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    • 1. 发明申请
    • SYSTEMS AND METHODS FOR SOLAR ENERGY STORAGE, TRANSPORTATION, AND CONVERSION
    • 太阳能储存,运输和转换的系统和方法
    • WO2010009052A2
    • 2010-01-21
    • PCT/US2009050418
    • 2009-07-13
    • UNIV CALIFORNIAVOLLHARDT K PETER CSEGALMAN RACHEL AMAJUMDAR ARUNAVAMEIER STEVEN
    • VOLLHARDT K PETER CSEGALMAN RACHEL AMAJUMDAR ARUNAVAMEIER STEVEN
    • H01L31/042
    • H01L31/0586C09K5/16F28D20/003F28D2020/0026H01G9/20H01M14/005H02S40/38Y02E10/50Y10S204/90
    • A system for converting solar energy to chemical energy, and, subsequently, to thermal energy includes a light-harvesting station, a storage station, and a thermal energy release station. The system may include additional stations for converting the released thermal energy to other energy forms, e.g., to electrical energy and mechanical work. At the light-harvesting station, a photochemically active first organometallic compound, e.g., a fulvalenyl diruthenium complex, is exposed to light and is photochemically converted to a second, higher-energy organometallic compound, which is then transported to a storage station. At the storage station, the high-energy organometallic compound is stored for a desired time and/or is transported to a desired location for thermal energy release. At the thermal energy release station, the high-energy organometallic compound is catalytically converted back to the photochemically active organometallic compound by an exothermic process, while the released thermal energy is captured for subsequent use.
    • 用于将太阳能转化为化学能的系统,以及随后的热能系统包括光收集站,存储站和热能释放站。 该系统可以包括用于将释放的热能转换成其他能量形式的附加站,例如电能和机械作业。 在光收集站,光化学活性的第一有机金属化合物,例如富瓦烯基二钌配合物暴露于光,并被光化学转化为第二较高能量的有机金属化合物,然后将其运送到储存站。 在储存站,高能量有机金属化合物被储存一段所需的时间和/或被运送到期望的位置以释放热能。 在热能释放站,高能有机金属化合物通过放热过程被催化转化回光化学活性的有机金属化合物,同时释放的热能被捕获用于随后的使用。