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1. 发明申请

WO2016188595A1 PALLADIUM-PLATINUM SYSTEM FOR USE AS HYDROGEN STORAGE MATERIAL AND/OR ELECTROCATALYST, PREFERABLY IN FUEL-CELLS 审中-公开
标题翻译：用作氢储存材料和/或电解质的铂 - 铂系统，优选在燃料电池
公开(公告)号：WO2016188595A1
公开(公告)日：2016-12-01
申请号：PCT/EP2015/079028
申请日：2015-12-08
申请人： UNIWERSYTET WARSZAWSKI
发明人： LEWERA, Adam , POLCZYNSKI, Piotr , JURCZAKOWSKI, Rafal
IPC分类号： C01B3/00 , H01M4/86
CPC分类号： C01B3/0084 , B01J23/42 , B01J23/44 , B01J35/0033 , B01J37/0244 , C01B3/0026 , H01M4/8657 , H01M4/92 , H01M8/0208 , H01M2008/1095 , Y02E60/327
摘要： The present invention relates to palladium-platinum system consisting of palladium layer covered with a platinum overlayer consisting of 1 to 10 platinum monolayers deposited on palladium for use as hydrogen storage. Such system can be used in fuel cells, hydride batteries and supercapacitors. A method for increasing hydrogen absorption kinetics of hydrogen absorption/desorption process is also disclosed.
摘要翻译：本发明涉及钯 - 铂体系，其由钯层覆盖，钯覆盖层由沉积在钯上的1至10铂单层组成，用作氢储存。这种系统可用于燃料电池，氢化物电池和超级电容器。还公开了一种提高氢吸收/解吸过程吸氢动力学的方法。

2. 发明申请

WO2023057928A1 UNSATURATED HYDROCARBON OLIGOMERIZATION METHOD 审中-公开
公开(公告)号：WO2023057928A1
公开(公告)日：2023-04-13
申请号：PCT/IB2022/059516
申请日：2022-10-05
申请人： UNIWERSYTET WARSZAWSKI , JOZEF STEFAN INSTITUTE
发明人： LESZCZYNSKI, Piotr , GROCHALA, Wojciech , JURCZAKOWSKI, Rafał , POLCZYNSKI, Piotr , KWIATKOWSKI, Piotr , KAZIMIERCZUK, Krzysztof , NAWROCKA, Ewa , JADWISZCZAK, Michal , MAZEJ, Zoran
IPC分类号： C10G29/20 , C10G50/00 , C10G29/205
摘要： An oligomerization method of unsaturated hydrocarbons having double bonds, proceeding in a liquid phase, in an organic medium, in a mixture of substrates mutually exhibiting a double bond system of the [2+2], [4+2] or [2+4] type, using a reaction initiating agent, according to the invention, characterized in that at least one of the substrates has an ionization potential lower than 9.33 eV or a redox potential lower than 2.0 V, at least one of the substrates has at least one double bond involved in the reaction that is not part of an aromatic ring, wherein the other substrate can react via a double bond system of the aromatic ring, as long as it has an electron delocalization energy in the aromatic ring lower than 18 kj/mol per aromatic carbon atom in the structure of that compound, and a solid silver(ll) salt is used as the initiating agent, which leads to the formation of a radical cation from a substrate of a lower ionization energy, which then reacts with another substrate molecule without a deprotonation step for that radical cation, and then transforming the resulting adduct into a neutral molecule with the formation of another radical cation from a substrate of a lower ionization energy, which radical cation further reacts in solution according to the same mechanism, wherein the process is carried out at 270-350 K, preferably at room temperature, in an apparatus made of a material which is chemically inert and inert with respect to silver(ll) salts, preferably in an apparatus with an inner surface made of glass, quartz, fluoropolymers or stainless steel, into which are introduced substrates and an anhydrous organic solvent, which is chemically inert, also with respect to the silver(ll) salt, and then the silver(ll) salt is introduced as an initiating agent, after which the apparatus is closed and the reaction is carried out for at least 24 hours, preferably for at least 72 hours, and then the solid silver compounds are recovered from the post-reaction mixture and subjected to regeneration, and the liquid phase is separated into a light fraction of dimeric cycloaddition products and heavier fractions of oligomeric linear addition products, from which pure products or mixtures of isomeric products are isolated, for example by chromatographic methods. The invention provides an unsaturated hydrocarbon oligomerization method, including the cycloaddition of unsaturated hydrocarbons, which makes it possible to carry out, under ordinary pressure and temperature conditions, reactions between reactants commonly regarded as inert.

3. 发明申请

WO2017109556A1 MEANS FOR CARRYING OUT ELECTROLESS METAL DEPOSITION WITH ATOMIC SUB-MONOLAYER PRECISION 审中-公开
标题翻译：用原子亚单层精度进行化学镀金属的方法
公开(公告)号：WO2017109556A1
公开(公告)日：2017-06-29
申请号：PCT/IB2015/059969
申请日：2015-12-23
申请人： UNIWERSYTET WARSZAWSKI
发明人： JURCZAKOWSKI, Rafal , POLCZYNSKI, Piotr , SZABAT, Hubert , JANUSZEWSKA, Aneta , LEWERA, Adam
IPC分类号： C23C18/16 , C23C18/31 , C23C18/42 , C23C18/44
CPC分类号： C23C18/42 , C23C18/44
摘要： The present invention relates to a method of deposition of thin metal layers on different substrates by electroless chemical method. In the method of the invention, the potential of the plating solution, i.e. a solution from which the metal deposition is carried out, is controlled with a redox buffer. The appropriate plating solution is also disclosed.
摘要翻译：本发明涉及通过无电化学方法在不同衬底上沉积薄金属层的方法。在本发明的方法中，用氧化还原缓冲液控制电镀液，即进行金属沉积的溶液的电位。也披露了适当的电镀液。

4. 发明申请

WO2014020541A1 SELECTIVE CATALYST, PARTICULARLY FOR ELECTROREDUCTION OF OXYGEN, AN ELECTROCHEMICAL SYSTEM CONTAINING THEREOF, AN PALLADIUM-INERT GAS ALLOY AND USE THEREOF, AND A CELL, PARTICULARLY A PHOTO¬ VOLTAIC CELL CONTAINING THEREOF 审中-公开
标题翻译：选择性催化剂，特别是用于电氧化氧，其电化学体系，一种铂 - 气体合金及其用途，以及一种细胞，特别是包含它的光电池
公开(公告)号：WO2014020541A1
公开(公告)日：2014-02-06
申请号：PCT/IB2013/056260
申请日：2013-07-30
申请人： UNIWERSYTET WARSZAWSKI
发明人： LEWERA, Adam , JURCZAKOWSKI, Rafal , POLCZYNSKI, Piotr
IPC分类号： H01M4/92
CPC分类号： H01M4/921 , H01M4/8825 , H01M4/9041 , H01M4/923 , H01M4/925 , H01M4/926 , H01M8/1013 , H01M14/00 , Y02E60/522
摘要： The present invention provides a catalyst comprising a layer of metallic palladium implant¬ ed with an inert gas ions, an electrochemical system containing thereof, a palladium- inert gas alloy stable in the normal conditions, use thereof and a fuel cell containing thereof.
摘要翻译：本发明提供一种催化剂，其包括用惰性气体离子注入的金属钯层，含有它的电化学体系，在正常条件下稳定的钯惰性气体合金，其使用和含有它的燃料电池。

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