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1. 发明申请

WO1993000155A1 A METHOD OF APPLYING MOLECULAR SIEVE CRYSTALS TO A SUPPORT, AND A LOADED SUPPORT THUS OBTAINED 审中-公开
标题翻译：将分子筛晶体应用于支持的方法和获得的负载支持
公开(公告)号：WO1993000155A1
公开(公告)日：1993-01-07
申请号：PCT/NL1992000110
申请日：1992-06-26
申请人： TECHNISCHE UNIVERSITEIT DELFT , JANSSEN, Jacobus, Cornelis , VAN BEKKUM, Herman
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： B01D71/02
CPC分类号： B01D69/105 , B01D67/0051 , B01D71/028 , B01D2323/08 , B01J29/035 , B01J29/40 , B01J29/7607 , B01J29/83 , B01J29/84 , B01J37/0246 , B01J2229/64 , B01J2229/66
摘要： A method of applying molecular sieve crystals to a support, wherein the surface of the support is brought into oxidic condition, whereafter the support is contacted with a solution of the molecular sieve-forming compound or compounds or precursors thereof, whereafter crystallization on the surface is effected.
摘要翻译：将分子筛晶体施加到载体上的方法，其中载体的表面进入氧化条件，然后将载体与分子筛形成化合物或其化合物或其前体的溶液接触，此后在表面上结晶为实现。

2. 发明申请

WO1994014746A1 PROCESS FOR SEPARATING THE ORTHO- AND PARA- ISOMERS OF HYDROXYMANDELIC ACID OR A SALT THEREOF, THE ISOMERS THUS OBTAINED, THE USE OF THE ORTHO-ISOMER FOR THE PREPARATION OF EDDHA 审中-公开
标题翻译：用于分离羟基肉豆蔻酸或其盐的异构体和对位异构体的方法，获得的异构体，ORTHO-ISOMER在制备EDDHA中的用途
公开(公告)号：WO1994014746A1
公开(公告)日：1994-07-07
申请号：PCT/NL1993000277
申请日：1993-12-23
申请人： TECHNISCHE UNIVERSITEIT DELFT , HOEFNAGEL, Anthonius, Johannes , VAN BEKKUM, Herman
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： C07C59/52
CPC分类号： C07C51/48 , C07B57/00 , C07C51/487 , C07C59/52
摘要： The invention relates to a method for separating the ortho- and para-isomers of hydroxymandelic acid or a salt thereof. For that purpose the starting material is a solid mixture of these ortho- and para-isomers in the alkali metal salt form. This mixture is extracted with a polar, aprotic, organic solvent. Then this organic solvent phase is separated from the other phase. The ortho-isomer can be recovered from the polar, aprotic, organic solvent phase and the para-isomer from the other phase.
摘要翻译：本发明涉及一种用于分离羟基扁桃酸或其盐的邻位和对位异构体的方法。为此目的，原料是碱金属盐形式的这些邻位和对位异构体的固体混合物。该混合物用极性非质子有机溶剂萃取。然后将该有机溶剂相与另一相分离。邻位异构体可以从极性，非质子，有机溶剂相和对位异构体从另一相中回收。

3. 发明申请

WO1996036640A2 PROCESS FOR THE PREPARATION OF ALKYL GLYCOSIDES 审中-公开
标题翻译：制备谷氨酰胆碱的方法
公开(公告)号：WO1996036640A2
公开(公告)日：1996-11-21
申请号：PCT/NL1996000205
申请日：1996-05-20
申请人： TECHNISCHE UNIVERSITEIT DELFT , DE GOEDE, Antonius, Theodorus, Johannes, Wilhelmus , VAN DER LEIJ, Ingrid, Gertrude , VAN DER HEIJDEN, Anna, Margaretha , VAN RANTWIJK, Frederik , VAN BEKKUM, Herman
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： C07H15/04
CPC分类号： C07H15/04
摘要： The present invention relates to a process for the preparation of alkyl glycosides by reacting an alcohol with a saccharide or a lower-alkyl glycoside in the presence of a catalyst, wherein the catalyst is a mesoporous silica-based molecular sieve material. This process allows to produce alkylated mono- and disaccharides. Preferably, an MCM-41 type material is used as the catalyst.
摘要翻译：本发明涉及一种通过在催化剂存在下使醇与糖或低级烷基糖苷反应制备烷基糖苷的方法，其中催化剂是介孔二氧化硅基分子筛材料。该方法允许产生烷基化的单糖和二糖。优选使用MCM-41型材料作为催化剂。

4. 发明申请

WO1993022268A1 PROCESS FOR THE PREPARATION OF POLYHYDROXYBENZOPHENONES 审中-公开
标题翻译：制备聚羟基苯并噻唑的方法
公开(公告)号：WO1993022268A1
公开(公告)日：1993-11-11
申请号：PCT/NL1993000095
申请日：1993-05-05
申请人： TECHNISCHE UNIVERSITEIT DELFT , HOEFNAGEL, Anthonius, Johannes , VAN BEKKUM, Herman
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： C07C45/46
CPC分类号： C07C45/46 , C07C45/54 , C07C49/83
摘要： The invention relates to a process for the preparation of polyhydroxybenzophenones by treating benzoic acid or a derivative thereof with a polyhydroxybenzene or a derivative thereof in the presence of a large pore zeolite as a catalyst.
摘要翻译：本发明涉及通过在大孔沸石作为催化剂存在下用多羟基苯或其衍生物处理苯甲酸或其衍生物来制备多羟基二苯甲酮的方法。

5. 发明申请

WO1992013631A1 AN INORGANIC COMPOSITE MEMBRANE COMPRISING MOLECULAR SIEVE CRYSTALS 审中-公开
标题翻译：包含分子晶体的无机复合膜
公开(公告)号：WO1992013631A1
公开(公告)日：1992-08-20
申请号：PCT/NL1992000029
申请日：1992-02-07
申请人： TECHNISCHE UNIVERSITEIT DELFT , GEUS, Eduard, Rudolf , JANSEN, Jacobus, Cornelis , JASPERS, Blandikus, Catharikus , SCHOONMAN, Johannes , VAN BEKKUM, Herman
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： B01D71/02
CPC分类号： B01D69/12 , B01D67/0046 , B01D67/0051 , B01D67/0069 , B01D71/028 , B01D2323/08 , B01J35/065 , B01J37/0246
摘要： Inorganic composite membrane containing molecular sieve crystals, comprising a macroporous support to which molecular sieve crystals and modifications thereof have been applied substantially as a monolayer, said crystals and modifications thereof having been oriented so that, to a substantial extent, the pores of the sieve crystals form a significant included angle with the support surface, there being present between the crystals a gastight matrix, at least gastight to a degree sufficient under practical conditions.
摘要翻译：含有分子筛晶体的无机复合膜包括分子筛结晶及其改性物基本上以单层形式施用的大孔载体，所述晶体及其修饰方向取向为在很大程度上使筛晶的孔与支撑表面形成显着的夹角，在晶体之间存在气密矩阵，至少气密至在实际条件下足够的程度。

6. 发明申请

WO1998006495A1 METHOD FOR PREPARING A COMPOSITE CATALYST 审中-公开
标题翻译：制备复合催化剂的方法
公开(公告)号：WO1998006495A1
公开(公告)日：1998-02-19
申请号：PCT/NL1997000461
申请日：1997-08-11
申请人： TECHNISCHE UNIVERSITEIT DELFT , VAN DER PUIL, Nelleke , CALIS, Hans, Peter, Alexander , OUDSHOORN, Otto, Leonard , JANSEN, Jacobus, Cornelis , VAN BEKKUM, Herman
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： B01J37/02
CPC分类号： B01J37/0246 , B01J2229/60
摘要： The invention relates to the preparation of composite catalysts consisting of a support material and a molecular sieve crystal phase that is present on the surface of the support material. The molecular sieve crystals can, as desired, be provided both on the inside and on the outside of a porous support material. With the method according to the invention a faster preparation of a composite with a higher crystal load and a better accessibility of the individual zeolite crystals can be realized. Further, the invention relates to the use of template on a support material for inducing in situ nucleation.
摘要翻译：本发明涉及由载体材料和存在于载体材料表面上的分子筛结晶相组成的复合催化剂的制备。根据需要，分子筛晶体可以在多孔载体材料的内侧和外侧上提供。利用根据本发明的方法，可以实现具有较高晶体负载和单个沸石晶体更好可接近性的复合材料的更快制备。此外，本发明涉及在载体材料上用于诱导原位成核的模板的用途。

7. 发明申请

WO1995017949A1 A PROCESS FOR TREATING NITROGEN OXIDE-CONTAINING GAS USING A CERIUM ZEOLITE 审中-公开
标题翻译：使用硅藻土处理含氮氧化物的方法
公开(公告)号：WO1995017949A1
公开(公告)日：1995-07-06
申请号：PCT/NL1995000001
申请日：1995-01-02
申请人： TECHNISCHE UNIVERSITEIT DELFT , ITO, Eri , VAN DEN BLEEK, Cornelis, Maria , VAN BEKKUM, Herman , JANSEN, Jacobus, Cornelis , HULTERMANS, Ronald, Johannes , LUGT, Pieter, Martin
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： B01D53/94
CPC分类号： B01D53/8628 , B01D53/9418 , B01D2251/2062 , B01D2255/2027 , B01D2255/2065 , B01D2255/50 , F02B3/06 , Y02T10/24
摘要： The invention relates to a process for treating nitrogen oxide-containing gas substantially having a temperature in the range of 300-560 DEG C, for instance exhaust gases of gas engines or off-gases of power plants, in which the gas is passed over a cerium-containing zeolite catalyst in the presence of substantially an excess of a NH-containing compound, for instance ammonia water or an aqueous urea solution, as reducing agent, whereby excess reducing agent is converted to nitrogen gas. The invention also relates to a process for treating exhaust gases of a diesel engine, in which the exhaust gas is passed over a cerium-containing zeolite catalyst in the presence of a NH-containing compound as reducing agent. The invention further relates to the use of a cerium-containing zeolite catalyst in a selective catalytic reduction process, in which ammonia water or an aqueous urea solution is used as reducing agent, for converting nitrogen oxides in diesel exhaust gas and substantially preventing the oxidation of sulfur dioxide and for converting excess reducing agent.
摘要翻译：本发明涉及一种用于处理基本上具有在300-560℃范围内的温度范围的含氮氧化物的气体的方法，例如燃气发动机或发电厂的废气的废气，其中气体通过在基本上过量的含NH化合物（例如氨水或尿素水溶液）存在下，将含铈沸石催化剂作为还原剂，由此将过量的还原剂转化为氮气。本发明还涉及一种用于处理柴油发动机废气的方法，其中废气在含有NH的化合物作为还原剂存在下通过含铈沸石催化剂。本发明还涉及含铈沸石催化剂在选择性催化还原方法中的用途，其中氨水或尿素水溶液用作还原剂，用于转化柴油机废气中的氮氧化物并基本上防止氧化二氧化硫和用于转化多余的还原剂。

8. 发明申请

WO1994009902A1 CATALYST SYSTEM OF THE STRUCTURED TYPE 审中-公开
标题翻译：结构型催化剂体系
公开(公告)号：WO1994009902A1
公开(公告)日：1994-05-11
申请号：PCT/NL1993000234
申请日：1993-11-05
申请人： TECHNISCHE UNIVERSITEIT DELFT , JANSEN, Jacobus, Cornelis , LEGEIN, Colette, Henriette , CALIS, Hans, Peter, Alexander , VAN BEKKUM, Herman , GERRITSEN, Albert, Willem , VAN DEN BLEEK, Cornelis, Maria
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： B01J37/02
CPC分类号： B01D53/8628 , B01J29/46 , B01J37/0246 , B01J2229/66
摘要： The invention relates to a catalyst system of the structured type, in which a structured support is covered with a layer of molecular sieve crystals and/or modifications thereof. These crystals have substantially the same orientation relative to the support surface. The invention further relates to a reactor in which this catalyst system is incorporated. Finally, the invention relates to a method for the selective reduction of nitrogen oxides utilizing a compound comprising a NH group, in which the catalyst system according to the invention is used.
摘要翻译：本发明涉及一种结构化型催化剂体系，其中结构化载体被一层分子筛晶体覆盖和/或其修饰。这些晶体相对于支撑表面具有基本相同的取向。本发明还涉及其中结合有该催化剂体系的反应器。最后，本发明涉及利用包含NH基团的化合物选择还原氮氧化物的方法，其中使用了本发明的催化剂体系。

9. 发明申请

WO1998021561A1 METHOD AND APPARATUS FOR MEASURING PARTICLE SIZE 审中-公开
标题翻译：用于测量颗粒尺寸的方法和装置
公开(公告)号：WO1998021561A1
公开(公告)日：1998-05-22
申请号：PCT/NL1997000619
申请日：1997-11-12
申请人： TECHNISCHE UNIVERSITEIT DELFT , WILLEMSE, Alexander, Willem , MERKUS, Henk, Gerard , SCARLETT, Brian
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： G01N15/02
CPC分类号： G01J3/4412 , G01N15/0205
摘要： Described is a method for measuring the particle size of ultra-small particles (202) which are suspended in a fluid. Laser light (121, 123) is guided via a first optical path (160) to a suspension (201), and light (125) scattered by the particles (202) in the suspension (201) is guided to an optical detector (140) via a second optical path (170). The optical detector (140) generates an electrical measuring signal (Sm) which is presented to a signal processing device (300). According to the concept of the invention, the signal-to-noise ratio of the measuring signal (Sm) is lowered by presenting to the optical detector (140) a noise signal in the form of a light signal (126) via a third optical path (180), so that the measuring signal (Sm) is always a heterodyne measuring signal. As a result, the uniformity, reliability and accuracy of the measuring signal is improved.
摘要翻译：描述了一种用于测量悬浮在流体中的超小颗粒（202）的粒度的方法。激光（121,123）经由第一光路（160）被引导到悬架（201），并且由悬架（201）中的颗粒（202）散射的光（125）被引导到光学检测器（140））经由第二光路（170）。光检测器（140）产生呈现给信号处理装置（300）的电测信号（Sm）。根据本发明的概念，通过经由第三光学器件向光学检测器（140）呈现光信号（126）形式的噪声信号来降低测量信号（Sm）的信噪比，路径（180），使得测量信号（Sm）总是外差测量信号。结果，提高了测量信号的均匀性，可靠性和精度。

10. 发明申请

WO1998001222A1 ROTARY REACTOR AND USE THEREOF 审中-公开
标题翻译：旋转反应器及其用途
公开(公告)号：WO1998001222A1
公开(公告)日：1998-01-15
申请号：PCT/NL1997000379
申请日：1997-07-03
申请人： TECHNISCHE UNIVERSITEIT DELFT , BAKKER, Wridzer, Jan, Willem , KAPTEIJN, Frederik , MOULIJN, Jacob, Adriaan
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： B01J19/28
CPC分类号： B01J19/2485 , B01J15/005 , B01J19/2425 , B01J19/28 , B01J2208/00017 , C10K1/30
摘要： The invention relates to a rotary reactor consisting of a number of tubular reaction compartments (A), each provided with a first end and a second end, a ceramic first reactor end plate (B) in which said first ends are received, and a second end plate (B) in which said second ends are received, which end plates (B, B) are further provided with means for supplying and/or discharging gases, and wherein against the first end plate a first ceramic flange (D) is arranged of the same material as said first end plate (B), which flange (D) is provided with openings for supply and discharges of gases, which openings correspond at least partly to openings in said first end plate (B), and wherein the assembly of flange (D) and said first end plate (B, B) are disposed against each other under pressure while rotating relative to each other.
摘要翻译：本发明涉及一种由多个管状反应室（A）组成的旋转反应器，每个管状反应室（A）分别设置有第一端和第二端，陶瓷第一反应器端板（B），其中所述第一端被容纳在其中，第二端端板（B），其中所述第二端被接纳，所述端板（B，B）还设置有用于供应和/或排出气体的装置，并且其中抵靠所述第一端板，布置有第一陶瓷凸缘（D）与所述第一端板（B）相同的材料，所述法兰（D）设置有用于供应和排出气体的开口，所述开口至少部分对应于所述第一端板（B）中的开口，并且其中所述组件的凸缘（D）和所述第一端板（B，B）在相对于彼此旋转的同时相对于彼此设置。

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