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    • 1. 发明申请
    • GRANULE AND COMPOSITION CONTAINING SAME
    • 包含其的颗粒和组合物
    • WO2003066793A1
    • 2003-08-14
    • PCT/EP2003/000695
    • 2003-01-23
    • UNILEVER PLCUNILEVER NVHINDUSTAN LEVER LIMITED
    • BATCHELOR, Stephen, NormanCHAPPLE, Andrew, PaulGRATTON, Peter, Leslie
    • C11D3/39
    • C11D3/3935B01J31/1815B01J2531/0258B01J2531/842C11D3/0021C11D3/3932
    • The invention subsists in a water-soluble or water dispersible granule comprising at least 0.05%wt of a macrocyclic (tetra) amido N-donor catalyst and at least 50%wt of a water-dispersible material which is not a catalyst. In typical formulations the water-soluble or water dispersible granule comprises: a) 0.05-10 %wt of a macrocyclic (tetra) amido N-donor catalyst, b) 50-99.85 %wt of a water dispersible material such as a sulphate salt c) 0.1-49.95 %wt of a binder.The present invention has particular application in detergent bleaching, especially for laundry cleaning. Accordingly, the granules are preferably present in a detergent composition which contains a surface-active material, optionally together with detergency builder. The amount of catalyst in the detergent composition is typically sufficient to provide a concentration in the wash liquor of generally 0.005 μm to 100 μm, preferably from 0.025 μM to 50 μM, more preferably from 0.05 μM to 10 μM.
    • 本发明存在于水溶性或水分散性颗粒中,其包含至少0.05重量%的大环四酰胺N-供体催化剂和至少50重量%的不是催化剂的水分散性材料。 在典型的制剂中,水溶性或水分散性颗粒包括:0.05-10重量%的大环四酰胺N-供体催化剂,b 50-99.85重量%的水分散性材料,例如硫酸盐c 0.1-49.95% 本发明特别适用于洗涤剂漂白,尤其适用于洗衣清洁。 因此,颗粒优选存在于含有表面活性材料的洗涤剂组合物中,任选地与洗涤助洗剂一起存在。 洗涤剂组合物中的催化剂的量通常足以使洗涤液中的浓度通常为0.005〜100μm,优选为0.025〜50μm,更优选为0.05〜10μM。
    • 2. 发明申请
    • DETERGENT GRANULE AND ITS MANUFACTURE
    • 洗涤颗粒及其制造
    • WO2011061045A1
    • 2011-05-26
    • PCT/EP2010/066159
    • 2010-10-26
    • UNILEVER NVUNILEVER PLCHINDUSTAN UNILEVER LIMITEDCHAPPLE, Andrew, Paul
    • CHAPPLE, Andrew, Paul
    • C11D3/10C11D3/37C11D11/04C11D1/37
    • C11D11/04C11D1/22C11D1/29C11D1/37C11D3/10C11D3/37
    • A sequential two step process for the manufacture of detergent granules comprising a mixed anionic non-soap surfactant system, the process comprising a first step of dry neutralisation and granulation of surfactant acid with a stoichiometric excess of habit modified Sodium Carbonate, which is a crystal growth modified Sodium Carbonate that comprises a mixture of Sodium Carbonate and polymer, to give a first granule comprising neutralised surfactant acid, polymer and the excess habit modified sodium carbonate, followed by a second step of reagglomeration of the first granule with a paste surfactant, comprising at least 50 wt% of neutralised anionic surfactant, to give the detergent granules comprising a mixed anionic non-soap surfactant system. The invention also relates to a high active detergent granule obtainable by the process.
    • 一种用于制造包含混合阴离子非皂表面活性剂体系的洗涤剂颗粒的连续两步方法,所述方法包括干法中和的第一步,并将表面活性剂酸与化学计量过量的习惯改性的碳酸钠制成,其为晶体生长 改性碳酸钠,其包含碳酸钠和聚合物的混合物,得到包含中和的表面活性剂酸,聚合物和过量习惯改性的碳酸钠的第一颗粒,随后是用糊状表面活性剂重新聚集第一颗粒的第二步骤, 至少50重量%的中和阴离子表面活性剂,得到包含混合阴离子非皂表面活性剂体系的洗涤剂颗粒。 本发明还涉及通过该方法获得的高活性洗涤剂颗粒。
    • 6. 发明申请
    • MODIFIED SODIUM CARBONATE CARRIER MATERIAL
    • 改性碳酸钠载体材料
    • WO2006081930A1
    • 2006-08-10
    • PCT/EP2006/000320
    • 2006-01-13
    • UNILEVER PLCUNILEVER NVHINDUSTAN LEVER LIMITEDCHAPPLE, Andrew, PaulCRAWFORD, Robert, John
    • CHAPPLE, Andrew, PaulCRAWFORD, Robert, John
    • C11D3/10C11D3/37C11D3/33C01D7/40C01D7/06
    • C11D3/3757C01D7/40C11D3/10C11D3/33
    • A process for preparing a modified sodium carbonate carrier material, the process comprising the steps of: (i) preparing an aqueous solution of sodium carbonate; an effective amount of a crystal growth modifier selected from the group comprising polyacrylates, polyaspartates and polyaspartic acids; and optionally one or more anionic and/or nonionic detergent-active compounds, one or more detergency builders and/or one or more further heat-insensitive detergent components; whereby crystal growth-modified sodium carbonate is formed; (ii) drying the solution to form a dry solid carrier material; (iii) optionally incorporating into the dried solid carrier material one or more detergent components in liquid form and/or mixing the dried solid material with one or more solid detergent components. Also, a modified sodium carbonate carrier material comprising: dry inorganic solids consisting of habit modified sodium carbonate; and polyaspartic acid, or a sodium salt of polyaspartic acid, wherein the weight ratio of polyaspartic acid to the dry inorganic solids is in the ratio from 0.5:100 to 10:100.
    • 一种制备改性碳酸钠载体材料的方法,该方法包括以下步骤:(i)制备碳酸钠水溶液; 有效量的选自聚丙烯酸酯,聚天冬氨酸酯和聚天冬氨酸的晶体生长改性剂; 和任选的一种或多种阴离子和/或非离子洗涤剂活性化合物,一种或多种去污助洗剂和/或一种或多种其它热不敏感洗涤剂组分; 由此形成晶体生长改性的碳酸钠; (ii)干燥溶液以形成干固体载体材料; (iii)任选地将干燥的固体载体材料中一种或多种液体形式的洗涤剂组分和/或将干燥的固体材料与一种或多种固体洗涤剂组分混合。 另外,改性碳酸钠载体材料包括:由习惯改性的碳酸钠组成的干燥无机固体; 聚天冬氨酸或聚天冬氨酸的钠盐,其中聚天冬氨酸与干无机固体的重量比为0.5:100至10:100。