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1. 发明申请

WO2016146813A1 CATIONIC DIRECT DYES 审中-公开
标题翻译：阳光直射
公开(公告)号：WO2016146813A1
公开(公告)日：2016-09-22
申请号：PCT/EP2016/055958
申请日：2016-03-18
申请人： BASF SE
发明人： BACHMANN, Frank , CREMER, Christian , FROEHLING, Beate , MURPHY, Bryan Patrick , ZHANG, Guiru , TORGERSON, Peter Marte
IPC分类号： C09B23/10
CPC分类号： A61Q5/065 , A61K8/49 , A61K8/4926 , A61K8/4946 , A61K2800/4322 , A61K2800/4324 , A61Q5/10 , C09B23/105 , C09B44/126 , C09B44/16 , C09B44/20 , C09B55/003 , C09B56/12
摘要： The invention relates to cationic direct dyes of the formula I (1), wherein m and n are independently from each other 0 or 1, D is an aromatic or a cationic heteroaromatic group, which are further specified, K is an aromatic or heteroaromatic group, E 1 and E 2 are independently from each other =CH- or =N-, An is an anion and a is a number from 1 to 6 and R 1 and R 2 are independently from each other and further specified. The compounds show washfastness at hair-dying.
摘要翻译：本发明涉及式I（1）的阳离子直接染料，其中m和n彼此独立地为0或1，D为芳族或阳离子杂芳族基团，其进一步规定为K为芳族或杂芳族基团，E1和E2彼此独立地= CH-或= N-，An是阴离子，a是1至6的数，R1和R2彼此独立地并进一步指定。化合物在染发时显示出耐洗性。

2. 发明申请

WO2012022709A1 DISULFIDE OR THIOL POLYMERIC HAIR DYES 审中-公开
标题翻译： DISOLFIDE或THIOL POLYMERIC HAIR DYES
公开(公告)号：WO2012022709A1
公开(公告)日：2012-02-23
申请号：PCT/EP2011/064022
申请日：2011-08-15
申请人： BASF SE , MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , FRÖHLING, Beate
发明人： MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , FRÖHLING, Beate
IPC分类号： C09B62/78 , C09B69/10 , A61Q5/10
CPC分类号： C09B67/0063 , A61K8/817 , A61K8/84 , A61K8/91 , A61Q5/10 , C09B62/78 , C09B69/101 , C09B69/106
摘要： The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
摘要翻译：本发明涉及（A）聚合物主链与（B）A发色团的反应产物; 和（C）至少一种含硫化物的化合物。使用这种新技术可以获得非常好的染色结果。

3. 发明申请

WO2011006946A9 POLYMERIC HAIR DYES 审中-公开
公开(公告)号：WO2011006946A9
公开(公告)日：2011-01-20
申请号：PCT/EP2010/060175
申请日：2010-07-15
申请人： BASF SE , CREMER, Christian , BECHERER, Oliver , FRÖHLING, Beate
发明人： CREMER, Christian , BECHERER, Oliver , FRÖHLING, Beate
IPC分类号： C09B26/04 , C09B69/10 , A61Q5/00
摘要： Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X 1 and X 2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R 5 )-, -S(O)-, -SO 2 -, -(CH 2 CH 2 -O) 1-5 -, -(CH 2 CH 2 CH 2 -O) 1-5 -, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R 1 )-, -C(NR 1 R 2 ) 2 -, -(R 1 )NC(O)-, -C(S)R 1 -; which may be interrupted and/or terminated at one or both ends by one or more than one -C 1 C 30 alkylene- or -C 2 -C 12 alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C 1 -C 30 alkyl, C 1 -C 30 alkoxy, C 2 -C 12 alkenyl, C 5 -C 10 aryl, C 5 -C 10 cycloalkyl, C 1 - C 10 alkyl(C 5 -C 10 arylene), hydroxy or halogen; R 1 and R 2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 - C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl- C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); Y 1 and Y 2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z 1 , Z 2 and Z 3 , independently from each other are -CR 8 - or -NR 9 +-; and at least one of Z 1 , Z 2 or Z 3 is -NR 9 +-; wherein at least one of Y 1 and Y 2 is a residue of an organic dye; R, R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 independently from each other are hydrogen; hydroxy; C 1 - C 5 alkyl; hydroxy-C 1 C 5 alkyl; C 1 C 5 alkoxy; -NO 2 ; -Cl; -Br; -COOH; -SO 3 H; -CN; NH 2 ; or CH 3 -CO-NH-; An 1 , An 2 and An 3 , independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p ≥ 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

4. 发明申请

WO2010079025A1 POLYMERIC HAIR DYES 审中-公开
标题翻译：聚合物染发剂
公开(公告)号：WO2010079025A1
公开(公告)日：2010-07-15
申请号：PCT/EP2009/066421
申请日：2009-12-04
申请人： BASF SE , MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , WALLQUIST, Olof , ZHOU, Xian-Zhi , WAGNER, Barbara
发明人： MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , WALLQUIST, Olof , ZHOU, Xian-Zhi , WAGNER, Barbara
IPC分类号： C09B69/10 , A61K8/64 , A61K8/65 , A61K8/88
CPC分类号： A61K8/64 , A61K8/645 , A61K8/65 , A61K2800/4322 , A61Q5/065 , C09B69/10 , C09B69/101 , C09B69/106
摘要： Polymeric dye comprising oligo and polypeptides selected from natural or synthetic aminoacids bearing at least one covalently bounded cationic dye. Very good dyeing results on human hair are obtained with these dyes.
摘要翻译：包含寡核苷酸和多肽的聚合染料选自具有至少一种共价结合阳离子染料的天然或合成氨基酸。用这些染料获得人毛发上的非常好的染色结果。

5. 发明申请

WO2020104564A1 AZOMETHINE DYE CHROMOPHORES 审中-公开
公开(公告)号：WO2020104564A1
公开(公告)日：2020-05-28
申请号：PCT/EP2019/082009
申请日：2019-11-21
申请人： BASF SE
发明人： BACHMANN, Frank , FROEHLING, Beate , CREMER, Christian , PERRITAZ, Marie-Pascale , WENDEL, Volker
IPC分类号： A61K8/49 , A61Q5/06
摘要： A composition for dyeing keratin fibres comprising a. at least one azomethine compound selected from compounds (3) and (4) and b. water. The composition may be used in a process for dyeing keratin fibres or, with simultaneous or sequential application of a composition comprising one or more oxidising agents, in a process for lightening keratin fibres.

6. 发明申请

WO2012150549A1 DISULFIDE DYES 审中-公开
标题翻译： DISIFFIDE DYES
公开(公告)号：WO2012150549A1
公开(公告)日：2012-11-08
申请号：PCT/IB2012/052178
申请日：2012-05-02
申请人： BASF SE , MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , FRÖHLING, Beate , BASF (CHINA) COMPANY LIMITED
发明人： MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , FRÖHLING, Beate
IPC分类号： C09B49/06 , A61K8/49 , A61K8/46 , C09B49/00
CPC分类号： A61K8/4986 , A61K8/49 , A61K2800/884 , A61Q5/04 , A61Q5/065 , A61Q5/10 , C09B26/04 , C09B29/081 , C09B29/3691 , C09B43/18 , C09B43/44 , C09B44/10 , C09B49/00 , C09B62/78 , C09D15/00
摘要： Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin- containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
摘要翻译：公开了式（1）或式（2）的化合物。这些化合物可用于染色有机材料，例如角蛋白纤维，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白纤维，棉或尼龙，优选毛发，更优选人发。（1）（2）。

7. 发明申请

WO2020182936A1 SUNSCREEN COMPOSITIONS CONTAINING POROUS METAL OXIDE SPHERES 审中-公开
公开(公告)号：WO2020182936A1
公开(公告)日：2020-09-17
申请号：PCT/EP2020/056628
申请日：2020-03-12
申请人： BASF SE
发明人： HERZOG, Bernd , LINDEMANN, Brigitte , CREMER, Christian , DARJI, Rupa
IPC分类号： A61K8/02 , A61K8/25 , A61K8/27 , A61K8/29 , A61K8/37 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q17/04
摘要： The present invention relates to a method for increasing sun protection factor (SPF) of a sunscreen composition, use of porous metal oxide spheres (e.g., microspheres) for increasing SPF of a sunscreen composition and preparation of sunscreen compositions comprising the porous spheres.

8. 发明申请

WO2015028543A1 STYRYL SULFIDE DYES 审中-公开
公开(公告)号：WO2015028543A1
公开(公告)日：2015-03-05
申请号：PCT/EP2014/068242
申请日：2014-08-28
申请人： BASF SE
发明人： BACHMANN, Frank , CREMER, Christian , KNOBLOCH, Markus , FRÖHLING, Beate , SPECKER, Werner
IPC分类号： C09B23/14 , A61Q5/10 , A61K8/49
CPC分类号： C09B23/145 , A61K8/4926 , A61Q5/10 , C07D213/56 , C07D401/14
摘要： Disclosed are styryl dyes of formula (1) wherein R 1 , R 2 , R 3 , R' 1 , R' 2 and R' 3 independently of each other are hydrogen; -NH(CO)-C 1 -C 5 alkyl; -N(C 1 -C 5 alkyl)(C 1 -C 5 alkyl-CN); C 1 -C 6 alkoxy; a heterocyclic radical; or R 1 and R 2 or R' 1 and R' 2 together form a 5- to 10-membered, monocyclic, carbocyclic or heterocyclic ring; wherein at least one of R 1 , R 2 , R 3 , R' 1 , R' 2 and R' 3 is different from hydrogen; Q and Q' independently from each other are the direct bond; *-C(O)-*; *-C(O)O-*; *-OCO-*; *-N(R 4 )-*; (AA); *-C(O)N(R 6 )-*; or *-(R 6 )NC(O)-*; and R 4 , R 5 and R 6 independently from each other are hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 - C 12 aryl; C 6 -C 12 aryl-C 1 -C 10 alkyl; or C 1 -C 10 alkyl(C 5 -C 12 aryl); X and X' are *-(CH 2 ) m -*; Y 1 and Y 2 independently from each other are C 1 -C 10 alkylene; C 5 -C 10 cycloalkylene; C 5 -C 12 arylene; or C 5 -C 12 arylene-(C 1 -C 10 alkylene); An - is an anion; m is a number from 1 to 8; n is 0, or 1; and p is 0, or 1.
摘要翻译：公开了式（1）的苯乙烯基染料，其中R1，R2，R3，R'1，R'2和R'3彼此独立地是氢; -NH（CO）-C 1 -C 5烷基; -N（C1-C5烷基）（C1-C5烷基-CN）; C1-C6烷氧基; 杂环基; 或R1和R2或R'1和R'2一起形成5至10元单环，碳环或杂环; 其中R1，R2，R3，R'1，R'2和R'3中的至少一个不同于氢; Q和Q'彼此独立是直接键; * -C（O） - *; * -C（O）O- *; * -OCO- *; * -N（R 4） - *; （AA）; * -C（O）N（R 6） - *; 或* - （R6）NC（O） - *; 和R 4，R 5和R 6彼此独立地是氢; C1-C 1-4烷基; C2-C14alkenyl; C 6 -C 12芳基; C6-12芳基-C 1 -C 10烷基; 或C 1 -C 10烷基（C 5 -C 12芳基）; X和X'是* - （CH 2）m- *; Y1和Y2彼此独立地为C1-C10亚烷基; C5-C10cycloalkylene; C5-C12arylene; 或C 5 -C 12亚芳基 - （C 1 -C 10亚烷基）; An-是阴离子; m是从1到8的数字; n为0或1; p为0或1。

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