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    • 5. 发明申请
    • POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
    • 可聚合光敏剂和辐射可固化组合物
    • WO2010069758A1
    • 2010-06-24
    • PCT/EP2009/066155
    • 2009-12-01
    • AGFA GRAPHICS NVLOCCUFIER, JohanVAN MAELE, LucVAN LUPPEN, JaymesCLAES, Roland
    • LOCCUFIER, JohanVAN MAELE, LucVAN LUPPEN, JaymesCLAES, Roland
    • C07C69/54C07C69/716C07C69/78C07C233/20C07D209/86C07D335/16C07D295/108G03F7/027
    • C07D335/16C07C69/54C07C233/20C07C235/08C07C323/12C07C2601/14C07C2602/42C07D209/86C07D295/108G03F7/027G03F7/031
    • A polymerizable photoinitiator represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w = 1 to (p-z) and z = O to (p-w); L represents an optionally substituted (p÷y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation. Radiation curable compositions including the polymerizable photoinitiator and methods of preparing the polymerizable photoinitiator are also disclosed.
    • 由式(I)表示的可聚合光引发剂:其中R 1,R 2和R 3独立地选自氢,任选取代的烷基和任选取代的芳基,或者R 1和R 3表示必要的原子以形成五 至八元环; p,w,y和z都是整数,y代表值1到6; p表示w和z的和; p表示1到6的值; w = 1〜(p-z),z = 0〜(p-w); L表示包含1至14个碳原子的任选取代的(p÷y)价连接基团; A表示选自丙烯酸酯基,甲基丙烯酸酯基,苯乙烯基,丙烯酰胺基,甲基丙烯酰胺基,马来酸酯基,富马酸酯基,衣康酸酯基,乙烯基醚基中的自由基聚合性基团 烯丙基醚基,烯丙基酯基和乙烯基酯基; 并且X表示光引发部分,其包含至少一个能够在暴露于光化辐射时引发自由基聚合反应的基团。 还公开了包含可聚合光引发剂的可辐射固化组合物和制备可聚合光引发剂的方法。
    • 7. 发明申请
    • CURABLE LIQUIDS AND INKS FOR TOYS AND FOOD PACKAGING APPLICATIONS
    • 用于玩具和食品包装应用的可固化液体和墨水
    • WO2009053348A1
    • 2009-04-30
    • PCT/EP2008/064180
    • 2008-10-21
    • AGFA GRAPHICS NVLOCCUFIER, JohanCLAES, Roland
    • LOCCUFIER, JohanCLAES, Roland
    • C09D11/10C09D11/00
    • C09D11/30B41M1/04C09D11/101C09D11/322C09D11/38
    • A free radical curable liquid for inkjet printing of food packaging materials comprising no initiator or otherwise one or more initiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric initiators, polymeric initiators and polymerizable initiators; wherein the polymerizable composition of said liquid consists essentially of: a) 25 - 100 wt% of one or more polymerizable compounds A having at least one acrylate group G1 and at least one second ethylenically unsaturated polymerizable functional group G2 selected from the group consisting of a vinlyether group, an allylether group and a allylester group; b) 0 - 55 wt% of one or more polymerizable compounds B selected from the group consisting of monofunctional acrylates and difunctional acrylates; and c) 0 - 55 wt% of one or more polymerizable compounds C selected from the group consisting of trifunctional acrylates, tetrafunctional acrylates, pentafunctional acrylates and hexafunctional acrylates, with the proviso that if the weight percentage of compounds B > 24 wt%, then the weight percentage of compounds C > 1 wt%; and wherein all weight percentages of A, B and C are based upon the total weight of the polymerizable composition; and with the proviso that at least one polymerizable compound B or C is present in the polymerizable composition if the free radical curable liquid contains no initiator.
    • 一种用于食品包装材料的喷墨印刷的自由基可固化液体,其不包含引发剂或其它一种或多种选自非聚合二 - 或多官能引发剂,低聚引发剂,聚合物引发剂和可聚合引发剂的引发剂; 其中所述液体的可聚合组合物基本上由以下组成:a)25-100重量%的一种或多种可聚合化合物A,其具有至少一个丙烯酸酯基团G1和至少一个第二烯键式不饱和可聚合官能团G2,其选自 乙烯醚基,烯丙基醚基和烯丙基; b)0-55重量%的选自单官能丙烯酸酯和双官能丙烯酸酯的一种或多种可聚合化合物B; 和c)0-55重量%的选自三官能丙烯酸酯,四官能丙烯酸酯,五官能丙烯酸酯和六官能丙烯酸酯的一种或多种可聚合化合物C,条件是如果化合物B的重量百分比> 24重量%,则 化合物C的重量百分比> 1wt%; 并且其中A,B和C的所有重量百分比均基于可聚合组合物的总重量; 并且条件是如果可自由基固化液体不含引发剂,则至少一种可聚合化合物B或C存在于可聚合组合物中。
    • 8. 发明申请
    • CURABLE LIQUIDS AND INKS FOR TOYS AND FOOD PACKAGING APPLICATIONS
    • 用于玩具和食品包装应用的可固化液体和墨水
    • WO2009053305A1
    • 2009-04-30
    • PCT/EP2008/063957
    • 2008-10-16
    • Agfa Graphics NVCLAES, RolandLOCCUFIER, Johan
    • CLAES, RolandLOCCUFIER, Johan
    • C09D11/10C09D11/00
    • C09D11/30B05D1/005B05D1/18B05D1/265B05D1/28B05D1/305B05D1/32B05D1/40B05D3/067C09D11/101C09D11/107C09D11/38Y10S522/904Y10S522/909
    • A free radical curable liquid for inkjet printing of food packaging materials comprising no initiator or otherwise one or more initiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric initiators, polymeric initiators and polymerizable initiators; wherein the polymerizable composition of said liquid consists essentially of: a) 25 - 100 wt% of one or more polymerizable compounds A having at least one acrylate group G1 and at least one second ethylenically unsaturated polymerizable functional group G2 différent from the group G1; b) 0 - 55 wt% of one or more polymerizable compounds B selected from the group consisting of monofunctional acrylates and difunctional acrylates; and c) 0 - 55 wt% of one or more polymerizable compounds C selected from the group consisting of trifunctional acrylates, tetrafunctional acrylates, pentafunctional acrylates and hexafunctional acrylates, with the proviso that if the weight percentage of compounds B > 24 wt%, then the weight percentage of compounds C > 1 wt%; and wherein ail weight percentages of A, B and C are based upon the total weight of the polymerizable composition; with the proviso that at least one polymerizable compound B or C is présent in the polymerizable composition if the free radical curable liquid contains no initiator; wherein the polymerizable compound A has a copolymerization ratio of 0.002
    • 一种用于食品包装材料的喷墨印刷的自由基可固化液体,其不包含引发剂或其它一种或多种选自非聚合二 - 或多官能引发剂,低聚引发剂,聚合物引发剂和可聚合引发剂的引发剂; 其中所述液体的可聚合组合物基本上由以下组成:a)25-100重量%的一种或多种可聚合化合物A,其具有至少一个丙烯酸酯基团G1和至少一个第二烯属不饱和可聚合官能团G2,其不同于组G1; b)0-55重量%的选自单官能丙烯酸酯和双官能丙烯酸酯的一种或多种可聚合化合物B; 和c)0-55重量%的选自三官能丙烯酸酯,四官能丙烯酸酯,五官能丙烯酸酯和六官能丙烯酸酯的一种或多种可聚合化合物C,条件是如果化合物B的重量百分比> 24重量%,则 化合物C的重量百分比> 1wt%; 并且其中A,B和C的重量百分比基于可聚合组合物的总重量; 条件是如果可自由基固化液体不含引发剂,则在可聚合组合物中至少有一种可聚合化合物B或C是必需的; 其中可聚合化合物A的共聚比为0.002
    • 9. 发明申请
    • NOVEL RADIATION CURABLE COMPOSITIONS
    • 新型可辐射固化组合物
    • WO2008074758A1
    • 2008-06-26
    • PCT/EP2007/064024
    • 2007-12-17
    • Agfa Graphics NVLOCCUFIER, JohanCLAES, RolandVAN LUPPEN, Jaymes
    • LOCCUFIER, JohanCLAES, RolandVAN LUPPEN, Jaymes
    • C08F2/00
    • C08F2/50
    • A radiation curable composition comprising a curable compound, a photo-initiator and a co-initiator characterized in that said co-initiator is represented by Formula (I), wherein MA is the residue of a mono- or oligofunctional Michael acceptor; L is a divalent linking group positioning the two tertiary amines in a 1-3 to 1-10 position, with the proviso that both amines are aliphatic; R1, R2 and R3 independently represent an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group or an optionally substituted (hetero) alkaryl group; any two of R1, R2 and R3 may represent the necessary atoms to form a ring; any two of R1, R2 and R3 may represent the necessary atoms to form a ring with any of the atoms of the linking group L; n is an integer ranging from 1 to 6.
    • 一种包含可固化化合物,光引发剂和共引发剂的可辐射固化组合物,其特征在于所述共引发剂由式(I)表示,其中MA是单官能或低官能迈克尔受体的残基; L是二价连接基团,将两个叔胺定位在1-3至1-10个位置,条件是两个胺都是脂族的; R1,R2和R3独立地表示任选取代的烷基,任选取代的烯基,任选取代的炔基或任选取代的(杂)烷芳基; R1,R2和R3中的任何两个可以表示形成环的必要原子; R1,R2和R3中的任何两个可以表示与连接基团L的任何原子形成环的必要原子; n为1〜6的整数。