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1. 发明申请

WO2012078240A1 SKEWED AND MIDDLE ATTACHED LINEAR CHAIN ALKYLPHENOL AND METHOD OF MAKING THE SAME 审中-公开
标题翻译：锯切和中间连接的线性链烷基酚及其制备方法
公开(公告)号：WO2012078240A1
公开(公告)日：2012-06-14
申请号：PCT/US2011/054720
申请日：2011-10-04
申请人： CHEVRON ORONITE COMPANY LLC , CAMPBELL, Curtis Bay , MAHIEUX, Cedrick
发明人： CAMPBELL, Curtis Bay , MAHIEUX, Cedrick
IPC分类号： C07C37/16 , C07C39/11 , B01J29/06 , B01J31/08
CPC分类号： C07C37/16 , C07C39/06
摘要： A process for preparing an alkylated hydroxyl aromatic compound comprising reacting (a) a hydroxyl aromatic compound (I), having the following structure;formula (I), wherein n 1, 2 or 3; m is 0, 1, 2, or 3 and R 1 is Hydrogen or hydrocarbyl group, and (b) at least one β-branched primary alcohol component in the presence of an alkylating catalyst thereby producing an alkylated hydroxyl aromatic compound.
摘要翻译：一种制备烷基化羟基芳族化合物的方法，包括使（a）具有以下结构的羟基芳族化合物（I）：式（I），其中n 1,2或3; m为0,1,2或3，R 1为氢或烃基，和（b）在烷基化催化剂存在下至少一种β-支链伯醇组分，由此制得烷基化羟基芳族化合物。

2. 发明申请

WO2014081624A1 SOLVENT EXTRACTION FOR PREPARING A SALT OF A SULFURIZED ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOSITION 审中-公开
标题翻译：用于制备硫化烷基取代羟基芳族化合物的盐的溶剂萃取
公开(公告)号：WO2014081624A1
公开(公告)日：2014-05-30
申请号：PCT/US2013/070252
申请日：2013-11-15
申请人： CHEVRON ORONITE COMPANY LLC
发明人： MAHIEUX, Cedrick , DUTTA, Richard Pran , CAMPBELL, Curtis Bay , YIP, Benjamin David
IPC分类号： C10M135/30
CPC分类号： C10M135/02 , C07G17/00 , C10M177/00 , C10M2219/02 , C10M2219/089 , C10N2230/64 , C10N2270/00
摘要： Disclosed is a process for preparing a salt of a sulfurized alkyl-substituted hydroxyaromatic composition having a reduced content of unsulfurized alkyl-substituted hydroxyaromatic compound and its unsulfurized metal salt. The process involves at least the steps of: (a) providing a composition comprising (i) a salt of a sulfurized alkyl-substituted hydroxyaromatic compound; (ii) an unsulfurized alkyl-substituted hydroxyaromatic compound and (iii) an unsulfurized metal salt of the alkyl-substituted hydroxyaromatic compound; wherein the alkyl-substituted hydroxyaromatic compound is derived from alkylation of a hydroxyaromatic compound with one or more olefins comprising C9 to C18 oligomers of monomers selected from propylene, butylene or mixtures thereof.
摘要翻译：公开了一种制备具有降低的未硫化烷基取代的羟基芳族化合物含量及其未硫化金属盐的硫化烷基取代的羟基芳族组合物的盐的方法。该方法至少包括以下步骤：（a）提供包含（i）硫化烷基取代的羟基芳族化合物的盐的组合物; （ii）未硫化烷基取代的羟基芳族化合物和（iii）烷基取代的羟基芳族化合物的未硫化金属盐; 其中所述烷基取代的羟基芳族化合物衍生自羟基芳族化合物与一种或多种烯烃的烷基化，所述烯烃包含选自丙烯，丁烯或其混合物的单体的C 9至C 18低聚物。

3. 发明申请

WO2014081538A1 PROCESS FOR PREPARING A SALT OF A SULFURIZED ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOSITION 审中-公开
标题翻译：制备磺化烷基取代羟基芳族化合物的盐的方法
公开(公告)号：WO2014081538A1
公开(公告)日：2014-05-30
申请号：PCT/US2013/067188
申请日：2013-10-29
申请人： CHEVRON ORONITE COMPANY LLC
发明人： MAHIEUX, Cedrick , DUTTA, Richard Pran , CAMPBELL, Curtis B.
IPC分类号： C07C43/20 , C07C211/00
CPC分类号： C10M159/20 , C10M2219/089 , C10N2230/04 , C10N2230/64 , C10N2270/00
摘要： Disclosed herein is a process for preparing a salt of a sulfurized alkyl-substituted hydroxyaromatic composition and the process involves the steps of: (a) providing a composition comprising (i) a salt of a sulfurized alkyl-substituted hydroxyaromatic compound; (ii) an unsulfurize'd alkyl-substituted hydroxyaromatic compound and (iii) an unsulfurized metal salt of the alkyl-substituted hydroxyaromatic compound;wherein the alkyl-substituted hydroxyaromatic compound is derived from alkylation of a hydroxyaromatic compound with one or more olefins comprising C9 to C18 oligomers of monomers selected from propylene, butylene or mixtures thereof; (b) protonating the unsulfurized metal salt of the alkyl-substituted hydroxyaromatic compound with an acidic compound capable of protonating the unsulfurized metal salt of the alkyl-substituted hydroxyaromatic compound; and ( c) removing the unsulfurized alkyl-substituted hydroxyaromatic compound and the protonated unsulfurized metal salt of the alkyl-substituted hydroxyaromatic compound from the composition.
摘要翻译：本文公开了一种制备硫化烷基取代的羟基芳族组合物的盐的方法，该方法包括以下步骤：（a）提供包含（i）硫化烷基取代的羟基芳族化合物的盐的组合物; （ii）未硫化的烷基取代的羟基芳族化合物和（iii）烷基取代的羟基芳族化合物的未硫化金属盐;其中烷基取代的羟基芳族化合物衍生自羟基芳族化合物与一种或多种包含C 9的烯烃的烷基化选自丙烯，丁烯或其混合物的单体的C18低聚物; （b）用能使烷基取代的羟基芳族化合物的未硫化金属盐进行质子化的酸性化合物使烷基取代的羟基芳族化合物的未硫化金属盐质子化; 和（c）从组合物中除去未硫化烷基取代的羟基芳族化合物和烷基取代的羟基芳族化合物的质子化未硫化金属盐。

4. 发明申请

WO2015066401A1 PROCESS FOR PREPARING A PARA-BRANCHED ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOUND 审中-公开
标题翻译：制备分支烷基取代羟基化合物的方法
公开(公告)号：WO2015066401A1
公开(公告)日：2015-05-07
申请号：PCT/US2014/063297
申请日：2014-10-31
申请人： CHEVRON ORONITE COMPANY LLC
发明人： MAHIEUX, Cedrick , CAMPBELL, Curtis Bay , KUPERMAN, Alexander
IPC分类号： C07C37/08
CPC分类号： C10M129/10 , C07C2/66 , C07C37/08 , C07C407/00 , C07C2529/18 , C10M177/00 , C10M2203/06 , C10M2207/023 , C10M2207/027 , C10M2207/028 , C10M2207/06 , C10N2220/028 , C10N2240/102 , C10N2270/00 , C07C39/06 , C07C409/08 , C07C15/107
摘要： Disclosed herein is a process for preparing an isomeric mixture comprising a major amount of a para-branched mono-alkyl-substituted hydroxyaromatic compound. The process involves the steps of: (a) subjecting an isomeric mixture comprising a major amount of a para-di(alkyl-substituted)aromatic compound; wherein a first alkyi substituent is a C3 to C8 alkyi moiety and a second alkyi substituent is a C4+n to C8+n branched alkyi moiety, wherein n is 0 to 42 and further wherein the second alkyi substituent is at least one carbon atom greater than the first alkyi substituent to oxidation conditions to a mixture of hydroperoxide compounds followed by converting the hydroperoxide moiety to a hydroxyl group.
摘要翻译：本文公开了一种制备包含主要量的对位支化单烷基取代的羟基芳族化合物的异构体混合物的方法。该方法包括以下步骤：（a）使含有主要量的对二（烷基取代的）芳族化合物的异构体混合物; 其中第一烷基取代基为C 3至C 8烷基部分，第二烷基取代基为C 4 + n至C 8 + n支链烷基部分，其中n为0至42，并且其中第二烷基取代基为至少一个碳原子较大比第一个氧化条件的烷基取代基转化为氢过氧化物化合物的混合物，然后将氢过氧化物部分转化为羟基。

5. 发明申请

WO2015065528A1 PROCESS FOR PREPARING A PARA-LINEAR ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOUND 审中-公开
标题翻译：用于制备直链烷基取代羟基化合物的方法
公开(公告)号：WO2015065528A1
公开(公告)日：2015-05-07
申请号：PCT/US2014/040287
申请日：2014-05-30
申请人： CHEVRON ORONITE COMPANY LLC
发明人： MAHIEUX, Cedrick , CAMPBELL, Curtis B. , KUPERMAN, Alexander
IPC分类号： C07C409/08
CPC分类号： C07C37/08 , C07C2/66 , C07C407/00 , C07C2529/18 , C10M129/10 , C10M177/00 , C10M2207/023 , C10N2270/00 , C07C39/06 , C07C15/107 , C07C409/08
摘要： Disclosed herein is a process for preparing an isomeric mixture comprising a major amount of a para-linear mono-alkyl-substituted hydroxyaromatic compound. The process involves: (a) providing an isomeric mixture comprising a major amount of a para-di (alkyl-substituted)aromatic compound; wherein a first alkyi substituent is a C3 to C8 alkyl moiety and a second alkyl substituent is a C4+n to C8+n linear alkyl moiety, and further wherein the second alkyl substituent is at least one carbon atom greater than the first alkyl substituent; (b) subjecting the above isomeric mixture to oxidation conditions in the presence of an oxygen-containing source, converting the first alkyl substituent which is a C3 to C8 alkyl moiety to a hydroperoxide-containing substituted moiety; and (c) converting the hydroperoxide-containing substituted moiety to a hydroxyl moiety thereby providing an isomeric mixture comprising a major amount of a para-linear mono-alkyl-substituted hydroxyaromatic compound.
摘要翻译：本文公开了一种制备包含主要量的对位线性单烷基取代的羟基芳族化合物的异构体混合物的方法。该方法包括：（a）提供包含主要量的对二（烷基取代的）芳族化合物的异构体混合物; 其中第一烷基取代基为C 3至C 8烷基部分，第二烷基取代基为C 4 + n至C 8 + n直链烷基部分，其中第二烷基取代基为至少一个比第一烷基取代基大的碳原子; （b）在含氧源的存在下使上述异构体混合物经历氧化条件，将C 3至C 8烷基部分的第一烷基取代基转化为含氢过氧化物的取代部分; 和（c）将含氢过氧化物的取代的部分转化为羟基部分，从而提供包含主要量的对位线性单烷基取代的羟基芳族化合物的异构体混合物。

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