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1. 发明申请

WO2016018792A8 METAL NANOWIRE INKS FOR THE FORMATION OF TRANSPARENT CONDUCTIVE FILMS WITH FUSED NETWORKS 审中-公开
标题翻译：金属纳米油墨与融合网络形成透明导电膜
公开(公告)号：WO2016018792A8
公开(公告)日：2016-06-09
申请号：PCT/US2015042203
申请日：2015-07-27
申请人： C3NANO INC
发明人： LI YING-SYI , YANG XIQIANG , KAMBE YU , CHEN XIAOFENG , GU HUA , LAM STEVEN MICHAEL , INOUYE MELANIE MARIKO , CHENG ARTHUR YUNG-CHI , TAN ALEX DA ZHANG , SCULLY CHRISTOPHER S , VIRKAR AJAY
IPC分类号： H01B1/22
CPC分类号： C09D11/52 , B05D1/005 , B05D1/02 , B05D1/18 , B05D1/265 , B05D1/28 , B05D3/0254 , B05D5/06 , C09D11/08 , C09D11/10 , C09D11/102 , C09D11/106 , C09D11/14 , C09D101/02 , C09D139/06 , C23C30/00 , G06F3/044 , G06F3/045 , G06F2203/04103 , H01B1/02 , H01B1/22 , H01B13/30 , H05K1/0274 , H05K1/097 , H05K2201/0108 , H05K2201/026 , H05K2201/10128 , H05K2201/10151
摘要： Fusing nanowire inks are described that can also comprise a hydrophilic polymer binder, such as a cellulose based binder. The fusing nanowire inks can be deposited onto a substrate surface and dried to drive the fusing process. Transparent conductive films can be formed with desirable properties.
摘要翻译：描述了熔融纳米线油墨，其还可以包含亲水性聚合物粘合剂，例如基于纤维素的粘合剂。熔融纳米线油墨可以沉积在基材表面上并干燥以驱动熔合过程。可以形成具有期望特性的透明导电膜。

2. 发明申请

WO2016061371A2 TRANSPARENT FILMS WITH CONTROL OF LIGHT HUE USING NANOSCALE COLORANTS 审中-公开
标题翻译：使用纳米颜料控制光亮度的透明膜
公开(公告)号：WO2016061371A2
公开(公告)日：2016-04-21
申请号：PCT/US2015/055768
申请日：2015-10-15
申请人： C3NANO INC.
发明人： XIQIANG, Yang , YADONG, Cao , YONGXING, Hu , GU, Hua , YING-SYI, Li , VIRKAR, Ajay
IPC分类号： C09D5/24 , G06F3/044
CPC分类号： C09D5/24 , C09D7/70 , G02B1/16 , G02B5/008 , G02B5/223 , G02B2207/101 , G06F1/16 , G06F3/0412 , G06F3/044 , G06F3/045 , H01B5/14
摘要： Nanoscale colorants are introduced to adjust the hue of transparent conductive films, such as to provide a whiter film. The transparent conductive films can have sparse metal conductive layers, which can be formed using silver nanowires. Color of the film can be evaluated using standard color parameters. In particular, values of color parameter b* can be reduced with the nanoscale colorants without unacceptably changing other parameters, such as haze, a* and transparency.
摘要翻译：引入纳米级着色剂以调节透明导电膜的色调，以提供更白的膜。透明导电膜可以具有可以使用银纳米线形成的稀疏金属导电层。可以使用标准颜色参数来评估胶片的颜色。特别地，可以用纳米级着色剂降低颜色参数b *的值，而不会不可接受地改变其它参数，例如雾度，a *和透明度。

3. 发明申请

WO2020159874A1 THIN FLEXIBLE STRUCTURES WITH SURFACES WITH TRANSPARENT CONDUCTIVE FILMS AND PROCESSES FOR FORMING THE STRUCTURES 审中-公开
公开(公告)号：WO2020159874A1
公开(公告)日：2020-08-06
申请号：PCT/US2020/015218
申请日：2020-01-27
申请人： C3NANO INC.
发明人： CHEN, Xiaofeng , KANG, Byunghwan , CHEN, Jackie , CAO, Yadong , LUO, Vicki , CHENG, Arthur Yung-Chi , MOON, Andrew Hyeongjoo , YANG, Xiqiang , VIRKAR, Ajay
IPC分类号： G06F3/041 , H01B1/02 , H01B1/16
摘要： Structures are described having thin flexible polymer substrates with electrically conductive films on each opposing surface while having high optical transmittance and good optical properties. The structures can have total thicknesses of no more than about 30 microns and good flexibility. Processing approaches are described that allow for the coating of the very thin structures by providing support through the coating process. The structures are demonstrated to have good durability under conditions designed to test accelerated wear for touch sensor use.

4. 发明申请

WO2016018792A1 METAL NANOWIRE INKS FOR THE FROMATION OF TRANSPARENT CONDUCTIVE FILMS WITH FUSED NETWORKS 审中-公开
标题翻译：金属纳米墨水由透明导电膜与熔断网络
公开(公告)号：WO2016018792A1
公开(公告)日：2016-02-04
申请号：PCT/US2015/042203
申请日：2015-07-27
申请人： C3NANO INC.
发明人： LI, Ying-Syi , YANG, Xiqiang , KAMBE, Yu , CHEN, Xiaofeng , GU, Hua , LAM, Steven, Michael , INOUYE, Melanie, Mariko , CHENG, Arthur, Yung-Chi , TAN, Alex, Da Zhang , SCULLY, Christopher, S. , VIRKAR, Ajay
IPC分类号： H01B1/22
CPC分类号： C09D11/52 , B05D1/005 , B05D1/02 , B05D1/18 , B05D1/265 , B05D1/28 , B05D3/0254 , B05D5/06 , C09D11/08 , C09D11/10 , C09D11/102 , C09D11/106 , C09D11/14 , C09D101/02 , C09D139/06 , C23C30/00 , G06F3/044 , G06F3/045 , G06F2203/04103 , H01B1/02 , H01B1/22 , H01B13/30 , H05K1/0274 , H05K1/097 , H05K2201/0108 , H05K2201/026 , H05K2201/10128 , H05K2201/10151
摘要： Fusing nanowire inks are described that can also comprise a hydrophilic polymer binder, such as a cellulose based binder. The fusing nanowire inks can be deposited onto a substrate surface and dried to drive the fusing process. Transparent conductive films can be formed with desirable properties.
摘要翻译：描述了熔融纳米线油墨，其还可以包含亲水性聚合物粘合剂，例如基于纤维素的粘合剂。熔融纳米线油墨可以沉积在基材表面上并干燥以驱动熔合过程。可以形成具有期望特性的透明导电膜。

5. 发明申请

WO2014133890A2 FUSED METAL NANOSTRUCTURED NETWORKS, FUSING SOLUTIONS WITH REDUCING AGENTS AND METHODS FOR FORMING METAL NETWORKS 审中-公开
标题翻译：熔融金属纳米结构网络，具有还原剂的熔融解决方案和形成金属网络的方法
公开(公告)号：WO2014133890A2
公开(公告)日：2014-09-04
申请号：PCT/US2014/017652
申请日：2014-02-21
申请人： C3NANO INC.
发明人： VIRKAR, Ajay , YANG, Xiqiang , LI, Ying-syi , MCKEAN, Dennis , LEMIEUX, Melburne, C.
IPC分类号： H03K17/96 , B32B5/02 , B32B15/02 , H05K1/02
CPC分类号： H03K17/9622 , B32B15/02 , B32B15/08 , B32B15/18 , B32B27/281 , B32B27/286 , B32B27/288 , B32B27/304 , B32B27/306 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/40 , B32B2270/00 , B32B2307/202 , B32B2307/412 , B32B2457/00 , C09D11/52 , G06F3/044 , G06F2203/04103 , G06F2203/04112 , H03K2217/96031 , H05K1/097 , H05K3/027 , H05K3/06 , H05K3/1283 , H05K2201/0108 , H05K2201/026 , H05K2203/107 , H05K2203/1131 , H05K2203/1157 , H05K2203/125 , Y10T428/12424 , Y10T428/12444 , Y10T442/655
摘要： Reduction/oxidation reagents have been found to be effective to chemically cure a sparse metal nanowire film into a fused metal nanostructured network through evidently a ripening type process. The resulting fused network can provide desirable low sheet resistances while maintaining good optical transparency. The transparent conductive films can be effectively applied as a single conductive ink or through sequential forming of a metal nanowire film with the subsequent addition of a fusing agent. The fused metal nanowire films can be effectively patterned, and the patterned films can be useful in devices, such as touch sensors.
摘要翻译：已经发现还原/氧化试剂通过明显的熟化方法将稀疏金属纳米线膜化学固化成熔融金属纳米结构网络是有效的。所得到的融合网络可以提供期望的低薄层电阻，同时保持良好的光学透明度。透明导电膜可以有效地作为单个导电油墨施加，或者通过随后添加熔融剂来连续地形成金属纳米线膜。熔融金属纳米线膜可以被有效地构图，并且图案化的膜可以用于诸如触摸传感器的器件中。

6. 发明申请

WO2013192437A3 METAL NANOSTRUCTURED NETWORKS AND TRANSPARENT CONDUCTIVE MATERIAL 审中-公开
标题翻译：金属纳米结构网络和透明导电材料
公开(公告)号：WO2013192437A3
公开(公告)日：2014-03-13
申请号：PCT/US2013046866
申请日：2013-06-20
申请人： C3NANO INC
发明人： VIRKAR AJAY , LI YING-SYI , YANG XIQIANG , LEMIEUX MELBURNE C
IPC分类号： H01B5/14
CPC分类号： C09D11/037 , C09D11/322 , C09D11/52 , G06F3/041 , G06F2203/04103 , H01B1/02 , H01L31/022466 , H01L31/1884 , Y02E10/50
摘要： Metal nanowires, such as silver nanowires coated on a substrate were fused together to form fused metal nanowire networks that have greatly improved conductivity while maintaining good transparency. Materials formed from the fused metal nanowire networks described herein can have a transparency to visible light of at least about 85% and a sheet resistance of no more than about 100 Olims/square or a transparency to visible light of at least about 90% and a sheet resistance of no more than about 250 Olims/square. In addition to maintaining good transparency, the materials formed from the sintered metal nanowire networks can have a haze of no more than 0.5. The method of forming such a fused metal nanowire networks are disclosed that involves exposure of metal nanowires to various fusing agents on a short timescale. The resulting sintered network can have a core-shell structure in which metal halide forms the shell. Additionally, effective methods are described for forming patterned structure with areas of sintered metal nanowire network with high conductivity and areas of un-sintered metal nanowires with low conductivity. The corresponding patterned films are also described. When formed into a film, materials comprising the metal nanowire network demonstrate low sheet resistance while maintaining desirably high levels of optical transparency with low haze, making them suitable for transparent electrode, touch sensors, and other electronic/optical device formation.
摘要翻译：将金属纳米线如涂覆在基材上的银纳米线熔合在一起形成熔融金属纳米线网络，其极大地改善导电性，同时保持良好的透明度。由本文所述的熔融金属纳米线网络形成的材料可以具有至少约85％的可见光和不超过约100奥立兴/平方米的薄层电阻或至少约90％的可见光透明度的透明度，以及表面电阻不超过约250欧姆/平方。除了保持良好的透明度之外，由烧结金属纳米线网络形成的材料可以具有不超过0.5的雾度。公开了形成这种熔融金属纳米线网络的方法，其包括在短时间尺度上将金属纳米线暴露于各种熔合剂。所得到的烧结网络可以具有其中金属卤化物形成壳的核 - 壳结构。另外，描述了用于形成具有导电性高的烧结金属纳米线网络区域和具有低导电性的未烧结金属纳米线区域的图案化结构的有效方法。还描述了相应的图案化膜。当形成膜时，包含金属纳米线网络的材料表现出低的薄层电阻，同时保持理想的高水平的具有低雾度的光学透明度，使得它们适合于透明电极，触摸传感器和其他电子/光学器件形成。

7. 发明申请

WO2013192437A2 METAL NANOSTRUCTURED NETWORKS AND TRANSPARENT CONDUCTIVE MATERIAL 审中-公开
标题翻译：金属纳米结构网络和透明导电材料
公开(公告)号：WO2013192437A2
公开(公告)日：2013-12-27
申请号：PCT/US2013/046866
申请日：2013-06-20
申请人： C3NANO INC.
发明人： VIRKAR, Ajay , LI, Ying-Syi , YANG, Xiqiang , LEMIEUX, Melburne, C.
IPC分类号： H01B5/14
CPC分类号： C09D11/037 , C09D11/322 , C09D11/52 , G06F3/041 , G06F2203/04103 , H01B1/02 , H01L31/022466 , H01L31/1884 , Y02E10/50
摘要： Metal nanowires, such as silver nanowires coated on a substrate were fused together to form fused metal nanowire networks that have greatly improved conductivity while maintaining good transparency. Materials formed from the fused metal nanowire networks described herein can have a transparency to visible light of at least about 85% and a sheet resistance of no more than about 100 Olims/square or a transparency to visible light of at least about 90% and a sheet resistance of no more than about 250 Olims/square. In addition to maintaining good transparency, the materials formed from the sintered metal nanowire networks can have a haze of no more than 0.5. The method of forming such a fused metal nanowire networks are disclosed that involves exposure of metal nanowires to various fusing agents on a short timescale. The resulting sintered network can have a core-shell structure in which metal halide forms the shell. Additionally, effective methods are described for forming patterned structure with areas of sintered metal nanowire network with high conductivity and areas of un-sintered metal nanowires with low conductivity. The corresponding patterned films are also described. When formed into a film, materials comprising the metal nanowire network demonstrate low sheet resistance while maintaining desirably high levels of optical transparency with low haze, making them suitable for transparent electrode, touch sensors, and other electronic/optical device formation.
摘要翻译：将金属纳米线如涂覆在基材上的银纳米线熔合在一起形成熔融金属纳米线网络，其极大地改善导电性，同时保持良好的透明度。由本文所述的熔融金属纳米线网络形成的材料可以具有至少约85％的可见光和不超过约100奥立兴/平方米的薄层电阻或至少约90％的可见光透明度的透明度，以及表面电阻不超过约250欧姆/平方。除了保持良好的透明度之外，由烧结金属纳米线网络形成的材料可以具有不超过0.5的雾度。公开了形成这种熔融金属纳米线网络的方法，其包括在短时间尺度上将金属纳米线暴露于各种熔合剂。所得到的烧结网络可以具有其中金属卤化物形成壳的核 - 壳结构。另外，描述了用于形成具有导电性高的烧结金属纳米线网络区域和具有低导电性的未烧结金属纳米线区域的图案化结构的有效方法。还描述了相应的图案化膜。当形成膜时，包含金属纳米线网络的材料表现出低的薄层电阻，同时保持理想的高水平的具有低雾度的光学透明度，使得它们适合于透明电极，触摸传感器和其他电子/光学器件形成。

8. 发明申请

WO2019113162A3 THIN AND UNIFORM SILVER NANOWIRES, METHOD OF SYNTHESIS AND TRANSPARENT CONDUCTIVE FILMS FORMED FROM THE NANOWIRES 审中-公开
公开(公告)号：WO2019113162A3
公开(公告)日：2019-06-13
申请号：PCT/US2018/063995
申请日：2018-12-05
申请人： C3NANO INC.
发明人： HU, Yongxing , LI, Ying-Syi , YANG, Xiqiang , ANG, Jing, Shun , VIRKAR, Ajay
IPC分类号： H01B1/02 , H01B1/20 , H01B1/22 , H05K1/09 , C09D11/52 , B22F9/16 , B22F9/18 , B22F9/24
摘要： Highly uniform and thin silver nanowires are described having average diameters below 20 nm and a small standard deviation of the diameters. The silver nanowires have a high aspect ratio. The silver nanowires can be characterized by a small number of nanowires having a diameter greater than 18 nm as well as with a blue shifted narrow absorption spectrum in a dilute solution. Methods are described to allow for the synthesis of the narrow uniform silver nanowires. Transparent conductive films formed from the thin, uniform silver nanowires can have very low levels of haze and low values of △L*, the diffusive luminosity, such that the transparent conductive films can provide little alteration of the appearance of a black background.

9. 发明申请

WO2019113162A2 THIN AND UNIFORM SILVER NANOWIRES, METHOD OF SYNTHESIS AND TRANSPARENT CONDUCTIVE FILMS FORMED FROM THE NANOWIRES 审中-公开
公开(公告)号：WO2019113162A2
公开(公告)日：2019-06-13
申请号：PCT/US2018/063995
申请日：2018-12-05
申请人： C3NANO INC.
发明人： HU, Yongxing , LI, Ying-Syi , YANG, Xiqiang , ANG, Jing, Shun , VIRKAR, Ajay
IPC分类号： H01B1/02
摘要： Highly uniform and thin silver nanowires are described having average diameters below 20 nm and a small standard deviation of the diameters. The silver nanowires have a high aspect ratio. The silver nanowires can be characterized by a small number of nanowires having a diameter greater than 18 nm as well as with a blue shifted narrow absorption spectrum in a dilute solution. Methods are described to allow for the synthesis of the narrow uniform silver nanowires. Transparent conductive films formed from the thin, uniform silver nanowires can have very low levels of haze and low values of △L*, the diffusive luminosity, such that the transparent conductive films can provide little alteration of the appearance of a black background.

10. 发明申请

WO2018071538A1 STABILIZED SPARSE METAL CONDUCTIVE FILMS AND SOLUTIONS FOR DELIVERY OF STABILIZING COMPOUNDS 审中-公开
标题翻译：用于稳定化合物的稳定化的稳定的金属导电薄膜和溶液
公开(公告)号：WO2018071538A1
公开(公告)日：2018-04-19
申请号：PCT/US2017/056134
申请日：2017-10-11
申请人： C3NANO INC.
发明人： YANG, Xiqiang , HU, Yongxing , VIRKAR, Ajay , CHENG, Arthur, Yung-Chi , MANZOUR, Faraz, Azadi , LI, Ying-Syi
IPC分类号： H01B1/22 , C09D11/52 , C09D7/12
摘要： Metal salt based stabilizers are described that are effective to improve stability of sparse metal conductive films formed with metal nanowires, especially silver nanowires. Specifically, vanadium (+5) compositions can be effectively placed in coatings to provide desirable stabilization under accelerated wear testing conditions. Sparse metal conductive films can comprise fused metal nanostructured networks. Cobalt (+2) compounds can be incorporated as stabilization agents within nanowire inks to provide a high degree of stabilization without significantly interfering with the fusing process.
摘要翻译：描述了金属盐基稳定剂，其有效改善用金属纳米线，尤其是银纳米线形成的稀疏金属导电膜的稳定性。具体而言，钒（+5）组合物可以有效地置于涂层中以在加速磨损测试条件下提供期望的稳定性。稀疏金属导电膜可以包含熔融金属纳米结构网络。钴（+2）化合物可作为稳定剂纳入纳米线油墨中，以提供高度稳定性而不会显着干扰定影过程。

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