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1. 发明申请

WO2009099436A1 CURABLE COMPOSITIONS PREPARED FROM MULTIFUNCTIONAL AND HYBRID N-VINYLFORMAMIDE COMPOUNDS 审中-公开
标题翻译：多功能和混合N-乙烯酰胺化合物制备的可固化组合物
公开(公告)号：WO2009099436A1
公开(公告)日：2009-08-13
申请号：PCT/US2008/052983
申请日：2008-02-05
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , MUSA, Osama, M. , SRIDHAR, Laxmisha, M. , KONG, Shengqian
发明人： MUSA, Osama, M. , SRIDHAR, Laxmisha, M. , KONG, Shengqian
IPC分类号： C08F12/28 , C08L33/24 , C08K3/00
CPC分类号： C09D139/02 , C08F212/34 , C08F226/02 , C08F290/06 , C08F2222/1013 , C08F222/40 , C08F222/12
摘要： A curable composition comprises a multi-functional N-vinylformamide compound and/or a hybrid N-vinylformamide compound and an initiator, optionally, an additional curable compound; and optionally, a filler. The hybrid N-vinylformamide compound has a second reactive functionality in addition to N-vinylformamide functionality selected from the group consisting of acrylate, methacrylate, cyanoacrylate, maleimide, cinnamyl, maleate, fumarate, epoxy, oxetane, silane, styrenic, benzoxazine, oxazoline, vinyl ester, vinyl ether, and combinations of these. These multi-functional and hybrid N-vinylformamide compounds are prepared through an alkylation procedure employing either cesium carbonate or potassium t-butoxide as base to deprotonate, from the nitrogen atom, the hydrogen atom bonded to the nitrogen atom. Reaction schemes include: formulae (I) and (II) in which n = 2 to 100; v is 1 to 100; w is 1 to 10; Y is an aliphatic or aromatic hydrocarbon {including those with heteroatoms); X is a second reactive functionality; and L is a leaving group; and each L and X present can be the same or different.
摘要翻译：可固化组合物包含多官能N-乙烯基甲酰胺化合物和/或杂化N-乙烯基甲酰胺化合物和引发剂，任选另外的可固化化合物; 和任选的填料。杂化N-乙烯基甲酰胺化合物除了选自丙烯酸酯，甲基丙烯酸酯，氰基丙烯酸酯，马来酰亚胺，肉桂基，马来酸酯，富马酸酯，环氧，氧杂环丁烷，硅烷，苯乙烯，苯并恶嗪，恶唑啉等的N-乙烯基甲酰胺官能团之外，具有第二反应性官能团。乙烯基酯，乙烯基醚以及它们的组合。这些多功能和杂化的N-乙烯基甲酰胺化合物是通过烷基化方法制备的，其使用碳酸铯或叔丁醇钾作为碱，从氮原子去除与氮原子键合的氢原子。反应方案包括：式（I）和（II）其中n = 2至100; v为1〜100; w为1〜10; Y是脂族或芳族烃（包括具有杂原子的烃）; X是第二反应性官能团; L是离去组; 并且存在的每个L和X可以相同或不同。

2. 发明申请

WO2008048733A1 1,3-DIPOLAR CYCLOADDITION OF AZIDES TO ALKYNES 审中-公开
标题翻译：氮氧化物的1,3-二醇环烷基
公开(公告)号：WO2008048733A1
公开(公告)日：2008-04-24
申请号：PCT/US2007/074449
申请日：2007-07-26
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , MUSA, Osama, M. , SRIDHAR, Laxmisha, M. , YUAN-HUFFMAN, Qingwen, Wendy
发明人： MUSA, Osama, M. , SRIDHAR, Laxmisha, M. , YUAN-HUFFMAN, Qingwen, Wendy
IPC分类号： C08G73/08 , C08G73/02 , C08F2/02
CPC分类号： C08G73/0605 , C08G73/0644 , C09J179/04
摘要： A process for the bulk polymerization, in the absence of any solvent, of a reactant containing azide functionality and a reactant containing a terminal alkyne functionality, in the presence of Cu (I) catalyst or in the presence of a Cu(II) catalyst without a reducing agent, is described. Polymerization can be achieved at temperatures less than 100 °C, which is suitable for low temperature cures. A controlled synthesis for low molecular weight oligomers is disclosed.
摘要翻译：在Cu（I）催化剂存在下或在不存在Cu（I）催化剂的情况下，在不存在任何溶剂的情况下本体聚合含有叠氮官能团的反应物和含有末端炔官能团的反应物的方法，描述了还原剂。可以在低于100℃的温度下实现聚合，适用于低温固化。公开了低分子量低聚物的受控合成。

3. 发明申请

WO2004101542A1 OXETANE COMPOUNDS CONTAINING CINNAMYL FUNCTIONALITY 审中-公开
标题翻译：含有CINNAMYL功能的OXETANE化合物
公开(公告)号：WO2004101542A1
公开(公告)日：2004-11-25
申请号：PCT/US2004/012490
申请日：2004-04-21
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION
发明人： MUSA, Osama, M.
IPC分类号： C07D305/06
CPC分类号： C07D305/06
摘要： These compounds contain an oxetane functionality and a cinnamyl functionality. The oxetane functionality is homopolymerizable in reactions that can undergo cationic or anionic ring opening, and the cinnamyl functionality is polymerizable with compounds such as electron acceptor compounds. The dual functionality allows for dual cure processing. The generic structure of such compounds is: in which R is a methyl or ethyl group, X and Y independently are a direct bond, or an ether, ester, or carbamate group, and Q is a divalent hydrocarbon (which may contain heteroatoms of N, O, or S), provided that X and Y will not both be direct bonds in the same molecule.
摘要翻译：这些化合物含有氧杂环丁烷官能团和肉桂基官能团。氧杂环丁烷官能度可以在可以经历阳离子或阴离子开环的反应中是均聚的，并且肉桂基官能团可用化合物如电子受体化合物聚合。双重功能允许双重固化处理。这种化合物的一般结构是：其中R是甲基或乙基，X和Y独立地是直接键，或醚，酯或氨基甲酸酯基，Q是二价烃（其可以含有N的杂原子，O或S），条件是X和Y两者都不会同一分子中的直接键。

4. 发明申请

WO2004101541A1 OXETANE COMPOUNDS CONTAINING STYRENIC FUNCTIONALITY 审中-公开
标题翻译：含有STYRENIC功能的OXETANE化合物
公开(公告)号：WO2004101541A1
公开(公告)日：2004-11-25
申请号：PCT/US2004/012489
申请日：2004-04-21
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION
发明人： MUSA, Osama, M.
IPC分类号： C07D305/06
CPC分类号： C07D305/06
摘要： These compounds contain an oxetane functionality and a styrenic functionality. The oxetane functionality is homopolymerizable in reactions that undergo cationic or anionic ring opening, and the styrenic is polymerizable with compounds such as electron acceptor compounds. The dual functionality allows for dual cure processing. The compounds will have the structure in which R 1 is a methyl or ethyl group; R 2 and R 3 are H or a methyl or ethyl group; R 4 is a direct bond or a divalent hydrocarbon; X and Y are independently a direct bond or an ether, ester, amide, or carbamate group, provided both X and Y are not a direct bond; Q is a divalent hydrocarbon (which may contain heteroatoms of N, 0, or S); and G is -OR 1 , -SR 1 , or -N(R2)(R3), in which R 1 , R 2 and R 3 are as described above.
摘要翻译：这些化合物含有氧杂环丁烷官能团和苯乙烯官能团。氧杂环丁烷官能度在经历阳离子或阴离子开环的反应中是可均聚的，苯乙烯类可与化合物如电子受体化合物一起聚合。双重功能允许双重固化处理。该化合物具有其中R 1为甲基或乙基的结构; R 2和R 3是H或甲基或乙基; R 4是直接键或二价烃; X和Y独立地是直接键或醚，酯，酰胺或氨基甲酸酯基，只要X和Y不是直接键; Q是二价烃（其可以含有N，O或S的杂原子）; 并且G是-OR 1，-SR 1或-N（R 2）（R 3），其中R 1，R 2和R 3如上所述。

5. 发明申请

WO2009078878A1 COMPOUNDS HAVING A DIPHENYL OXIDE BACKBONE AND MALEIMIDE FUNCTIONAL GROUP 审中-公开
标题翻译：具有二氧化钛氧化物和氧化物官能团的化合物
公开(公告)号：WO2009078878A1
公开(公告)日：2009-06-25
申请号：PCT/US2007/088130
申请日：2007-12-19
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , MUSA, Osama, M. , MARR, Brian
发明人： MUSA, Osama, M. , MARR, Brian
IPC分类号： C07D207/452
CPC分类号： C07D207/452 , H01L2924/0002 , H01L2924/09701 , H01L2924/00
摘要： A compound having a diphenyl oxide backbone, and pendant from the backbone at least one hydrocarbon chain, the hydrocarbon chain containing an ester functionality and being terminated with a maleimide functional group is prepared from the reaction of diphenyl oxide, formaldehyde or paraformaldehyde, and a compound containing both carboxylic acid and maleimide functionality. Exemplary compounds include: formula (I) and formula (II) in which m and n are independently an integer from 1 to 100, provided that n is greater than m.
摘要翻译：具有二苯氧基骨架的化合物和从骨架悬挂至少一个烃链，含有酯官能团的烃链和用马来酰亚胺官能团封端的化合物是由二苯醚，甲醛或多聚甲醛和化合物含有羧酸和马来酰亚胺官能团。示例性化合物包括式（I）和式（II），其中m和n独立地为1至100的整数，条件是n大于m。

6. 发明申请

WO2009014541A1 ALCOHOLS CONTAINING IMIDE MOIETIES AND REACTIVE OLIGOMERS PREPARED THEREFROM 审中-公开
标题翻译：含有其他物质的反应物和反应性低聚物
公开(公告)号：WO2009014541A1
公开(公告)日：2009-01-29
申请号：PCT/US2007/074463
申请日：2007-07-26
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , MUSA, Osama, M. , MARR, Brian
发明人： MUSA, Osama, M. , MARR, Brian
IPC分类号： C07D403/12 , C07D403/14
CPC分类号： C07D403/14 , C07D209/48 , C07D403/06 , C07D403/12
摘要： This invention relates to oligomeric compounds that are prepared by the reaction of a dianhydride with an amiπo-alcohol to yield an imide-diol intermediate, which is then esterified with a carboxylic acid to form a reactive oligomer. An exemplary reaction scheme is in formula (I).
摘要翻译：本发明涉及通过二酐与氨基醇反应制得的低聚化合物，得到酰亚胺二醇中间体，然后用羧酸酯化形成反应性低聚物。示例性反应方案在式（I）中。

7. 发明申请

WO2004101646A1 ADHESIVE COMPOSITIONS CONTAINING HYBRID OXETANE COMPOUNDS 审中-公开
标题翻译：含有混合氧化合物的粘合剂组合物
公开(公告)号：WO2004101646A1
公开(公告)日：2004-11-25
申请号：PCT/US2004/012394
申请日：2004-04-21
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION
发明人： MUSA, Osama, M.
IPC分类号： C08G65/18
CPC分类号： B07B1/46 , B07B1/4609 , B07B1/4618 , C08K5/14 , C08K5/1525 , C09J4/06 , C08L21/00 , C08F279/02
摘要： Compositions for use as adhesives, coatings or encapsulants contain an oxetane functionality and an electron acceptor or an electron donor functionality, and can be represented by the formula (I ) in which R 1 is a methyl or ethyl group, R 2 is a divalent hydrocarbon, X and Y are independently a direct bond, or an ether, ester, or carbamate functionality, Q is a divalent hydrocarbon, and E is an electron donor or electron acceptor functionality.
摘要翻译：用作粘合剂，涂料或密封剂的组合物含有氧杂环丁烷官能团和电子受体或电子给体官能团，并且可以由式（I）表示，其中R 1是甲基或乙基，R 2，是二价烃，X和Y独立地是直接键，或醚，酯或氨基甲酸酯官能团，Q是二价烃，E是电子给体或电子受体官能团。

8. 发明申请

WO2009070172A1 CURABLE RESINS CONTAINING ACETAL, KETAL, ACETAL ESTER, OR KETAL ESTER LINKAGES 审中-公开
标题翻译：含有乙醛，乙醇，乙醇或乙醇的可固化树脂
公开(公告)号：WO2009070172A1
公开(公告)日：2009-06-04
申请号：PCT/US2007/086083
申请日：2007-11-30
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , MUSA, Osama, M. , ZHANG, Xinnan
发明人： MUSA, Osama, M. , ZHANG, Xinnan
IPC分类号： C07D403/12 , C07D405/12
CPC分类号： C07D207/448
摘要： Thermosetting maieimide, cinnamyl, and styrenic resins contain acetal, ketal, acetai ester, or ketal ester linkages, which linkages are degradable when subjected to heat or acid. The inventive compounds can be used in thermosetting compositions that may need to be reworked, formula (1).
摘要翻译：热固性马来酰亚胺，肉桂基和苯乙烯树脂含有缩醛，缩酮，乙酸酯或缩酮酯键，当经受热或酸时，该键可降解。本发明化合物可用于可能需要重新加工的热固性组合物，式（1）。

9. 发明申请

WO2009067112A1 REDOX-INDUCED CATIONICALLY POLYMERIZABLE COMPOSITIONS WITH LOW CURE TEMPERATURE 审中-公开
标题翻译：具有低温温度的红外诱导的聚合可聚合组合物
公开(公告)号：WO2009067112A1
公开(公告)日：2009-05-28
申请号：PCT/US2007/085272
申请日：2007-11-20
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , SRIDHAR, Laxmisha, M. , MUSA, Osama, M.
发明人： SRIDHAR, Laxmisha, M. , MUSA, Osama, M.
IPC分类号： C08G61/12 , C08L61/00 , C08L27/00 , C08L29/00
CPC分类号： C08F4/40
摘要： A cationically polymerizable composition comprising (i) a cationically polymerizable resin, (ii) an onium salt, (iii) an azo or peroxide initiator, exhibits a lower cure temperature upon the addition of (iv) a catalytic or substoichiometric amount of an electron -rich vinyl resin to the reaction.
摘要翻译：一种阳离子聚合性组合物，其包含（i）阳离子聚合性树脂，（ii）鎓盐，（iii）偶氮或过氧化物引发剂，在加入（iv）催化或亚化学计量量的电子 - 富乙烯基树脂进行反应。

10. 发明申请

WO2005083771A1 ASSEMBLY OF A SEMICONDUCTOR DIE ATTACHED TO SUBSTRATE WITH OXAZOLINE DERIVATIVE BEARING AN ELECTRON DONOR OR ACCEPTOR FUNCTIONALITY 审中-公开
标题翻译：用氧化硅衍生物负载承载电子或受体功能的半导体器件组装
公开(公告)号：WO2005083771A1
公开(公告)日：2005-09-09
申请号：PCT/US2004/004736
申请日：2004-02-17
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , MUSA, Osama, M. , XHANG, Ruzhi
发明人： MUSA, Osama, M. , XHANG, Ruzhi
IPC分类号： H01L21/58
CPC分类号： C07D263/10 , C07D263/14 , C07D413/12 , C08G61/00 , C08G61/02 , C08G73/02 , H01L21/563 , H01L23/293 , H01L24/29 , H01L24/83 , H01L2224/29 , H01L2224/29101 , H01L2224/2919 , H01L2224/2929 , H01L2224/29324 , H01L2224/29339 , H01L2224/29344 , H01L2224/29347 , H01L2224/29355 , H01L2224/29364 , H01L2224/29369 , H01L2224/29386 , H01L2224/29388 , H01L2224/29393 , H01L2224/73203 , H01L2224/8385 , H01L2924/00013 , H01L2924/01005 , H01L2924/01006 , H01L2924/01011 , H01L2924/01013 , H01L2924/01015 , H01L2924/0102 , H01L2924/01029 , H01L2924/01046 , H01L2924/01047 , H01L2924/0105 , H01L2924/01056 , H01L2924/01078 , H01L2924/01079 , H01L2924/01082 , H01L2924/014 , H01L2924/0665 , H01L2924/07802 , H01L2924/10253 , H01L2924/00 , H01L2924/00014 , H01L2924/04642 , H01L2924/0503 , H01L2924/05432 , H01L2224/29099 , H01L2224/29199 , H01L2224/29299
摘要： An assembly of a semiconductor die attached to a substrate is made with a composition comprising compounds that contain an oxazoline functionality and an electron acceptor or an electron donor functionality. Electron donor functionalities include styrenic, cinnamyl, and vinyl ether groups. Electron acceptor functionalities include maleimide, acrylate, fumarate, and maleate groups. An exemplary compound has the structure: formula (I).
摘要翻译：用包含含有恶唑啉官能团和电子受体或电子供体官能团的化合物的组合物制成附着于基底的半导体管芯的组件。电子给体官能团包括苯乙烯，肉桂基和乙烯基醚基团。电子受体官能团包括马来酰亚胺，丙烯酸酯，富马酸酯和马来酸酯基团。示例性化合物具有以下结构：式（I）。

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