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    • 9. 发明申请
    • PROCESS FOR FORMING PROPYLENE OXIDE FROM OXIDATION OF METHYL BENZYL ALCOHOL
    • 由甲基苄基醇氧化形成丙烯氧化物的方法
    • WO2016164595A1
    • 2016-10-13
    • PCT/US2016/026468
    • 2016-04-07
    • LYONDELL CHEMICAL TECHNOLOGY, L.P.
    • DANG, Vu, A.LEYSHON, David, W.NAGY, SandorGREY, Roger, A.
    • C07D301/12C07D303/04
    • C07D301/12B01J29/7088C07D301/32C07D301/36C07D303/04Y02P20/52
    • The present disclosure relates to a method of preparing propylene oxide comprising the steps: (a) oxidizing alpha-methylbenzyl alcohol with air to form a first reaction mixture comprising hydrogen peroxide and acetophenone; (b) reacting propylene with the first reaction mixture in the presence of a catalyst to form a second reaction mixture comprising propylene oxide; (c) separating the propylene oxide from the second reaction mixture to form a third reaction mixture; (d) heating the third reaction mixture to decompose hydrogen peroxide, whereby a fourth reaction mixture is formed; (e) hydrogenating the acetophenone in the fourth reaction mixture with hydrogen to form a fifth reaction mixture comprising alpha-methylbenzyl alcohol; and (f) separating alpha-methylbenzyl alcohol from the fifth reaction mixture and returning the methyl benzyl alcohol to step (a).
    • 本公开涉及一种制备环氧丙烷的方法,包括以下步骤:(a)用空气氧化α-甲基苄醇以形成包含过氧化氢和苯乙酮的第一反应混合物; (b)在催化剂存在下使丙烯与第一反应混合物反应以形成包含环氧丙烷的第二反应混合物; (c)从第二反应混合物中分离环氧丙烷以形成第三反应混合物; (d)加热第三反应混合物以分解过氧化氢,由此形成第四反应混合物; (e)用氢将第四反应混合物中的苯乙酮氢化以形成包含α-甲基苄醇的第五反应混合物; 和(f)从第五反应混合物中分离出α-甲基苄醇并将甲基苄醇返回到步骤(a)。