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    • 3. 发明申请
    • HYDROGEN STORAGE ALLOYS HAVING A HIGH POROSITY SURFACE LAYER
    • 具有高孔隙度表面层的氢储存合金
    • WO2004094680A1
    • 2004-11-04
    • PCT/US2004/008831
    • 2004-03-23
    • OVONIC BATTERY COMPANY, INC.
    • FETCENKO, Michael, A.OVSHINSKY, Stanford, R.YOUNG, KwoREICHMAN, BenjaminOUCHI, TaiheiKOCH, JohnMAYS, William
    • C22C30/00
    • H01M4/383H01M10/345Y02E60/324Y10S420/90
    • Electrochemical and thermal hydrogen storage alloy compositions that provide superior performance, including an electrochemical hydrogen storage alloy that provides superior low temperature discharge characteristics. The alloy compositions include microstructures in the interface region that are highly porous and that include catalytic metallic particles. The microstructures include a large volume fraction of voids having spherical or channel-like shapes and are sufficiently open structurally to facilitate greater mobility of reactive species within the microstructure and in the vicinity of catalytic metallic particles. Greater accessibility to reactive sites accordingly results. The greater mobility of reactive species and/or the greater density of catalytic particles lead to faster kinetics and improved performance (e.g. higher power), especially at low operating temperatures. The microstructures may be formed through inclusion of a microstructure tuning element in the alloy composition, through control of processing conditions and/or through inclusion of etching steps in the post-formation processing of hydrogen storage alloys.
    • 提供优异性能的电化学和热储氢合金组合物,包括提供优异的低温放电特性的电化学储氢合金。 合金组合物包括界面区域中的高度多孔的微结构,并且包括催化金属颗粒。 微结构包括具有球形或通道状形状的大体积分数的空隙,并且在结构上足够开放以促进反应性物质在微结构内和催化金属颗粒附近的更大迁移率。 因此可以更好地获得反应性网站。 活性物质的较大迁移率和/或更大密度的催化剂颗粒导致更快的动力学和改进的性能(例如更高的功率),特别是在低的操作温度下。 可以通过在合金组合物中包含微结构调谐元件,通过控制加工条件和/或通过在储氢合金的后形成处理中包括蚀刻步骤来形成微观结构。
    • 4. 发明申请
    • ELECTROLOYTIC PRODUCTION OF HYDROGEN AND CARBONATE RECYCLING IN A HYDROGEN PRODUCING REACTION
    • 氢生产反应中氢和碳酸循环的电解生产
    • WO2004061161A2
    • 2004-07-22
    • PCT/US2003/039617
    • 2003-12-12
    • OVONIC BATTERY COMPANY, INC.
    • REICHMAN, BenjaminMAYS, William
    • C25C
    • C01F11/06C01B3/02C01B13/18C25B1/02
    • Methods for producing hydrogen gas from organic substances. According to the methods, hydrogen is produced from an electrochemical reaction of an organic substance with water or a base. The instant methods permit the production of hydrogen at lower operating voltages or lower operating temperatures relative to water electrolysis. Operable organic substances include alcohols, ethers, carboxylic acids, aldehydes, and ketones. In a preferred embodiment, hydrogen gas is produced from an electrochemical reaction of methanol in the presence of a base such as NaOH or KOH. A process for producing hydrogen gas from a reaction of an organic substance and a base with a recycling of a carbonate or bicarbonate by-product and regeneration of the base. In one embodiment, reaction of an organic substance and a base produces hydrogen gas and a metal carbonate. The instant invention provides recycling of the metal carbonate by-product. In another embodiment, a bicarbonate by product is formed by a hydrogen producing reaction of an organic substance and a base and bicarbonate recovery occurs by heating the bicarbonate to form a carbonate and recycling according to the instant carbonate recycling process.
    • 从有机物质生产氢气的方法。 根据该方法,由有机物与水或碱的电化学反应产生氢。 本方法允许相对于水电解在较低工作电压或较低工作温度下生产氢。 可操作的有机物质包括醇,醚,羧酸,醛和酮。 在优选的实施方案中,在碱例如NaOH或KOH的存在下,由甲醇的电化学反应产生氢气。 从有机物和碱的反应产生氢气的方法,其中碳酸盐或碳酸氢盐副产物的再循环和碱的再生。 在一个实施方案中,有机物质和碱的反应产生氢气和金属碳酸盐。 本发明提供了金属碳酸盐副产物的再循环。 在另一个实施方案中,产物的碳酸氢盐通过有机物质和碱的产生氢的反应形成,碳酸氢盐回收是通过加热碳酸氢盐形成碳酸盐并根据本发明的碳酸盐回收方法循环而发生的。