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    • 2. 发明申请
    • COMPOSITE ARTICLE AND METHODS OF MAKING THE SAME
    • 复合制品及其制备方法
    • WO2017031298A1
    • 2017-02-23
    • PCT/US2016/047522
    • 2016-08-18
    • 3M INNOVATIVE PROPERTIES COMPANY
    • CLOUGH, Robert S.SPAGNOLA, Joseph C.LYONS, Christopher S.WEIGEL, Mark D.KLUN, Thomas P.
    • C08J7/04
    • C08J7/045C08J2367/02C08J2433/12
    • A composite article comprises a substrate, base polymer layer, an inorganic barrier layer, and top polymer layer. The base polymer layer is disposed on the substrate, and includes a polymerized reaction product of components comprising at least 60 percent by weight of at least one di(meth)acrylate represented by the formula wherein: each R 1 is independently H or methyl; and each R 2 independently represents an alkyl group having from 1 to 4 carbon atoms, or two R 2 groups may together form an alkylene group having from 2 to 7 carbon atoms. An inorganic barrier layer is bonded to the base polymer layer. The top polymer layer is disposed on the inorganic barrier layer opposite the substrate, wherein the top polymer layer comprises a polymerized reaction product of components comprising at least 60 percent by weight of a cycloaliphatic (meth)acrylate having from 13 to 24 carbon atoms.
    • 复合制品包括基底,基础聚合物层,无机阻挡层和顶部聚合物层。 基础聚合物层设置在基材上,并且包括含有至少60重量%的至少一种由下式表示的二(甲基)丙烯酸酯的组分的聚合反应产物:其中:每个R 1独立地为H或甲基; 并且每个R 2独立地表示具有1至4个碳原子的烷基,或两个R 2基团可以一起形成具有2至7个碳原子的亚烷基。 无机阻挡层与基础聚合物层结合。 顶部聚合物层设置在与基底相对的无机阻挡层上,其中顶部聚合物层包含含有至少60重量%的具有13-24个碳原子的脂环族(甲基)丙烯酸酯的组分的聚合反应产物。