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1. 发明申请

WO2004037415A2 CATALYST SYSTEMS FOR ETHYLENE OLIGOMERISATION TO LINEAR ALPHA OLEFINS 审中-公开
标题翻译：乙烯齐聚到线型α-烯烃的催化剂体系
公开(公告)号：WO2004037415A2
公开(公告)日：2004-05-06
申请号：PCT/EP2003/010708
申请日：2003-09-23
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric, Johannes, Maria , DE BOER-WILDSCHUT, Marijke , VAN DER HEIJDEN, Harry , VAN ZON, Arie
发明人： DE BOER, Eric, Johannes, Maria , DE BOER-WILDSCHUT, Marijke , VAN DER HEIJDEN, Harry , VAN ZON, Arie
IPC分类号： B01J31/00
CPC分类号： C07C2/32 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/1815 , B01J2231/20 , B01J2531/0213 , B01J2531/0241 , B01J2531/0294 , B01J2531/0297 , B01J2531/842 , B01J2531/845 , C07C2531/22 , C07C11/02
摘要： A catalyst system comprising: (a) one or more bisarylimino pyridine iron or cobalt catalysts; (b) a first co-catalyst compound which is selected from aluminium alkyls, aluminoxanes, and mixtures thereof; and (c) a second co-catalyst compound which comprises one or more compounds of the formula ZnR’ 2 wherein each R’, which may be the same or different, is selected from hydrogen, optionally substituted C 1 -C 20 hydrocarbyl, phenyl, C1, Br, I, SR’’, NR’’ 2, OH, OR’’, CN, NC wherein R’’ , which within the same molecule may the same or different, is C 1 -C 20 hydrocarbyl.
摘要翻译：一种催化剂体系，其包含：（a）一种或多种双芳基亚氨基吡啶铁或钴催化剂; （b）选自烷基铝，铝氧烷及其混合物的第一助催化剂化合物; 和（c）包含一种或多种式ZnR'2化合物的第二助催化剂化合物，其中每个R'可相同或不同，选自氢，任选取代的C C1-C20烃基，苯基，C1，Br，I，SR“，NR”2，OH，OR“，CN，NC其中R” 其在相同分子内可以相同或不同，为C 1 -C 20烃基。

2. 发明申请

WO2008077908A1 LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体催化低级化合物的配体和催化剂体系
公开(公告)号：WO2008077908A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064391
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/6571 , C07F11/00 , B01J31/18
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand having the general Formula (I); P(R 4 J-P(R 1 ) (R 2 )=N(R 3 ) (I) wherein: the R 1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R 2 group is selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups; the R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.
摘要翻译：本发明涉及具有通式（I）的配体; （R 4）（R 4）（R 2）= N（R 3）（I）其中：R 1基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R 2基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4，亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合，通过两个氧，硫或硝基键合到磷原子上亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的原子。

3. 发明申请

WO2008077911A1 LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：用于烯烃单体低级化的配体和催化剂体系
公开(公告)号：WO2008077911A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064398
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/535 , C07F11/00 , B01J31/18
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to a ligand having the general formula (I) : (R 1 ) 2 P-P(R 1 )m(R 2 ) n =N(R3) (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions, with the proviso that m is 0 or 1, n is 1 or 2 and the total of m + n is 2. The present invention also relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands.
摘要翻译：本发明涉及具有通式（I）的配体：（R 1）2 PP（R 1）2（R 1）其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 0-2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基，条件是m为0或1，n为1或2，m + n的总和为2.本发明还涉及使用所述配体的烯烃单体的同时三聚和四聚的催化剂体系和方法。

4. 发明申请

WO2007057455A1 CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体的催化低聚
公开(公告)号：WO2007057455A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068652
申请日：2006-11-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： B01J31/24 , B01J31/18 , B01J31/34 , C07C2/32 , C07C2/36
CPC分类号： C07C2/36 , B01J31/188 , B01J31/34 , B01J2231/20 , B01J2531/62 , C07C2531/14 , C07C2531/24 , C07F9/46
摘要： A catalyst precursor composition comprising: a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I) ; (R 1 ) (R 2 ) P-X-P(R 3 ) (R 4 ) wherein: X is a bridging group of the formula -N(R 5 )-, wherein R 5 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; at least three of R 1 to R 4 are independently selected from optionally substituted aromatic groups, each bearing a polar substituent on at least one of the ortho-positions; and optionally one of R 1 to R 4 is independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; c) a second ligand having the general formula (II) ; (R 1 ' ) (R 2 ' ) P-X'-P(R 3 ' ) (R 4 ' ) wherein: X' is a bridging group as defined for X of the first ligand, component (b) , of general formula (I) ; at least R 1 ' and R 2 ' of R 1 ' to R 4 ' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; and optionally none, one or both of R 3 ' and R 4 ' are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and additional component; d) a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.
摘要翻译：一种催化剂前体组合物，其包含：a）铬，钼或钨的来源; b）具有通式（I）的第一配体; （R 1）（R 2）PXP（R 3）（R 4）其中：X是式-N（R 5） - 的桥连基团，其中R 5选自氢，烃基，取代的烃基，杂烃基，取代的异烃基，甲硅烷基或其衍生物; R 1至R 4中的至少三个独立地选自任选取代的芳族基团，其各自在至少一个邻位上带有极性取代基; 并且任选的R 1至R 4中的一个独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当该基团为芳族时，其不含任何邻位的极性取代基; c）具有通式（II）的第二配体; （R'1）（R 2）P-X'-P（R 3）（R 4）其中：X'是如通式（I）的第一配体组分（b）的X所定义的桥连基团; R 1至R 4的至少R 1'和R 2'独立地选自烃基取代的烃基，杂烃基和取代的杂烃基，条件是当该基团是芳族的时，它在任何邻位不含极性取代基; 并且任选地，R“3”和“R”4中的任一个或两个独立地选自在至少一个邻位取代基上带有极性取代基的任选取代的芳族基团，位置。本发明还涉及包含本发明的催化剂前体组合物和另外的组分的催化剂体系; d）助催化剂。本发明还涉及烯烃单体的三聚和四聚的方法，特别是乙烯对1-己烯和1-辛烯的三聚和四聚，其中该方法包括使至少一种烯属单体与本发明的催化剂体系接触发明。

5. 发明申请

WO2005005354A1 PROCESS FOR PRODUCING LINEAR ALPHA OLEFINS 审中-公开
标题翻译：生产线性ALPHA油脂的方法
公开(公告)号：WO2005005354A1
公开(公告)日：2005-01-20
申请号：PCT/EP2004/051365
申请日：2004-07-06
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , KRAGTWIJK, Eric , ON, Quoc, An , SMIT, Johan, Paul , VAN ZON, Arie
发明人： DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , KRAGTWIJK, Eric , ON, Quoc, An , SMIT, Johan, Paul , VAN ZON, Arie
IPC分类号： C07C2/32
CPC分类号： C07C2/32 , B01J31/143 , B01J31/1815 , B01J2231/20 , B01J2531/842 , B01J2531/845 , C07C2531/14 , C08F10/00 , C08F4/7042
摘要： A process for the production of alpha-olefins comprising reacting ethylene under oligomerisation conditions in the presence of a mixture comprise ng: (a) a metal salt based on Fe (II), Fe (III), Co (II) or Co(III); (b) a pyridine bis-imine ligand; and (c) a co-catalyst which is the reaction product of water with one or more organometallic aluminium compounds, wherein the one or more organometallic aluminium compounds is selected from: (i) ßδ-branched compounds of Formula (I): Al (CH 2 ,-CR 1 R 2 -CH 2 ,-CR 4 R 5 R 6 ) X R 3 Y H Z ; (ii) ßγ-branched compounds of Formula (II) Al (CH 2 -CR 1 R 2 -CR 4 R 5 R 6 ) X R 3 Y H Z and mixtures thereof; wherein when the metal salt and the bis-arylimine pyridine ligand are mixed together they are soluble in aliphatic or aromatic hydrocarbon solvent.
摘要翻译：一种制备α-烯烃的方法，包括在低聚条件下在混合物存在下使乙烯反应，包括：（a）基于Fe（II），Fe（III），Co（II）或Co（III）的金属盐）; （b）吡啶双亚胺配体; 和（c）作为水与一种或多种有机金属铝化合物的反应产物的助催化剂，其中一种或多种有机金属铝化合物选自：（i）式（I）的β支链化合物：Al CH 2，-CR 1 R 2 -CH 2，-CR 4 R 5 R 6）XR 3 YHZ; （ⅱ）式（II）ßg支链化合物Al（CH 2 -CR 1 R 2 -CR 4 R 5 R 6）XR 3 YHZ及其混合物; 其中当将金属盐和双芳基亚胺吡啶配体混合在一起时，它们可溶于脂族或芳族烃溶剂。

6. 发明申请

WO2007057458A1 CATALYTIC PROCESS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体低级化的催化方法
公开(公告)号：WO2007057458A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068659
申请日：2006-11-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07C2/36 , C07C11/107 , B01J31/24
CPC分类号： B01J31/188 , B01J31/143 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07C2/36 , C07C2531/24 , C07F9/46
摘要： A process for the simultaneous trimerization and tetramerization of olefinic monomers , wherein the process comprises contacting at least one olefinic monomer with catalyst system comprising : a) a source of chromium, molybdenum or tungsten; b) a ligand having the general formula (I) ; (R 1 ) 2 P-X-P (R 1 ) m (R 2 )n wherein : X is a bridging group of the formula -N(R 3 )-, wherein R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups and c) a cocatalyst, at a pressure in the range of from below atmospheric to about 40 barg and at a temperature in the range of from about 0 °C to about 120 °C. The present invention further relates to a process for the simultaneous trimerization and tetramerization of ethylene to 1-hexene and 1-octene.
摘要翻译：一种用于烯烃单体的同时三聚和四聚的方法，其中所述方法包括使至少一种烯属单体与催化剂体系接触，所述催化剂体系包括：a）铬，钼或钨的来源; b）具有通式（I）的配体; （R 1）2 PXP（R 1）2（R 2）2（R 2） n其中：X是式-N（R 3 O 3） - 的桥连基团，其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; R 2和R 2独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，和c）助催化剂，其压力范围为低于大气压至约40巴，温度为在约0℃至约120℃的范围内。本发明还涉及一种将乙烯同时三聚和四聚到1-己烯和1-辛烯的方法。

7. 发明申请

WO2006108803A1 CATALYTIC TRIMERIZATION AND TETRAMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体的催化三聚和四聚体
公开(公告)号：WO2006108803A1
公开(公告)日：2006-10-19
申请号：PCT/EP2006/061425
申请日：2006-04-07
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： B01J31/24 , B01J31/18
CPC分类号： B01J31/188 , B01J31/143 , B01J31/2409 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2540/10 , C07C2/36 , C07C2531/24 , C07C11/02 , C07C11/107
摘要： A catalyst precursor composition comprising: a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I) ; (R 1 ) (R 2 ) P-X-P(R 3 ) (R 4 ) (I), wherein: X is a bivalent organic bridging group; R 1 and R 3 are independently selected from, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, with the proviso that when R 1 and R 3 are aromatic groups they do not contain a polar substituent at any of the ortho-positions; R 2 and R 4 are independently selected from optionally substituted aromatic groups, each R 2 and R 4 bearing a polar substituent on at least one of the ortho-positions; and c) a second ligand having the general formula (II) ; (R 1' ) (R 2' )P-X'-P(R 3' ) (R 4' ) (II), wherein: X' is a bridging group of the formula -N(R 5' )-, wherein R 5' is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; and R 1' , R 2' , R 3' and R 4' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups of which at least one of R 1' , R 2' , R 3' and R 4' is substituted with a polar substituent, or R 1' , R 2' , R 3' and R 4' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, wherein any substituents on one or more of R 1' , R 2' , R 3' and R 4' are non-polar. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and additional component; d) a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.
摘要翻译：一种催化剂前体组合物，其包含：a）铬，钼或钨的来源; b）具有通式（I）的第一配体; （R 1）（R 2）（R 4）（R 4）（R 4）（R 4）（R 4） X是二价有机桥连基团; R 1和R 3独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当R 1和 R 3是在任何邻位不包含极性取代基的芳族基团; R 2和R 4独立地选自任选取代的芳族基团，每个R 2和R 4都带有一个在至少一个邻位上的极性取代基; 和c）具有通式（II）的第二配体; （R'1'）（R 2'）P-X'-P（R 3'）（R 4' （II），其中：X'是式-N（R 5'）的桥连基团，其中R 5'选自氢烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; 和R 1'，R 2'，R 3'和R 4'独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，其中R 1，R 2，R 3，R'和R“中的至少一个 > 4'被极性取代基取代，或R 1，R 2，R 3，R 3， SO 4“独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，其中R 1，R 2，R 2， SUP>，R 3'和R 4'是非极性的。本发明还涉及包含本发明的催化剂前体组合物和另外的组分的催化剂体系; d）助催化剂。本发明还涉及烯烃单体的三聚和四聚的方法，特别是乙烯对1-己烯和1-辛烯的三聚和四聚，其中该方法包括使至少一种烯属单体与本发明的催化剂体系接触发明。

8. 发明申请

WO2006005762A1 PROCESS FOR PREPARING LINEAR ALPHA OLEFINS 审中-公开
标题翻译：制备线性ALPHA油脂的方法
公开(公告)号：WO2006005762A1
公开(公告)日：2006-01-19
申请号：PCT/EP2005/053352
申请日：2005-07-13
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , OOSTERVELD, Inge , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , OOSTERVELD, Inge , VAN ZON, Arie
IPC分类号： C07C2/22
CPC分类号： C07C2/08 , C07C1/327 , C07C5/2575 , C07C2523/755 , C07C2527/128 , C07C2531/14 , C07C11/02
摘要： A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of: (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i)reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin, and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.
摘要翻译：制备具有n个碳原子的直链α-烯烃具有2n个碳原子的直链α-烯烃的方法，包括以下步骤：（a）在二聚催化剂存在下将具有n个碳原子的直链α-烯烃二聚化以产生线性内部具有2n个碳原子的烯烃; （b）（i）使催化量的异构化/置换催化剂存在下使步骤（a）中产生的具有2n个碳原子的直链内烯烃与三烷基铝化合物反应，以使线性内烯烃异构化，从所述三烷基铝化合物取代烷基以形成烷基铝化合物，其中至少一个与铝结合的烷基是源自所述线性内烯烃的异构化的直链烷基，和（b）（ii ）使所述烷基铝化合物与α-烯烃反应，任选地在置换催化剂存在下使所述烷基铝化合物的所述直链烷基取代形成具有2n个碳原子的直链α-烯烃。

9. 发明申请

WO2005090371A1 TRANSITION METAL COMPLEXES 审中-公开
标题翻译：过渡金属复合物
公开(公告)号：WO2005090371A1
公开(公告)日：2005-09-29
申请号：PCT/EP2005/051316
申请日：2005-03-22
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , ON, Quoc, An , SMIT, Johan, Paul , VAN ZON, Arie
发明人： DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , ON, Quoc, An , SMIT, Johan, Paul , VAN ZON, Arie
IPC分类号： C07F13/00
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0244 , B01J2531/842 , B01J2531/845 , C07F11/005 , C07F15/025 , C07F15/065 , C08F10/00 , C08F4/60089 , C08F4/69224 , C08F4/7042
摘要： A transition metal complex which is a bis-arylimine pyridine MX n complex, comprising a bis-arylimine pyridine ligand having the formula (I), wherein R 1 -R 5 , R 7 -R 9 , R 12 and R 14 are each, independently, hydrogen, optionally substituted hydrocarbyl, an inert functional group, or any two of R 1 -R 3 and R 7 -R 9 vicinal to one another taken together may form a ring, and R 6 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R 7 or R 4 to form a ring, R 10 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R 9 or R 4 to form a ring, R 11 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R 12 or R 5 to form a ring, R 15 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R 14 or R 5 to form a ring, provided that R 13 and at least one of R 12 and R 14 are independently selected from optionally substituted C 1 -C 30 alkyl, optionally substituted C 4 -C 30 alkyloxy, halogen and optionally substituted C 5 -C 20 aryl, or R 13 taken together with R 12 or R 14 form a ring, or R 12 taken together with R 11 form a ring and R 14 taken together with R 15 form a ring, and provided that at least one of R 12 , R 13 and R 14 is optionally substituted C 4 -C 30 alkyloxy; M is a transition metal atom in particular selected from Ti, V, Cr, Mn, Fe, Co, Ni, Pd, Rh, Ru, Mo, Nb, Zr, Hf, Ta, W, Re, Os, Ir or Pt; n matches the formal oxidation state of the transition metal atom M; and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co)oligomerization, polymerization and dimerization reactions.
摘要翻译：一种二芳基亚胺吡啶MXn络合物的过渡金属络合物，其包含具有式（I）的双芳基亚胺吡啶配体，其中R1-R5，R7-R9，R12和R14各自独立地为氢，任选取代的烃基，惰性官能团或彼此相邻的R 1 -R 3和R 7 -R 9中的任何两个可以一起形成环，并且R 6是氢，任选取代的烃基，惰性官能团，或与R 7或R 4一起形成环，R 10为氢，任选取代的烃基，惰性官能团，或与R 9或R 4一起形成环，R 11为氢，任选取代的烃基，惰性官能团，或与R 12或R 5一起形成环，R 15是氢，任选取代的烃基，惰性官能团，或与R 14或R 5一起形成环，条件是R 13和R 12和R 14中的至少一个独立地选自任选取代的C 1 -C 30烷基，选项烯基取代的C 4 -C 30烷氧基，卤素和任选取代的C 5 -C 20芳基，或R 13与R 12或R 14一起形成环，或R 12与R 11一起形成环，R 14与R 15一起形成环， R 12，R 13和R 14中的至少一个是任选取代的C 4 -C 30烷氧基; M是特别选自Ti，V，Cr，Mn，Fe，Co，Ni，Pd，Rh，Ru，Mo，Nb，Zr，Hf，Ta，W，Re，Os，Ir或Pt中的过渡金属原子; n匹配过渡金属原子M的正式氧化态; X是卤化物，任选取代的烃基，醇盐，酰胺或氢化物。本发明的过渡金属络合物，它们与非配位阴离子的配合物和含有这种络合物的催化剂体系在非极性介质和化学惰性非极性溶剂，特别是芳族烃溶剂中具有良好的溶解性。催化剂体系可用于广泛的（共）低聚，聚合和二聚反应。

10. 发明申请

WO2003011876A1 LIGANDS AND CATALYST SYSTEMS THEREOF FOR ETHYLENE OLIGOMERISATION TO LINEAR ALPHA OLEFINS 审中-公开
标题翻译：乙烯低聚物与线性ALPHA油脂的配体和催化剂体系
公开(公告)号：WO2003011876A1
公开(公告)日：2003-02-13
申请号：PCT/EP2002/008636
申请日：2002-07-29
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , VERHOEF-VAN WIJK, Wilhelmina, Cornelia , ZON, Arie
发明人： DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , VERHOEF-VAN WIJK, Wilhelmina, Cornelia , ZON, Arie
IPC分类号： C07F17/00
CPC分类号： C08F10/00 , C07F15/025 , C07F15/065 , C07F17/00 , Y02P20/582 , C08F4/7042
摘要： Mixed bis-imine pyridine ligands of formula (I), wherein Z 1 , which is different from Z 2 , is an optionally substituted aryl group; and Z 2 comprises an optionally substituted heterohydrocarbyl moiety, or an optionally substituted aryl group in combination with a metal, said optionally substituted aryl group being π-co-ordinated to the metal; Formula (I); mixed bis-imine pyridine MX n complexes comprising a ligand of formula (I), wherein M is a metal atom selected from Fe or Co, n is 2 or 3, and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; mixed [bis-imine pyridine MY p .L n + ] [NC - ]q complexes comprising a ligand of formula (I), wherein Y is a ligand which may insert an olefin, M is a metal atom selected from Fe or Co, NC - is a non-coordinating anion and p+q is 2 or 3, matching the formal oxidation state of said metal atom; L is a neutral Lewis donor molecule; and n = 0, 1, or 2; and processes for the production of alpha olefins from ethylene, using said complexes.
摘要翻译：式（I）的混合双亚胺吡啶配体，其中不同于Z> 2的Z> 1是任选取代的芳基; 并且Z> 2 <包含任选取代的杂烃基部分或与金属组合的任选取代的芳基，所述任选取代的芳基与金属配位; 式（I）; 混合的双亚胺吡啶MX> n <络合物，其包含式（I）的配体，其中M是选自Fe或Co的金属原子，n为2或3，X为卤化物，任选取代的烃基，醇盐，酰胺，或氢化物; 包含式（I）配位体的混合[双亚胺吡啶MY> p <.L> nα+]] [NC'] q络合物，其中Y是可插入烯烃的配体，M是选自Fe或Co的金属原子，NC - 是非配位阴离子，p + q是2或3，与所述金属原子的形式氧化态匹配; L是中性Lewis供体分子; 和n = 0,1或2; 以及使用所述复合物从乙烯生产α-烯烃的方法。

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