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1. 发明申请

WO2012088176A1 HIGH MOLECULAR WEIGHT IONOMERS AND IONICALLY CONDUCTIVE COMPOSITIONS FOR USE AS ONE OR MORE ELECTRODE OF A FUEL CELL 审中-公开
标题翻译：高分子量重金属离子和离子导电组合物用作燃料电池的一个或多个电极
公开(公告)号：WO2012088176A1
公开(公告)日：2012-06-28
申请号：PCT/US2011066287
申请日：2011-12-20
申请人： DU PONT , TOYOTA MOTOR CO LTD , TAKAMI MASAYOSHI , YOSHIDA TOSHIHIKO , AIMU MASANORI , PERRY RANDAL L , ROELOFS MARK GERRIT , WHELAND ROBERT CLAYTON , ATEN RALPH MUNSON
发明人： TAKAMI MASAYOSHI , YOSHIDA TOSHIHIKO , AIMU MASANORI , PERRY RANDAL L , ROELOFS MARK GERRIT , WHELAND ROBERT CLAYTON , ATEN RALPH MUNSON
IPC分类号： H01M6/18 , H01M4/88 , H01M8/10 , H01M10/0565
CPC分类号： H01M8/1039 , H01M4/8663 , H01M4/8828 , H01M6/183 , H01M8/1004 , H01M8/1027 , H01M10/0565 , H01M2300/0082
摘要： This invention relates to solid polymer electrolyte materials for use in one or more electrode of a fuel cell. The solid polymer electrolyte materials comprise one or more ionomer which comprises polymerized units of monomers A and monomers B, wherein monomers A are perfluoro dioxole or perfluoro dioxolane monomers, and the monomers B are functionalized perfluoro olefins having fluoroalkyl sulfonyl, fluoroalkyl sulfonate or fluoroalkyl sulfonic acid pendant groups, CF2=CF(O)[CF2]nSO2X. The ionomer of the solid polymer electrolyte material has a number average molecular weight, Mn, of greater than 140,000. Specifically, the ionomers of the invention may find use in the catalyst layer of an electrode because the high molecular weight ionomers mitigate the formation of cracks in the catalyst layer.
摘要翻译：本发明涉及用于燃料电池的一个或多个电极的固体聚合物电解质材料。固体聚合物电解质材料包含一种或多种离聚物，其包含单体A和单体B的聚合单元，其中单体A是全氟二氧杂环戊烯单体或全氟二氧戊环单体，单体B是具有氟代烷基磺酰基，氟烷基磺酸酯或氟烷基磺酸的全氟烯烃的官能化侧链基团，CF 2 = CF（O）[CF 2] n SO 2 X。固体高分子电解质材料的离聚物的数均分子量Mn大于14万。具体地，本发明的离聚物可用于电极的催化剂层，因为高分子量离聚物可以减轻催化剂层中的裂纹的形成。

2. 发明申请

WO2012086185A1 CATHODE CATALYST LAYER, MEMBRANE ELECTRODE ASSEMBLY AND POLYMER ELECTROLYTE FUEL CELL AND MANUFACTURING METHOD THEREOF 审中-公开
标题翻译：阴极催化层，膜电极组件和聚合物电解质燃料电池及其制造方法
公开(公告)号：WO2012086185A1
公开(公告)日：2012-06-28
申请号：PCT/JP2011007116
申请日：2011-12-20
申请人： TOYOTA MOTOR CO LTD , DU PONT , NONOYAMA NOBUAKI , AIMU MASANORI , PERRY RANDAL LEWIS , ROELOFS MARK GERRIT , WHELAND ROBERT CLAYTON , ATEN RALPH MUNSON
发明人： NONOYAMA NOBUAKI , AIMU MASANORI , PERRY RANDAL LEWIS , ROELOFS MARK GERRIT , WHELAND ROBERT CLAYTON , ATEN RALPH MUNSON
IPC分类号： H01M4/88 , H01M4/86 , H01M8/10
CPC分类号： H01M4/8657 , H01M4/8652 , H01M4/8663 , H01M4/8668 , H01M4/886 , H01M8/1004 , H01M2008/1095 , Y02E60/521 , Y02P70/56
摘要： A cathode catalyst layer used for a polymer electrolyte fuel cell that includes an electrolyte membrane is provided. The cathode catalyst layer comprises a catalyst having weight of not greater than 0.3 mg/cm2 of a reaction surface of the cathode catalyst layer that is adjoining the electrolyte membrane; and an electrolyte resin having oxygen permeability of not less than 2.2*10-14 mol/m/s/Pa in an environment of temperature of 80 degrees Celsius and relative humidity of 50%.
摘要翻译：提供了用于包含电解质膜的固体高分子型燃料电池的阴极催化剂层。阴极催化剂层包含负极与电解质膜相邻的阴极催化剂层的反应面重量不大于0.3mg / cm 2的催化剂; 以及在80℃的温度和50％的相对湿度的环境中具有不低于2.2×10-14mol / m / s / Pa的透氧度的电解质树脂。

3. 发明申请

WO2008054420A3 CHEMICALLY STABILIZED IONOMERS CONTAINING INORGANIC FILLERS 审中-公开
标题翻译：含有无机填料的化学稳定离子
公开(公告)号：WO2008054420A3
公开(公告)日：2008-07-10
申请号：PCT/US2006049018
申请日：2006-12-21
申请人： DU PONT , ROELOFS MARK GERRIT
发明人： ROELOFS MARK GERRIT
IPC分类号： H01M8/10 , C08F214/18 , C08J5/22 , C08K3/00 , H01M2/16
CPC分类号： C08J5/2237 , C08F214/18 , C08J2327/18 , C08K3/22 , C08K3/32 , H01M2/166 , H01M8/1023 , H01M8/1039 , H01M8/1048 , H01M8/106 , H01M8/1062 , H01M8/1081 , H01M2300/0082 , H01M2300/0091 , Y02P70/56 , Y10T428/249978 , Y10T428/24999
摘要： Ionomeric polymers that are chemically stabilized and contain inorganic fillers are prepared, and show reduced degradation. The ionomers care useful in membranes and electrochemical cells.
摘要翻译：制备化学稳定并含有无机填料的离子聚合物，并显示降低的降解。离子交换聚合物可用于膜和电化学电池。

4. 发明申请

WO2007073500A3 METHODS TO PREPARE CHEMICALLY STABILIZED IONOMERS CONTAINING INORGANIC FILLERS 审中-公开
标题翻译：制备含有无机填料的化学稳定化离子的方法
公开(公告)号：WO2007073500A3
公开(公告)日：2007-09-27
申请号：PCT/US2006049017
申请日：2006-12-21
申请人： DU PONT , ROELOFS MARK GERRIT
发明人： ROELOFS MARK GERRIT
IPC分类号： C08L101/02 , C08F8/22 , C08F8/42 , C08J5/22 , C08K3/22 , C08K3/32 , C08L27/22 , H01M8/10
CPC分类号： C08F8/22 , C08F8/42 , C08J5/2281 , C08J2327/18 , H01M8/1023 , H01M8/1039 , H01M8/1046 , H01M8/1048 , H01M8/106 , H01M8/1081 , Y02P70/56
摘要： lonomeric polymers that are chemically stabilized and contain inorganic fillers are prepared and show reduced degradation. The ionomeric polymers are useful in electrochemical and fuel cells.
摘要翻译：化学稳定并含有无机填料的单体聚合物被制备并显示降低的降解。离聚物聚合物可用于电化学和燃料电池。

5. 发明申请

WO2005049204A3 TRIFLUOROSTYRENE CONTAINING COMPOUNDS GRAFTED TO BASE POLYMERS 审中-公开
标题翻译：包含化合物的三氟甲磺酸酯基团聚合物
公开(公告)号：WO2005049204A3
公开(公告)日：2005-12-15
申请号：PCT/US2004020704
申请日：2004-06-25
申请人： DU PONT , CHOUDHURY BISWAJIT , ROELOFS MARK GERRIT , YANG ZHEN-YU
发明人： CHOUDHURY BISWAJIT , ROELOFS MARK GERRIT , YANG ZHEN-YU
IPC分类号： C08F255/02 , C08F259/08 , C08F291/18 , C08F291/00 , B01D71/28 , B01D71/78
CPC分类号： C08F259/08 , C08F255/02 , C08F291/18 , C08F291/185
摘要： A fluorinated ion exchange polymer prepared by grafting a monomer on to a base polymer, wherein the grafting monomer is selected from the group consisting of structure 1a, structure 1b and mixtures thereof, (INSERT 1a and 1b HERE) wherein Y is selected from the group consisting of -RFSO2F (sulfonyl fluoride), -RFSO3M (fluorosulfonic acid or salt), RFSO2NH2 (fluorosulfonamide), and -RFSO2N(M)SO2R F (imide); wherein M is H, an alkali cation, or ammonium; and RF and R F groups are perfluorinated or partially fluorinated, and may optionally include ether oxygens; and n is between 1 and 2 for 1a, or n is between 1 and 3 for 1b. These ion exchange polymers are useful in preparing catalyst coated membranes and membrane electrode assemblies used in fuel cells.
摘要翻译：通过将单体接枝到基础聚合物上而制备的氟化离子交换聚合物，其中接枝单体选自结构1a，结构1b及其混合物，其中Y选自基团由RFSO2F（磺酰氟），-RFSO3M（氟磺酸或盐），RFSO2NH2（氟磺酰胺）和-RFSO2N（M）SO2R2F（酰亚胺）组成; 其中M为H，碱性阳离子或铵; RF和R 2 F基团是全氟化或部分氟化的，并且可以任选包括醚氧; 对于1a，n对于1和2之间，对于1b，n在1和3之间。这些离子交换聚合物可用于制备用于燃料电池的催化剂涂覆的膜和膜电极组件。

6. 发明申请

WO9523989A3 LINE-WIDTH INSENSITIVE SEGMENTED WAVE REFLECTORS HAVING SELECTED BRAGG REFLECTION CHARACTERISTICS 审中-公开
标题翻译：具有选择的BRAGG反射特性的线宽无损分离波导反射器
公开(公告)号：WO9523989A3
公开(公告)日：1995-12-07
申请号：PCT/US9502328
申请日：1995-02-24
申请人： DU PONT
发明人： BINDLOSS WILLIAM , ROELOFS MARK GERRIT
IPC分类号： G02B6/12 , G02B6/124 , G02F1/37 , G02F1/377 , H01S5/12 , H01S5/125 , H01S5/14 , H01S3/133
CPC分类号： G02F1/3775 , G02B6/124 , H01S5/1218 , H01S5/125 , H01S5/141
摘要： A segmented article is disclosed which has selected Bragg reflection characteristics for a selected input wavelength. The article includes alternating sections of optical materials which are aligned and have refractive indexes different from adjacent sections to form at least one superperiod consisting of a plurality of segments such that each segment consists of a section of a first optical material and a section of a second optical material. At least one segment of the superperiod is different in optical path from another segment of the superperiod, and the interfaces between sections of the superperiod create backward travelling waves of complex amplitude at the selected input wavelength. The sequentially odd interfaces in the superperiod form a first set of interfaces and the sequentially even interfaces in the superperiod form a second set of interfaces. The article is characterized by (1) the sum for the superperiod sections of the product of the length of each section in the direction of alignment and the refractive index of the section being equal to about Nzμ/2 where Nz is an integer and μ is the wavelength of an input wave; and (2) the interfaces of the sequentially odd or even set of interfaces in the superperiod being spaced such that the modulus of the sum of the complex amplitudes created by that set is about zero or is less than 40 percent of the modulus of the sum of the complex amplitudes created by the other set. Devices are disclosed where the Bragg reflection from a Bragg reflector of this invention is used to stabilize a laser source.

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