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1. 发明申请

WO2016201222A1 AMORPHOUS FLUORINATED COPOLYMER GAS SEPARATION MEMBRANES 审中-公开
标题翻译：非晶荧光共聚物气体分离膜
公开(公告)号：WO2016201222A1
公开(公告)日：2016-12-15
申请号：PCT/US2016/036884
申请日：2016-06-10
申请人： COMPACT MEMBRANE SYSTEMS, INC
发明人： SHANGGUAN, Ning , FEIRING, Andrew , MAJUMDAR, Sudipto
IPC分类号： B01D61/38 , C07C7/144 , C07C21/18 , C08F214/26 , C08K5/02
CPC分类号： B01D71/32 , B01D53/228 , B01D67/0006 , B01D71/52 , B01D71/76 , B01D2323/06 , B01D2323/08 , B01D2325/20 , C07C17/38 , C08F214/186 , C07C21/18 , C07C21/185
摘要： Membranes having a permselective active layer of a copolymerized perfluorinated monomer and an non-fluorinated alkylvinylester monomer demonstrate superior selective permeability performance for separating gas mixtures compared to membranes of exclusively perfluorinated polymers. Preferred active layer compositions are copolymers of perfluoro-2,2-dimethyl-1,3 dioxole (PDD) copolymerized with an alkylvinyl ester such as vinyl acetate, and vinyl pivalate, and with alkylvinyl esters that are substantially hydrolyzed to provide copolymerized vinyl alcohol functionality. The membranes can have a thin, high diffusion rate, "gutter layer" of a fluorinated polymer highly permeable to nitrogen positioned between the active layer and a porous support layer. A novel copolymer effective in selectively permeable membranes is a copolymer of PDD and an alkylvinyl ester compound having the formula H 2 C=CHOC(0)R 1 in which R 1 is a linear or branched alkyl group of from 2 to 5 carbon atoms.
摘要翻译：具有共聚全氟化单体和非氟化烷基乙烯基酯单体的选择性活性层的膜与专门的全氟化聚合物的膜相比，显示出优异的用于分离气体混合物的选择性渗透性能。优选的活性层组合物是与烷基乙烯基酯如乙酸乙烯酯和新戊酸乙烯酯共聚的全氟-2,2-二甲基-1,3-二氧杂环戊烯（PDD）和基本上水解以提供共聚乙烯醇官能团的烷基乙烯基酯的共聚物。膜可以具有薄的高扩散速率，位于有源层和多孔支撑层之间的氮高度可渗透的氟化聚合物的“沟槽层”。在选择性渗透膜中有效的新型共聚物是PDD和具有式H 2 C = CHOC（O）R 1的烷基乙烯基酯化合物的共聚物，其中R 1是2至5个碳原子的直链或支链烷基。

2. 发明申请

WO2021202255A1 METHOD FOR REMOVING ETHYLENE FROM AGRICULTURAL PRODUCTS 审中-公开
公开(公告)号：WO2021202255A1
公开(公告)日：2021-10-07
申请号：PCT/US2021/024269
申请日：2021-03-26
申请人： COMPACT MEMBRANE SYSTEMS, INC.
发明人： NEMSER, Stuart Marshall , MAJUMDAR, Sudipto , SHANGGUAN, Ning
IPC分类号： B01D53/22 , B01D69/02 , B01D71/32 , B01D71/66 , B01D2256/24 , B01D2257/104 , B01D2257/7022 , B01D53/226 , B01D53/228
摘要： A method for removing ethylene from the atmosphere surrounding an agricultural product that is sensitive to ethylene, which promotes climacteric ripening and senescence, is disclosed. The method uses a membrane for selective ethylene permeation and removal from a container that is used to store, transport, and preserve the agricultural product.

3. 发明申请

WO2016182880A1 IMPROVED MEMBRANES FOR SEPARATION OF ALKENES FROM ALKANES 审中-公开
标题翻译：用于从碱中分离碱的改良膜
公开(公告)号：WO2016182880A1
公开(公告)日：2016-11-17
申请号：PCT/US2016/031117
申请日：2016-05-06
申请人： COMPACT MEMBRANE SYSTEMS, INC.
发明人： SHANGGUAN, Ning , FEIRING, Andrew, Edward , MAJUMDAR, Sudipto
IPC分类号： C08F214/22 , C08F14/18 , C08F14/22
CPC分类号： B01D71/76 , B01D53/228 , B01D69/02 , B01D69/12 , B01D71/26 , B01D71/32 , B01D71/34 , B01D71/82 , B01D2325/20 , B32B3/26 , B32B27/08 , B32B27/205 , B32B27/28 , B32B27/286 , B32B27/322 , B32B2307/70 , B32B2307/724 , B32B2307/732 , C07C7/144 , C08F4/00 , C08F214/202 , C08F216/1466 , C08F2216/1475 , C08G61/10
摘要： lonomers of Group 11 metals which include repeat units from vinylidene fluoride, can separate alkenes from alkanes when comprising a layer of a membrane. These membranes have excellent permeability and/or selectivity for alkenes in the separation of alkenes from alkanes.
摘要翻译：包括偏二氟乙烯的重复单元的第11族金属的单体单体当包含膜层时可以将烷烃与烷烃分离。这些膜在烯烃与烷烃的分离中具有优异的烯烃渗透性和/或选择性。

4. 发明申请

WO2016182889A1 COPOLYMER FOR USE IN ALKENE-ALKANE SEPARATION MEMBRANES 审中-公开
标题翻译：用于ALKENE-ALKANE分离膜的共聚物
公开(公告)号：WO2016182889A1
公开(公告)日：2016-11-17
申请号：PCT/US2016/031140
申请日：2016-05-06
申请人： COMPACT MEMBRANE SYSTEMS, INC.
发明人： SHANGGUAN, Ning , LOUSENBERG, Robert, Daniel , FEIRING, Andrew, Edward
IPC分类号： C07C7/144 , B01D69/14 , B01D71/32
CPC分类号： B01D71/76 , B01D53/228 , B01D69/02 , B01D69/12 , B01D71/26 , B01D71/32 , B01D71/34 , B01D71/82 , B01D2325/20 , B32B3/26 , B32B27/08 , B32B27/205 , B32B27/28 , B32B27/286 , B32B27/322 , B32B2307/70 , B32B2307/724 , B32B2307/732 , C07C7/144 , C08F4/00 , C08F214/202 , C08F216/1466 , C08F2216/1475 , C08G61/10
摘要： Described herein are copolymers derived from certain perfluorinated sulfonyl fluoride monomers, cyclic or cyclizable perfluorinated monomers, and one or both of ethylene and/or vinyl fluoride. Group 11 metal sulfonate ionomers of these copolymers, especially silver ionomers, are useful in membranes which separate olefins from alkanes.
摘要翻译：本文描述的是衍生自某些全氟化磺酰氟单体，环状或可环化全氟化单体以及乙烯和/或氟乙烯中的一种或两种的共聚物。这些共聚物，特别是银离聚物的第11族金属磺酸盐离聚物可用于将烯烃与烷烃分离的膜。

5. 发明申请

WO2019191388A1 CARBON DIOXIDE SEPARATION MEMBRANES AND PROCESS 审中-公开
公开(公告)号：WO2019191388A1
公开(公告)日：2019-10-03
申请号：PCT/US2019/024517
申请日：2019-03-28
申请人： COMPACT MEMBRANE SYSTEMS INC.
发明人： SHANGGUAN, Ning , NEMSER, Stuart Marshall , MAJUMDAR, Sudipto , FEIRING, Andrew Edward
IPC分类号： B01D53/22 , B01D69/02 , B01D69/12 , B01D71/32 , B01D71/38
摘要： This invention discloses a thin-film composite membrane and process for the separation of carbon dioxide from non-hydrophilic gases such as methane, hydrogen, and nitrogen. The thin-film composite membrane has a gas-separation layer and a nonporous high-diffusion-rate layer, and has carbon dioxide to non-hydrophilic gas selectivity that is greater than the intrinsic selectivity of the gas-separation layer alone.

6. 发明申请

WO2016182887A1 THIN FILM COMPOSITE MEMBRANES FOR SEPARATION OF ALKENES FROM ALKANES 审中-公开
标题翻译：用于分离碱金属的薄膜复合膜
公开(公告)号：WO2016182887A1
公开(公告)日：2016-11-17
申请号：PCT/US2016/031135
申请日：2016-05-06
申请人： COMPACT MEMBRANE SYSTEMS, INC.
发明人： MAJUMDAR, Sudipto , KOIZUMI, Yosuke , SHANGGUAN, Ning , FEIRING, Andrew, Edward
IPC分类号： C07C7/144 , B01D69/12 , B01D69/10 , B01J47/12 , B01D71/06 , B01D53/22
CPC分类号： B01D71/76 , B01D53/228 , B01D69/02 , B01D69/12 , B01D71/26 , B01D71/32 , B01D71/34 , B01D71/82 , B01D2325/20 , B32B3/26 , B32B27/08 , B32B27/205 , B32B27/28 , B32B27/286 , B32B27/322 , B32B2307/70 , B32B2307/724 , B32B2307/732 , C07C7/144 , C08F4/00 , C08F214/202 , C08F216/1466 , C08F2216/1475 , C08G61/10
摘要： Composite membranes comprised of at least two layers, one of the layers being a silver ionomer and a second layer which is a fluorinated polymer with certain permeability properties, are especially useful for the separation of alkanes from alkenes, Particularly useful is a three-layer composite membrane in which a porous layer is laminated to the second layer.
摘要翻译：由至少两层组成的复合膜，其中一层为银离聚物，第二层为具有一定渗透性能的氟化聚合物，特别适用于从烯烃中分离烷烃，特别有用的是三层复合材料膜，其中多孔层层压到第二层。

7. 发明申请

WO2023287628A1 THIN-FILM COMPOSITE MEMBRANES HAVING IMPROVED ADHESION BETWEEN LAYERS AND USES THEREOF 审中-公开
公开(公告)号：WO2023287628A1
公开(公告)日：2023-01-19
申请号：PCT/US2022/036284
申请日：2022-07-07
申请人： COMPACT MEMBRANE SYSTEMS INC.
发明人： MAJUMDAR, Sudipto , LOUSENBERG, Robert D. , LOPRETE, Kenneth E. , SHANGGUAN, Ning , GONCHAROVSKY, Irene , WARGO, Jacob A.
IPC分类号： B01D69/02 , B01D53/22 , B01D69/12 , B01D71/32 , B01D71/44 , B01D71/70 , B01D71/82
摘要： In an aspect, provided herein is an improved thin-film composite membrane and gas-separation processes using the composite membrane. The composite membrane incorporates a gutter layer from a polymer material selected from a substituted polyacetylene, an addition-polymerized and substituted polynorbornene, or an addition-polymerized and substituted polytricyclononene. The gutter layer provides improved adhesion with a gas-separation layer incorporating a fluorinated ionomer.

8. 发明申请

WO2022241069A1 FLUORINATED COPOLYMERS HAVING NITROGEN FUNCTIONALITY AND USES THEREOF 审中-公开
公开(公告)号：WO2022241069A1
公开(公告)日：2022-11-17
申请号：PCT/US2022/028905
申请日：2022-05-12
申请人： COMPACT MEMBRANE SYSTEMS INC.
发明人： SHANGGUAN, Ning , LOUSENBERG, Robert, D.
IPC分类号： B01D71/32 , C08F8/12 , C08F226/02 , B01D2256/245 , B01D2257/504 , B01D53/228 , B01D69/107 , B01D71/44 , B01D71/52 , B01D71/56 , B01D71/76
摘要： A fluorinated copolymer having pendant amide functionality is disclosed in an aspect herein. A membrane from the fluorinated copolymer having at least some of the pendant amide functionality hydrolyzed to pendant amine functionality is highly permeable to carbon dioxide and can be useful in the gas-separation layer of a thin-film composite membrane for the separation of carbon dioxide from nitrogen or methane.

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