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    • 3. 发明申请
    • METAL COMPOUNDS OF CALIXARENES, DETERGENT COMPOSITIONS CONTAINING THEM AND USE THEREOF IN LUBRICANT COMPOSITIONS
    • CALIXARENES的金属化合物,含有它们的洗涤剂组合物及其在润滑剂组合物中的用途
    • WO2017025900A1
    • 2017-02-16
    • PCT/IB2016/054803
    • 2016-08-10
    • ENI S.P.A
    • NOTARI, MarcelloROSELLI, AlbertoCASNATI, AlessandroSANSONE, FrancescoBURLINI, Alessandro
    • C11D3/18C11C3/04C10M107/28
    • C11C3/04C10M107/28C11D3/168C11D3/187C11D3/2065
    • The present invention relates to a metal compound of calixarene not containing sulfur and dispersible in oil, which can be partially salified, or neutral, or basic or overbased, said calixarene having general formula (I) in which: a) R 1 , R 2 , R 3 and R 4 are independently selected from hydrogen, or a group containing carbon and hydrogen, or a group containing in addition to carbon and hydrogen also heteroatoms, provided that said heteroatoms are not sulfur; b) one of the two substituents R 5 and R 6 is hydrogen, while the other may be selected from hydrogen, or a linear or branched alkyl with a number of carbon atoms between 1 and 6, preferably methyl, ethyl, 1 -propyl, 2-propyl, n-butyl, sec-butyl, more preferably methyl or ethyl; c) n is the number of units of the calixarene ring and is comprised in the range between 4 and 16, preferably between 5 and 12; said calixarene being characterized in that in at least one of the n units of the calixarene ring, at least one of the substituents R 1 , R 2 , R 3 and R 4 contains at least one acid group of carboxylic type available for the reaction with a metal base, with the proviso that said acid group of carboxylic type is not contained in a unit of the calixarene ring derived from salicylic acid.
    • 本发明涉及不含硫并可分散在油中的杯芳烃的金属化合物,其可部分成盐,或中性或碱性或高碱性,所述具有通式(I)的杯芳烃其中:a)R 1,R 2,R 3 和R 4独立地选自氢或含有碳和氢的基团,或除碳和氢之外还含有杂原子的基团,条件是所述杂原子不是硫; b)两个取代基R5和R6中的一个是氢,而另一个可以选自氢或具有1-6个碳原子的直链或支链烷基,优选甲基,乙基,1-丙基,2-丙基, 丙基,正丁基,仲丁基,更优选甲基或乙基; c)n是杯芳烃环的单元数,并且包含在4和16之间,优选在5和12之间的范围内; 所述杯芳烃的特征在于在杯芳烃环的n个单元中的至少一个中,取代基R 1,R 2,R 3和R 4中的至少一个含有至少一种可用于与金属碱反应的羧酸类型的酸基, 条件是羧酸类的酸基不包含在由水杨酸衍生的杯芳烃的单元中。