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    • 6. 发明申请
    • POLYALKENYL COUPLING AGENT AND CONJUGATED DIENE POLYMERS PREPARED THEREFROM
    • 聚烯烃偶联剂和共混二烯聚合物
    • WO2015175812A1
    • 2015-11-19
    • PCT/US2015/030841
    • 2015-05-14
    • KRATON POLYMERS U.S. LLC
    • VAN DER HUIZEN, Adriaan AlbertDE WIT, Frank Wijnand
    • C08F297/04
    • C08F36/06C08C19/02C08F36/08C08F297/044
    • A process is provided for preparing a coupled polymer by anionic polymerization wherein the coupled polymer is a conjugated diene polymer comprising the following reaction steps: a) polymerizing a monomer or a mixture of monomers comprising at least one conjugated diene optionally one or more monoalkenyl arene compounds in the presence of an anionic initiator to form a living polymer arm or mixture of arms, with an average apparent molecular weight greater than 2000; b) reacting the living polymer arm or arms (P) with a polyalkenyl coupling agent (CA), c) terminating the polymerization if any living polymers remain after step b), and d) optionally functionalizing and/or hydrogenating the coupled polymer so produced, wherein the polyalkenyl coupling agent is an alpha,omega-bis(vinylphenyl)alkane. Also provided is the polymer so prepared and its use in concentrates, aqueous emulsions and products made from aqueous emulsions.
    • 提供了通过阴离子聚合制备偶联聚合物的方法,其中偶联聚合物是共轭二烯聚合物,其包含以下反应步骤:a)使包含至少一种共轭二烯的单体或单体混合物任选地一个或多个单烯基芳烃化合物 在阴离子引发剂的存在下,形成平均表观分子量大于2000的活性聚合物臂或臂的混合物; b)使活性聚合物臂或臂(P)与聚链烯基偶联剂(CA)反应,c)如果任何活性聚合物在步骤b)之后保留,则终止聚合,和d)任选地官能化和/或氢化所生成的偶联聚合物 ,其中所述聚链烯基偶联剂是α,ω-双(乙烯基苯基)烷烃。 还提供了如此制备的聚合物及其在浓缩物,水性乳液和由水性乳液制成的产品中的用途。