionally having organic groups anchored on the surface thereof and called METIQ-6, to a method for preparing the latter and to the utilization thereof as catalyst in oxidation reactions. The incorporation of organic species during synthesis of the material called METIQ-6 is carried out by means of a post-synthesis process on the TIQ-6 material.
摘要翻译：本发明涉及一种由氧，硅，锗，铝，硼，镓，锆和/或钛称为TIQ-6形成的微孔材料，用于制备所述材料的方法及其在氧化反应中作为催化剂的应用。 TIQ-6制备方法是基于合成含有钛和/或锆的凝胶，在受控条件下进行水热处理，并用有机化合物溶液处理得到的层状材料，优选具有含有质子接受的长烃链组。该溶胀材料经受涉及搅拌，超声波或现有技术中已知的任何其它方法的具体处理，目的是获得具有高外表面的分层固体。本发明还涉及具有与TIQ-6类似的特征的材料，但另外具有锚固在其表面上的称为METIQ-6的有机基团，其制备方法和用作氧化反应中的催化剂的方法。在称为METIQ-6的材料的合成期间掺入有机物质是通过对TIQ-6材料的后合成方法进行的。

6. 发明申请

WO2017027271A1 METHODS FOR PRODUCING ALKYLBENZENES, PARAFFINS, OLEFINS AND OXO ALCOHOLS FROM WASTE PLASTIC FEEDSTOCKS 审中-公开
标题翻译：从废物塑料原料生产烷基苯甲酸，对苯二甲酸，烯烃和氧化物的方法
公开(公告)号：WO2017027271A1
公开(公告)日：2017-02-16
申请号：PCT/US2016/045219
申请日：2016-08-03
申请人： THE PROCTER & GAMBLE COMPANY
发明人： SCHEIBEL, Jeffrey, John , VINSON, Phillip, Kyle , CRON, Scott, Leroy , WILLIAMS, Thomas, Earl
IPC分类号： C10G3/00 , C10G45/00 , C10G45/02 , C07C5/32 , C11D3/34 , C10G1/00 , C10G65/04 , C10G1/10
CPC分类号： C11D1/22 , C07B41/02 , C07B41/04 , C07B45/04 , C07C2/66 , C07C5/32 , C07C303/02 , C10G1/002 , C10G1/10 , C10G3/42 , C10G3/50 , C10G45/00 , C10G45/02 , C10G65/04 , C10G2300/1003 , C10G2400/00 , C11D1/146 , C11D1/29 , C11D1/37 , C11D17/042 , C11D17/045 , C07C11/02 , C07C15/107
摘要： The present invention relates generally to methods for producing detergent compounds from waste plastic feedstocks. More specifically, the invention relates to methods for producing detergent intermediates, including alkylbenzenes, paraffins, olefins, oxo alcohols, and surfactant derivatives thereof from waste plastic feedstock.
摘要翻译：本发明一般涉及从废塑料原料生产洗涤剂化合物的方法。更具体地，本发明涉及用废塑料原料生产洗涤剂中间体的方法，包括烷基苯，链烷烃，烯烃，羰基合成醇及其表面活性剂衍生物。

7. 发明申请

WO2013104605A3 PROCESS FOR THE ASYMMETRIC OXIDATION OF ORGANIC COMPOUNDS WITH PEROXIDES IN THE PRESENCE OF A CHIRAL ACID CATALYST 审中-公开
标题翻译：有机化合物与叔酸催化剂存在过氧化物的不对称氧化方法
公开(公告)号：WO2013104605A3
公开(公告)日：2013-09-26
申请号：PCT/EP2013050190
申请日：2013-01-08
申请人： STUDIENGESELLSCHAFT KOHLE MBH
发明人： LIST BENJAMIN , CORIC ILIJA , LIAO SAIHU
IPC分类号： C07C315/02
CPC分类号： C07C315/02 , B01J31/0258 , B01J31/0264 , B01J2231/70 , C07B45/04 , C07B53/00 , C07B2200/07 , C07C2601/14 , C07C2602/08 , C07D493/10 , C07F9/657154 , C07F9/65744 , C07C317/14 , C07C317/22 , C07C317/12 , C07C317/04 , C07C317/44
摘要： The present invention relates to a process for the asymmetric oxidation of nucleophilic organic compounds, particularly metal-free, with peroxide compounds in the presence of a chiral Bronsted acid catalyst. In one detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral imidodiphosphate catalyst. In another detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral phosphoric acid catalyst.
摘要翻译：本发明涉及在手性Bronsted酸催化剂存在下用过氧化物化合物对亲核有机化合物，特别是不含金属的不对称氧化的方法。一方面，本发明涉及在手性酰亚胺二磷酸盐催化剂存在下用过氧化物化合物对硫代化合物进行对映选择性磺基氧化的方法。另一个细节，本发明涉及在手性磷酸催化剂存在下用过氧化物化合物对硫代化合物进行对映选择性磺基氧化的方法。

8. 发明申请

WO0137629A3 HIGH SURFACE MICROPOROUS MATERIALS WHICH ARE ACTIVE IN OXIDATION REACTIONS. TIQ-6 AND METIQ-6 审中-公开
标题翻译：在氧化反应中活性高的高表面微孔材料。 TIQ-6和METIQ-6
公开(公告)号：WO0137629A3
公开(公告)日：2002-03-14
申请号：PCT/ES0000456
申请日：2000-11-24
申请人： CONSEJO SUPERIOR INVESTIGACION , UNIV VALENCIA POLITECNICA , CORMA CANOS AVELINO , FORNES SEGUI VICENTE , DIAZ MORALES URBANO , DOMINE MARCELO EDUARDO
发明人： CORMA CANOS AVELINO , FORNES SEGUI VICENTE , DIAZ MORALES URBANO , DOMINE MARCELO EDUARDO
IPC分类号： B01J29/89 , B01J31/02 , B01J35/10 , B01J37/00 , C01B37/00 , C01B39/00 , C01B39/08 , C01B39/46 , C01B39/48 , C07B41/02 , C07B41/06 , C07B41/08 , C07B43/00 , C07B45/04 , C07B61/00 , C07C37/08 , C07C39/02 , C07C45/29 , C07C47/02 , C07C49/04 , C07C51/23 , C07C53/08 , C07C315/00 , C07C317/02 , C07D301/12 , C07D487/22
CPC分类号： B01J31/0231 , B01J29/89 , B01J31/0212 , B01J31/0274 , B01J31/0275 , B01J31/38 , B01J2231/72 , C01B37/005 , C01B39/085 , C01B39/48 , C07B41/02 , C07B41/06 , C07B41/08 , C07B43/00 , C07B45/04 , C07D301/12 , Y10S423/23
摘要： The invention relates to a microporous material formed by oxygen, silicon, germanium, aluminum, boron, gallium, zirconium and/or titanium known as TIQ-6, to a method for preparing said material and to its applications as catalyst in oxidation reactions. The TIQ-6 preparation method is based on the synthesis of a gel containing titanium and/or zirconium, hydrothermal treatment thereof under controlled conditions and treatment of the resulting laminar material with an organic compound solution, preferably having a long hydrocarbonated chain containing a proton accepting group. This swollen material is subjected to a specific treatment involving agitation, ultrasound or any other method known in prior art with the purpose of obtaining a delaminated solid with a high outer surface. The invention also relates to a material having similar characteristics as that of TIQ-6 but additionally having organic groups anchored on the surface thereof and called METIQ-6, to a method for preparing the latter and to the utilization thereof as catalyst in oxidation reactions. The incorporation of organic species during synthesis of the material called METIQ-6 is carried out by means of a post-synthesis process on the TIQ-6 material.
摘要翻译：本发明涉及一种由氧，硅，锗，铝，硼，镓，锆和/或钛称为TIQ-6形成的微孔材料，用于制备所述材料的方法及其在氧化反应中作为催化剂的应用。 TIQ-6制备方法是基于合成含有钛和/或锆的凝胶，在受控条件下进行水热处理，并用有机化合物溶液处理得到的层状材料，优选具有含有质子接受的长烃链组。该溶胀材料经受涉及搅拌，超声波或现有技术中已知的任何其它方法的具体处理，目的是获得具有高外表面的分层固体。本发明还涉及具有与TIQ-6类似的特征的材料，但另外具有锚固在其表面上的称为METIQ-6的有机基团，其制备方法和在氧化反应中用作催化剂的方法。在称为METIQ-6的材料的合成期间掺入有机物质是通过对TIQ-6材料的后合成方法进行的。

9. 发明申请

WO2013104605A2 PROCESS FOR THE ASYMMETRIC OXIDATION OF ORGANIC COMPOUNDS WITH PEROXIDES IN THE PRESENCE OF A CHIRAL ACID CATALYST 审中-公开
标题翻译：在手性酸催化剂存在下过氧化有机化合物与过氧化物的不对称氧化方法
公开(公告)号：WO2013104605A2
公开(公告)日：2013-07-18
申请号：PCT/EP2013/050190
申请日：2013-01-08
申请人： STUDIENGESELLSCHAFT KOHLE MBH
发明人： LIST, Benjamin , CORIC, Ilija , LIAO, Saihu
IPC分类号： C07C409/44 , C07C317/14 , C07F9/24 , B01J31/02
CPC分类号： C07C315/02 , B01J31/0258 , B01J31/0264 , B01J2231/70 , C07B45/04 , C07B53/00 , C07B2200/07 , C07C2601/14 , C07C2602/08 , C07D493/10 , C07F9/657154 , C07F9/65744 , C07C317/14 , C07C317/22 , C07C317/12 , C07C317/04 , C07C317/44
摘要： The present invention relates to a process for the asymmetric oxidation of nucleophilic organic compounds, particularly metal-free, with peroxide compounds in the presence of a chiral Bronsted acid catalyst. In one detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral imidodiphosphate catalyst. In another detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral phosphoric acid catalyst.
摘要翻译：本发明涉及在手性布朗斯台德酸催化剂存在下用过氧化物化合物对亲核有机化合物（特别是不含金属）进行不对称氧化的方法。具体而言，本发明涉及在手性亚氨基二磷酸酯催化剂存在下，用过氧化物化合物对硫代化合物进行对映选择性磺化氧化的方法。更详细地说，本发明涉及在手性磷酸催化剂存在下用过氧化物化合物对硫代化合物进行对映选择性磺化氧化的方法。

10. 发明申请

WO2012104415A1 A THIONATION PROCESS AND A THIONATING AGENT 审中-公开
标题翻译：渗透过程和渗透剂
公开(公告)号：WO2012104415A1
公开(公告)日：2012-08-09
申请号：PCT/EP2012/051864
申请日：2012-02-03
申请人： VIRONOVA AB , PETTERSSON, Birgitta , HASIMBEGOVIC, Vedran , SVENSSON, Per, H. , BERGMAN, Jan
发明人： PETTERSSON, Birgitta , HASIMBEGOVIC, Vedran , SVENSSON, Per, H. , BERGMAN, Jan
IPC分类号： C07B45/00 , C01B25/14 , C07D213/06 , C07C325/02 , C07C327/44 , C07D207/24 , C07D209/30 , C07D211/72 , C07D211/84 , C07D213/63 , C07D239/93 , C07D241/06
CPC分类号： C07F9/58 , C07B45/00 , C07B45/04 , C07C325/02 , C07C327/48 , C07D207/24 , C07D207/416 , C07D209/08 , C07D209/30 , C07D209/34 , C07D209/42 , C07D209/88 , C07D211/72 , C07D211/84 , C07D211/88 , C07D213/63 , C07D213/70 , C07D213/83 , C07D215/36 , C07D219/04 , C07D219/08 , C07D223/06 , C07D239/58 , C07D239/70 , C07D239/93 , C07D241/08 , C07D241/44 , C07D243/14 , C07D243/22 , C07D245/04 , C07D309/36 , C07D311/84 , C07D341/00 , C07D471/04 , C07D473/36 , C07D487/04 , C07F9/581
摘要： A process for transforming a group >C=O (I) in a compound into a group >C=S (II) or into a tautomeric form of group (II) in a reaction giving a thionated reaction product, by use of crystalline P 2 S 5 ·2 C 5 H 5 N as a thionating agent. A thionating agent which is crystalline P 2 S 5 ·2 C 5 H 5 N
摘要翻译：在化合物中将C = O（I）的基团转化成组> C = S（II）的基团或通过使用结晶P2S5在产生硫酸化反应产物的反应中变成互变异构形式的基团（II）的方法 ·2 C5H5N作为硫化剂。结晶P2S5·2C5H5N的硫化剂

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