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1. 发明申请

WO2010045928A2 METHOD FOR THE CATALYTIC CONVERSION OF SOLID-LIKE HYDROCARBONS 审中-公开
标题翻译： PROCESS FOR类似于固体烃类催化反应
公开(公告)号：WO2010045928A2
公开(公告)日：2010-04-29
申请号：PCT/DE2009001457
申请日：2009-10-17
申请人： HOCHSCHULE MERSEBURG FH , SEITZ MATHIAS , SCHWIEGER WILHELM , SCHWAB ANDREAS VEIT
发明人： SEITZ MATHIAS , SCHWIEGER WILHELM , SCHWAB ANDREAS VEIT
IPC分类号： C10G1/00
CPC分类号： C10G1/002 , C10G1/02 , C10G1/08 , C10G1/086 , Y02E50/14 , Y02E50/32
摘要： The invention relates to a method for the catalytic conversion of solid-like hydrocarbons, wherein the solid-like hydrocarbons pass through grinding, drying, and primary and secondary reaction processes. The grinding bodies are molded bodies having a carrier material which forms a molded body core and to which the catalyst material is applied. The solid-like hydrocarbons to be converted and the catalytically active material, which is present in the form of the molded bodies, are brought into contact with each other. According to the invention, the grinding, drying, and primary and secondary reaction processes take place simultaneously in that the solid matter is dried and ground simultaneously, a solid-solid reaction of organic solid matter of the solid-like hydrocarbons and solid catalyst is carried out, and the developing gaseous or liquid products are further cleaved and/or converted in secondary reactions on the catalyst surface. The invention is used in particular for the material use of brown coals and/or biomass and/or plastics, such as thermoset materials and thermoplastics, and/or oil coke and/or oil sands and/or oil shale in refining plants.
摘要翻译：本发明涉及一种用于固体状烃的催化转化方法，其中通过研磨，干燥，原发性和继发性反应过程中的固体状烃。在这种情况下，被设置为具有芯体的模具形成支撑材料的研磨元件成形体，被施加到催化剂材料。反应后的状固体烃和催化活性物质，这是在模体的形状被带入彼此接触。根据本发明的运行由固体材料研磨，干燥，同时从初级和次级反应过程同时干燥并研磨，有机固体在催化剂表面进一步进行固体状烃和固体催化剂和退出气态或液态产品，在二次反应的固 - 固反应被分割和/或转化。本发明特别用于在涂布生产线褐煤和/或生物量和/或塑料，如热固性树脂和热塑性塑料，和/或石油焦炭和/或油砂和/或油页岩的回收。

2. 发明申请

WO2009138223A3 ALUMINUM-CONTAINING SUBSTRATE COMPRISING A MICROPOROUS LAYER OF AN ALUMINUM PHOSPHATE ZEOLITE, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF 审中-公开
标题翻译：铝 - 体基材随着对生产和使用的铝磷酸盐沸石的微孔层，方法
公开(公告)号：WO2009138223A3
公开(公告)日：2010-02-25
申请号：PCT/EP2009003408
申请日：2009-05-13
申请人： SORTECH AG , BAUER JUERGEN , HERRMANN RALPH , SCHWIEGER WILHELM , AVHALE ABHIJEET
发明人： BAUER JUERGEN , HERRMANN RALPH , SCHWIEGER WILHELM , AVHALE ABHIJEET
IPC分类号： C23C18/12
CPC分类号： C23C18/1212 , B01J29/83 , B01J29/85 , B01J35/10 , B01J35/1057 , B01J35/109 , B01J37/0215 , B01J37/0244 , B01J37/0246 , B01J2229/62 , B01J2229/66 , C23C18/1225 , C23C18/1241 , C23C18/1254
摘要： An aluminum-containing substrate is described that comprises at least one superficially applied microporous layer of an aluminum phosphate zeolite (ALPO) as well as other layers. Said aluminum-containing substrate is characterized in that the microporous layer of the aluminum phosphate zeolite represents a primer coating on which a microporous or mesoporous secondary material is located which differs from the material of the primer coating. Said aluminum-containing substrate is produced in a particularly advantageous manner according to a method in which 1. an aluminum-containing substrate is hydrothermally treated in an aqueous suspension containing at least phosphorus as a network-forming element, and a microporous primer coating of an aluminum phosphate zeolite is formed on the substrate by means of an in situ crystallization process, especially the molar ratio between the network-forming aluminum that is deficient in the aqueous suspension and the sum of all network-forming elements in the aqueous suspension being less than 0.5 such that the aluminum required for compensating the deficiency is removed from the aluminum-containing substrate, and 2. a microporous or mesoporous secondary material is formed on the microporous primer coating by subjecting the aluminum-containing substrate that comprises the microporous primer coating to another treatment in an aqueous suspension containing the network-forming elements required for forming the porous secondary material. The described aluminum-containing substrate is particularly suitable as a heat exchanger, as a catalytic reactor, or as a component in heat transformation technology with an anti-corrosive or anti-fouling effect.
摘要翻译：本发明公开了具有磷酸铝沸石（ALPO）和另外的层的至少一个表面涂覆微孔层的含铝基材。此含铝基材的特征在于，所述磷酸铝沸石的微孔层是在其上从主层或微中孔材料的材料独特的是次要的初级层。此含铝基材是通过根据一方法制备特别有利地，其在所述第一基板中至少含有作为形成网络的元件的水性悬浮液中的荧光体水热处理，并通过磷酸铝沸石的微多孔初级层的原位结晶而形成在其上，特别是含有铝的在缺乏形成网络的铝到所有存在于水性悬浮液成网元素的总和的存在于水性悬浮液之间的摩尔比小于0.5，使得所需的铝被认为以补偿下冲的含铝基材，和2.将微孔或中孔的二次材料被通过包括在水性悬浮液中的微多孔性含铝基材，以进一步处理所述主层的主微孔层上由形成，含有用于多孔次要材料的形成了必要的成网元素进行。描述的含铝基材特别适合作为热交换器，作为催化反应器，或者如在热转化技术具有腐蚀作用或防污效果的成分。

3. 发明申请

WO2010099919A3 METHOD FOR FORMING AN ALUMINOSILICATE-ZEOLITE LAYER ON A METAL SUBSTRATE, THE COATED SUBSTRATE AND THE USE THEREOF 审中-公开
标题翻译：法形成的硅铝酸盐沸石层上的金属衬底，所述涂覆的基材及其使用
公开(公告)号：WO2010099919A3
公开(公告)日：2010-11-18
申请号：PCT/EP2010001255
申请日：2010-03-01
申请人： SORTECH AG , HERRMANN RALPH , SCHWIEGER WILHELM , BAUER JUERGEN
发明人： HERRMANN RALPH , SCHWIEGER WILHELM , BAUER JUERGEN
IPC分类号： C23C18/12
CPC分类号： C23C18/1212 , B01J20/165 , B01J20/3238 , B01J29/06 , C23C18/1241 , C23C22/66
摘要： Described is a method for forming an aluminosilicate-zeolite layer on an aluminum-containing substrate which is transferred into an aqueous reaction dispersion containing silicon and optionally aluminum as network forming elements, wherein, irrespective of whether or not aluminum is present in the aqueous reaction dispersion, the molar ratio of the aluminum in the aqueous reaction dispersion, optionally 0, to the sum of said network forming elements contained in the aqueous reaction dispersion ranges between 0 and about 0.4, the aqueous reaction dispersion containing the aluminum-containing substrate is heated, aluminum is extracted from the aluminum-containing substrate for the aluminosilicate-zeolite formation process, and the layer of an aluminosilicate-zeolite is formed on the aluminum-containing substrate by in-situ crystallization. Said method is characterized in that a layer of an aluminum-rich aluminosilicate-zeolite having an Si/Al ratio of lower than 5 is formed on the aluminum-containing substrate by introducing into the aqueous reaction dispersion a Si source in an amount sufficient for forming the Si/Al ratio of lower than 5, an Al source that meets the requirements of the molar deficit, and the aluminum-containing metal substrate, wherein the pH value of the aqueous reaction dispersion is alkalinized and the layer of the aluminum-rich aluminosilicate-zeolite is crystallized onto the aluminum-containing metal substrate. By means of said method, advantageous coatings made of an aluminum-rich aluminosilicate-zeolite are obtained on an aluminum-containing metal substrate. This product can be used in advantageous applications, in particular in sorption-based application areas such as for heterogeneous catalysis, separation and cleaning processes, sorption heat pumps, in conjunction with immobilized catalysts and in microreaction techniques.
摘要翻译：公开了一种用于含铝的基材，将其转化为其中硅和任选铝被包括作为成网元素的含水反应分散体中，而不管上形成硅铝酸盐沸石层的方法是否铝存在于水性反应分散体或不中，在含水反应分散体，任选地0铝之间的摩尔比，形成包含在0和约0.4之间的水性反应分散体元素所指定的网络的总和，加热所述水性反应分散体中，含铝基材含有和含铝基材的硅铝酸盐通过原位结晶在含铝基材上形成铝提取沸石形成过程和铝硅酸盐沸石层。此方法的特征在于通过以形成所述Si / Al比施加到水性反应分散体中的Si源在所述含铝基材上形成的小于5的Si / Al比的富铝的铝硅酸盐沸石的层被引入小于5足够量和满足摩尔过量的要求，以及对含铝金属基材的Al源，其中所述水性反应分散液的pH调成碱性及富铝的铝硅酸盐沸石的金属的上层的含铝底物结晶。通过该方法获得在含铝金属基材上的富铝铝硅酸盐沸石的有利涂层。该产品可进行有益的用途，特别是在sorptionsbasierenden应用，例如，用于非均相催化，分离和清洗过程，在吸附热泵，在与固定化的催化剂连接，以及在微反应技术。

4. 发明申请

WO2006048211A2 METHOD FOR PRODUCTION OF A SUBSTRATE COATED WITH A ZEOLITE LAYER 审中-公开
标题翻译：工艺生产具有涂有一层基底沸石
公开(公告)号：WO2006048211A2
公开(公告)日：2006-05-11
申请号：PCT/EP2005011610
申请日：2005-10-29
申请人： SORTECH AG , SCHWIEGER WILHELM , HERRMANN RALPH , THANGARAJ SELVAM , REDDY MARTHALA , SCHEFFLER FRANZISKA , SCHMIDT FERDINAND , MITTELBACH WALTER , HENNING HANS-MARTIN , BAUER JUERGEN
发明人： SCHWIEGER WILHELM , HERRMANN RALPH , THANGARAJ SELVAM , REDDY MARTHALA , SCHEFFLER FRANZISKA , SCHMIDT FERDINAND , MITTELBACH WALTER , HENNING HANS-MARTIN , BAUER JUERGEN
IPC分类号： C23C18/12
CPC分类号： C23C18/1212 , B01J29/85 , B01J2229/64 , B01J2229/66 , C23C18/1241 , C23C18/1245 , C23C18/1254 , Y10T428/249978
摘要： The invention relates to a method for production of a zeolite layer on a substrate containing metal, comprising the following method steps: production of an aqueous suspension, comprising several components, one component comprises at least one cross-linking element from the third, fourth or fifth main group of the periodic table, the substrate containing metal comprises at least one of the cross-linking elements, introduction of the substrate containing metal to the aqueous suspension, heating the aqueous suspension and the substrate containing the metal present therein for the in-situ crystallisation of a zeolite layer on the substrate containing metal, whereby the cross-linking elements in the substrate containing metal are extracted and included in the zeolite layer, a cross-linking element present in the suspension for formation of the zeolite layer is present at a concentration so low that a crystallisation in the suspension is largely or completely avoided and said element is principally provided by the substrate.
摘要翻译：本发明涉及一种用于在含基底金属制备的沸石层，其包括步骤： - 制备水性悬浮液，其包括若干部件; - 至少一个部件包括选自周期表的第三，第四或第五主族网络形成元件; - 含金属的衬底包括形成网络的元件中的至少一者; - 引入含金属到水性悬浮液中的底物; - 加热该水性悬浮液和含有金属存在于其中的底物包含金属的基板，其中所述包含金属的基板成网元素从取出并安装在沸石层上的沸石层的原位结晶; -a存在于悬浮液中形成网络的元件以形成沸石层是在不足之前，所以在该悬浮液结晶大部分或完全避免，并且由基板主要提供这个元素。

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