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1. 发明申请

WO2003055835A1 気相接触酸化方法および(メタ)アクロレイン又は(メタ)アクリル酸の製造方法审中-公开
标题翻译：蒸气相催化氧化方法及生产（甲基）丙烯酸或（甲基）丙烯酸的方法
公开(公告)号：WO2003055835A1
公开(公告)日：2003-07-10
申请号：PCT/JP2002/013608
申请日：2002-12-26
申请人：三菱化学株式会社 , 矢田修平 , 小川寧之 , 鈴木芳郎 , 保坂浩親 , 神野公克 , 斉藤輝雄
发明人：矢田修平 , 小川寧之 , 鈴木芳郎 , 保坂浩親 , 神野公克 , 斉藤輝雄
IPC分类号： C07C45/35
CPC分类号： C07C51/215 , C07C45/33 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for vapor-phase catalytic oxidation by feeding a gaseous raw material into a fixed-bed multi-pipe reactor comprising reaction pipes filled with catalysts, wherein two or more catalyst layers different in activity are placed in each reaction pipe in a state stratified in the reaction direction and the catalyst layer nearest to the port of feeding the gaseous raw material has a higher catalytic activity than that of the next catalyst layer adjacent thereto; and a process for production of (meth)acrolein or (meth)acrylic acid by vapor -phase catalytic oxidation of a raw material for production of (meth)acrolein or (meth)acrylic acid with molecular oxygen or a gas containing molecular oxygen in a fixed-bed multi-pipe reactor comprising reaction pipes each containing two or more catalyst layers placed in the axial direction, wherein the difference between the maximum and minimum reaction peak temperatures of each catalyst layer in the pipe-axial direction is controlled to be 20 °C or below. According to these processes, the occurrence of hot spots can be efficiently inhibited.
摘要翻译：一种通过将气态原料进料到固定床多管反应器中的气相催化氧化方法，其包括填充有催化剂的反应管，其中活性不同的两个或更多个催化剂层以分层的状态放置在每个反应管中反应方向和最靠近进料气态原料的催化剂层具有比与其相邻的下一个催化剂层更高的催化活性; 以及通过气相催化氧化生成（甲基）丙烯醛或（甲基）丙烯酸的方法和（甲基）丙烯醛或（甲基）丙烯酸与分子氧或包含分子氧的气体在固定床多管反应器，其包含反应管，每个反应管包含沿轴向设置的两个或更多个催化剂层，其中每个催化剂层在管轴方向上的最大和最小反应峰值温度之间的差被控制在20° C或以下。根据这些方法，可以有效地抑制热点的发生。

2. 发明申请

WO2003076373A1 接触気相酸化方法审中-公开
标题翻译：催化蒸汽相氧化工艺
公开(公告)号：WO2003076373A1
公开(公告)日：2003-09-18
申请号：PCT/JP2003/002855
申请日：2003-03-11
申请人：三菱化学株式会社 , 坂倉康之 , 矢田修平 , 神野公克 , 保坂浩親 , 鈴木芳郎
发明人：坂倉康之 , 矢田修平 , 神野公克 , 保坂浩親 , 鈴木芳郎
IPC分类号： C07C27/14
CPC分类号： C07C45/35 , B01J8/067 , B01J2208/00053 , B01J2208/00061 , B01J2208/00088 , B01J2208/00221 , B01J2208/00256 , B01J2208/0053 , B01J2208/025 , B01J2219/0002 , B01J2219/00259 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for catalytic vapor phase oxidation wherein a raw material gas is introduced for oxidation into a reaction tube of a multi-tubular reactor which is equipped with, arranged within the shell of the reactor, a plurality of reaction tubes having a catalyst packed therein and a plurality of baffle plates for converting the direction of the flow of a heating medium introduced into the shell, characterized in that the temperature of the catalyst packed in a reaction tube which is connected with no baffle plates is measured at plural points. The process allows the prevention of runaway reaction or early deterioration of a catalyst, in the production of (meth)acrylic acid or the like from propylene or isobutylene by a catalytic vapor phase oxidation process using a multi-tubular reactor, which leads to the production thereof with stability in high yield for a long period of time.
摘要翻译：一种用于催化气相氧化的方法，其中将原料气体引入用于氧化的多管式反应器的反应管中，所述多管式反应器配备有布置在反应器壳体内的多个反应管，其中装有催化剂，多个用于转换引入壳体的加热介质的流动方向的挡板，其特征在于，在多个点处测量装在与无挡板相连的反应管中的催化剂的温度。该方法允许通过使用多管式反应器的催化气相氧化方法从丙烯或异丁烯生产（甲基）丙烯酸等，防止催化剂失控反应或早期劣化，这导致生产其长期稳定地以高产率。

3. 发明申请

WO2003076380A1 （メタ）アクリル酸類の製造方法审中-公开
标题翻译：生产（甲基）丙烯酸的方法
公开(公告)号：WO2003076380A1
公开(公告)日：2003-09-18
申请号：PCT/JP2003/002856
申请日：2003-03-11
申请人：三菱化学株式会社 , 矢田修平 , 保坂浩親 , 神野公克
发明人：矢田修平 , 保坂浩親 , 神野公克
IPC分类号： C07C45/33
CPC分类号： C07C51/215 , C07C45/33 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for producing (meth)acrolein or (meth)acrylic acid by vapor phase catalytic oxidation of propylene, propane or isobutylene in an oxidation reactor, characterized in that the raw material mixed gas introduced to the oxidation reactor is adjusted to have a temperature higher than the dew point of the mixed gas. The process allows the prevention of the variation in the composition of the raw material mixed gas, the abnormal temperature elevation of the oxidation reactor, and the reduction of catalyst activity and catalyst life, which leads to the production of (meth)acrylic acid and a derivative thereof with stability and with good efficiency.
摘要翻译：一种在氧化反应器中通过气相催化氧化丙烯，丙烷或异丁烯生产（甲基）丙烯醛或（甲基）丙烯酸的方法，其特征在于将引入氧化反应器的原料混合气体调节至温度升高比混合气体的露点高。该方法可以防止原料混合气体的组成变化，氧化反应器的异常升温以及催化剂活性和催化剂寿命的降低，从而生成（甲基）丙烯酸和衍生物具有稳定性和效率。

4. 发明申请

WO2004018403A1 多管式反応器を用いた気相接触酸化方法审中-公开
标题翻译：使用多重反应器的蒸气相催化氧化方法
公开(公告)号：WO2004018403A1
公开(公告)日：2004-03-04
申请号：PCT/JP2003/010600
申请日：2003-08-21
申请人：三菱化学株式会社 , 矢田修平 , 保坂浩親 , 神野公克
发明人：矢田修平 , 保坂浩親 , 神野公克
IPC分类号： C07C51/21
CPC分类号： C07C51/215 , B01J8/067 , B01J2208/00212 , B01J2208/00221 , B01J2208/0023 , C07C45/33 , C07C45/35 , C07C51/00 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A method of vapor phase catalytic oxidation that is capable of effectively removing heat of reaction, preventing occurrence of hot spots and efficiently obtaining a desired product. In particular, a method of performing a vapor phase catalytic oxidation of substance to be oxidized with a gas containing molecular oxygen by means of a multitubular reactor, the multitubular reactor comprising a cylindrical reactor shell fitted with a raw material supply port and a product outlet; multiple circular conduits disposed around the cylindrical reactor shell and used to introduce heat medium into the cylindrical reactor shell or to lead heat medium out therefrom; a circulation device for connecting the multiple circular conduits to each other; multiple reaction tubes restrained by means of multiple tube plates of the reactor and having a catalyst accommodated therein; and multiple baffles arranged in the longitudinal direction of the reaction tube and used to change the direction of heat medium introduced in the reactor shell. In this method, the vapor phase catalytic oxidation is carried out under such conditions that the heat transfer coefficient of heat medium is 1000 W/(m .K) or higher.
摘要翻译：一种气相催化氧化方法，其能够有效地除去反应热，防止发生热点并有效地获得所需产物。具体而言，一种通过多管式反应器对含有分子氧气体进行氧化的物质进行气相催化氧化的方法，该多管式反应器包括装配有原料供给口和产品出口的圆柱形反应器壳体; 多个圆形管道设置在圆柱形反应器壳体周围，用于将热介质引入圆柱形反应器壳体或从其中引出热介质; 用于将多个圆形导管彼此连接的循环装置; 多个反应管通过反应器的多个管板约束并具有容纳在其中的催化剂; 以及沿反应管的纵向布置的多个挡板，用于改变引入反应器壳体的热介质的方向。在该方法中，气相催化氧化在热介质的传热系数为1000W /（m 2·K）以上）的条件下进行。

5. 发明申请

WO2003059857A1 多管式反応器、多管式反応器を用いる気相接触酸化方法、及び多管式反応器に適用されるスタートアップ方法审中-公开
标题翻译：多层反应器，使用多层反应器的蒸气相催化氧化方法和应用于多反应器的启动方法
公开(公告)号：WO2003059857A1
公开(公告)日：2003-07-24
申请号：PCT/JP2003/000160
申请日：2003-01-10
申请人：三菱化学株式会社 , 矢田修平 , 保坂浩親 , 強力正康 , 神野公克 , 小川寧之 , 鈴木芳郎
发明人：矢田修平 , 保坂浩親 , 強力正康 , 神野公克 , 小川寧之 , 鈴木芳郎
IPC分类号： C07C45/35
CPC分类号： B01J35/026 , B01J8/06 , B01J8/067 , B01J23/002 , B01J23/8876 , B01J2208/00221 , B01J2208/0053 , B01J2208/00716 , B01J2523/00 , C07C45/33 , C07C45/35 , C07C51/215 , C07C51/252 , F28D7/1607 , F28D2021/0022 , F28F9/026 , F28F9/028 , F28F9/22 , F28F2265/10 , C07C47/22 , C07C57/04 , B01J2523/12 , B01J2523/13 , B01J2523/22 , B01J2523/305 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： A multipipe reactor, wherein pipes having smaller tolerances between a nominal size and actual sizes are used as reaction pipes to stably perform a high yield reaction for a long period, a catalyst is filled into the reaction pipes so that the catalyst layer peak temperature portions of the reaction pipes are not overlapped with the connection portions thereof with baffle boards to effectively prevent hot spots from occurring and stably perform a reaction for a long period without the clogging of the reaction pipes, a heat medium and material gas are allowed to flow in the direction of a counter flow and a specified type of catalyst is filled into the reaction pipes so that activity is increased starting at the inlet of the material gas toward the outlet thereof to prevent the automatic oxidation reaction of products so as to prevent equipment from being damaged due to the reaction, and, at the time of starting, gas with a temperature of 100 to 400 C ° is led to the outside of the reaction pipes to increase the temperature of the reaction pipes and, at the room temperature, a solid heat medium is heated to circulate the medium to the outside of the reaction pipes to efficiently start up the reactor without affecting the activity of the catalyst.
摘要翻译：使用具有公称尺寸和实际尺寸之间的较小公差的管作为反应管，以长期稳定地进行高产率反应的多管反应器，将催化剂填充到反应管中，使得催化剂层的峰值温度部分反应管不与其与挡板的连接部分重叠，以有效地防止热点发生并且长时间稳定地进行反应而不会使反应管堵塞，允许热介质和材料气体流入逆流方向和特定类型的催化剂被填充到反应管中，使得从材料气体的入口向其出口开始活动增加，以防止产品的自动氧化反应，从而防止设备被损坏由于反应，并且在起始时，温度为100〜400℃的气体被引导到真空的外部以提高反应管的温度，并且在室温下，将固体热介质加热以使介质循环到反应管的外部，以有效启动反应器而不影响催化剂的活性。

6. 发明申请

WO2003057653A1 気相接触酸化方法审中-公开
标题翻译：蒸气相催化氧化方法
公开(公告)号：WO2003057653A1
公开(公告)日：2003-07-17
申请号：PCT/JP2002/013372
申请日：2002-12-20
申请人：三菱化学株式会社 , 矢田修平 , 強力正康 , 保坂浩親 , 神野公克 , 斉藤輝雄 , 鈴木芳郎
发明人：矢田修平 , 強力正康 , 保坂浩親 , 神野公克 , 斉藤輝雄 , 鈴木芳郎
IPC分类号： C07C27/14
CPC分类号： B01J8/003 , B01J8/0085 , B01J8/067 , B01J23/002 , B01J23/28 , B01J23/31 , B01J23/8876 , B01J35/026 , B01J2208/00212 , B01J2208/00221 , B01J2208/00513 , B01J2208/00539 , B01J2208/00663 , B01J2208/00752 , B01J2523/00 , C07C45/33 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/12 , B01J2523/13 , B01J2523/305 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： A method for vapor phase catalytic oxidation involving using a fixed bed multi-tube heat-exchanger type reactor having a plurality of reaction tubes, feeding a raw material gas for reaction to the inside of the reaction tube packed with a catalyst to produce a reaction product gas, characterized in that the pressure loss of each reaction tube having a catalyst packed therein is adjusted in a manner wherein a reaction tube showing a pressure loss less than an average pressure loss for the total reaction tubes is additionally packed with an inert material in its portion near the entrance of a raw material gas, or is removed of the catalyst and re-packed with the catalyst, and a reaction tube showing a pressure loss greater than the above average value is removed of the catalyst and then re-packed with the catalyst, so as for the each reaction tube to show a pressure loss within the range of ± 20 % of the average value. The method can provide a vapor phase catalytic oxidation method which is almost free of variations in the reaction states in respective reaction tubes.
摘要翻译：一种气相催化氧化方法，涉及使用具有多个反应管的固定床多管热交换型反应器，将装有催化剂的反应管内的反应原料气体供给反应产物气体，其特征在于，其中装有催化剂的每个反应管的压力损失被调节，其中显示出低于总反应管的平均压力损失的压力损失的反应管在其中另外填充惰性材料在原料气体的入口附近的部分，或者将催化剂除去并重新填充催化剂，并且除去大于上述平均值的压力损失的反应管，然后将其重新填充催化剂，以使每个反应管显示的压力损失在±20％的平均值的范围内。该方法可以提供几乎没有各反应管中的反应状态变化的气相催化氧化方法。

7. 发明申请

WO2003040002A1 易重合性化合物の貯蔵タンク及び貯蔵方法审中-公开
标题翻译：储存罐易于聚合的化合物和储存方法
公开(公告)号：WO2003040002A1
公开(公告)日：2003-05-15
申请号：PCT/JP2002/011468
申请日：2002-11-01
申请人：三菱化学株式会社 , 矢田修平 , 小川寧之 , 鈴木芳郎 , 神野公克 , 保坂浩親 , 強力正康
发明人：矢田修平 , 小川寧之 , 鈴木芳郎 , 神野公克 , 保坂浩親 , 強力正康
IPC分类号： B65D90/00
CPC分类号： B01J19/00 , B01J2219/00006 , B01J2219/00083 , B01J2219/00247 , B01J2219/00252 , B01J2219/00254 , Y10T137/0391 , Y10T137/6416 , Y10T137/6579 , Y10T137/85978
摘要： A storage tank for an easily polymerizable compound having an inlet line and a delivery line, characterized in that it further has one or more of circulation lines for preventing the clogging of pipe lines a method for storing an easily polymerizable compound which comprises storing the easily polymerizable compound in the storage tank while circulating the compound by the use of the circulating line a method and facilities for connecting the lines which comprises using a flange, a bolt or a nut comprising a material having the corrosion resistance to a corrosive liquid a method for polymerizing methacrylic acid or a derivative thereof, characterized in that in a step of producing and/or purifying it, the temperature of the resulting purified or off-spec methacrylic acid or its derivative to be fed to the storage tank is controlled to a temperature of a liquid being stored in the storage tank or lower.
摘要翻译：一种用于容易聚合的化合物的储罐，其具有入口管线和输送管线，其特征在于，还具有一个或多个用于防止管道堵塞的循环管线，用于储存容易聚合的化合物的方法，该方法包括将容易聚合的在使用循环管线循环化合物的同时，将化合物复合在一起，连接线路的方法和设施包括使用法兰，螺栓或螺母，其包括具有耐腐蚀性的材料与腐蚀性液体的聚合方法甲基丙烯酸或其衍生物，其特征在于在制备和/或纯化的步骤中，将所得到的纯化或不合格的甲基丙烯酸或其衍生物进料至储罐的温度控制在液体储存在储罐中或更低。

8. 发明申请

WO2003031384A1 (メタ)アクリル酸類の製造方法および蒸留方法审中-公开
标题翻译：生产甲基丙烯酸酯化合物的方法和蒸馏方法
公开(公告)号：WO2003031384A1
公开(公告)日：2003-04-17
申请号：PCT/JP2002/010411
申请日：2002-10-07
申请人：三菱化学株式会社 , 矢田修平 , 小川寧之 , 鈴木芳郎 , 神野公克 , 保坂浩親 , 高崎研二 , 強力正康
发明人：矢田修平 , 小川寧之 , 鈴木芳郎 , 神野公克 , 保坂浩親 , 高崎研二 , 強力正康
IPC分类号： C07C51/44
CPC分类号： C07C51/44 , B01D3/14 , B01D3/146 , B01D3/42 , B01D3/4211 , C07C67/54 , C07C57/04 , C07C69/54
摘要： A process for the production of a (meth)acrylic compound which involves shutdown and startup of a distilling column, wherein in the shutdown, the heating of a reboiler attached to the distilling column is stopped and then the reboiler is rapidly cooled and/or wherein in the startup, the inner wall surface of the distilling column is heated to a temperature higher than the condensation temperature of the (meth)acrylic compound and the distilling column is started up with the inner wall surface heated. Since the polymerization in a distilling column can be inhibited according to this process, the distilling column can be shut down early and safely, which enables the long−term stable distillation of acrylic monomers.
摘要翻译：一种生产涉及关闭和启动蒸馏塔的（甲基）丙烯酸化合物的方法，其中在关闭时，停止连接到蒸馏塔的再沸器的加热，然后再沸器被快速冷却和/或其中在启动时，将蒸馏塔的内壁表面加热到高于（甲基）丙烯酸化合物的冷凝温度的温度，并且在加热的内壁表面开始蒸馏塔。由于根据该方法可以抑制蒸馏塔中的聚合，所以可以提早关闭蒸馏塔，从而能够长期稳定地蒸馏丙烯酸单体。

9. 发明申请

WO2003053557A1 易重合性物質の取り扱い装置及び方法、減圧下にある装置からの液体の抜き出し装置、及び易重合性物質の製造方法审中-公开
标题翻译：用于处理聚合物质的装置和方法，用于在降低压力下从装置中提取液体的装置，以及制造聚合聚合物质的方法
公开(公告)号：WO2003053557A1
公开(公告)日：2003-07-03
申请号：PCT/JP2002/013373
申请日：2002-12-20
申请人：三菱化学株式会社 , 矢田修平 , 小川寧之 , 保坂浩親 , 鈴木芳郎 , 中村光夫
发明人：矢田修平 , 小川寧之 , 保坂浩親 , 鈴木芳郎 , 中村光夫
IPC分类号： B01J3/02
CPC分类号： C07C51/44 , B01D3/14 , B01J2219/00006 , B01J2219/00162 , B01J2219/00164 , B01J2219/00247 , B01J2219/00254 , C07C67/54 , Y10S203/07 , Y10S203/09 , Y10S203/22 , Y10T137/0396 , Y10T137/1044 , Y10T137/86083 , Y10T137/86718 , C07C57/04 , C07C69/54
摘要： A device capable of distilling and refining lase-of-polymerization substance, wherein piping is performed so that, when a strainer during operation is switched to a spare one, the strainer can be switched after air inside the spare strainer is replaced with pumped liquid to eliminate the air in the spare strainer so as to switch the strainer installed on the upstream side of a liquid extracting pump in a vacuum distillation tower for distilling and refining the lase-of-polymerization substance without causing any trouble with the operation of the distillation tower, and a means for measuring a pressure difference across the upstream side and downstream side of the strainer during operation is installed to switch, at an appropriate timing, two or more units of strainers disposed parallel with each other so as to efficiently manufacture the lase-of-polymerization substance.
摘要翻译：一种能够蒸馏和精炼聚合物质的装置，其中执行管道，使得当操作过程中的过滤器切换到备用过滤器时，可以在备用过滤器内的空气被泵送的液体替换之后切换过滤器消除备用过滤器中的空气，以将安装在液体提取泵上游侧的过滤器切换到真空蒸馏塔中，用于蒸馏和精制聚合物质，而不会对蒸馏塔的操作造成任何麻烦并且安装用于在操作期间测量过滤器的上游侧和下游侧的压力差的装置，以在适当的时刻切换彼此平行设置的两个或更多个单元的过滤器，以便有效地制造过滤器，聚合物质。

10. 发明申请

WO2003047746A1 酸化反応器、（メタ）アクリル酸類の製造方法および易重合性化合物の分析方法审中-公开
标题翻译：氧化反应器，生产（甲基）丙烯酸或类似物的方法，以及分析易溶聚合化合物的方法
公开(公告)号：WO2003047746A1
公开(公告)日：2003-06-12
申请号：PCT/JP2002/012654
申请日：2002-12-03
申请人：三菱化学株式会社 , 矢田修平 , 小川寧之 , 鈴木芳郎 , 保坂浩親 , 佐村康彦
发明人：矢田修平 , 小川寧之 , 鈴木芳郎 , 保坂浩親 , 佐村康彦
IPC分类号： B01J19/00
CPC分类号： B01J8/008 , B01J4/002 , B01J8/02 , B01J19/26 , B01J2208/00973 , B01J2208/025 , B01J2219/00006 , B01J2219/00119 , B01J2219/00247 , B01J2219/00252 , C07C45/35 , C07C51/215 , C07C51/252 , G01N1/2035 , G01N1/2247 , G01N31/005 , G01N33/44 , G01N2001/1062 , G01N2001/2057 , G01N2001/2285 , Y10T436/117497 , C07C47/22 , C07C57/04
摘要： An oxidation reactor having a manhole nozzle provided being projected from the body of the reactor, characterized in that the manhole nozzle has a partition plate separating the inside of the manhole nozzle from the inside of the reactor; the above oxidation reactor further having a means for supplying an inert gas to the inside of the manhole nozzle; a method for producing (meth)acrylic acid or (meth)acrolein through the catalytic gas phase oxidation of propane, propylene, or isobutylene in an oxidation reactor, characterized in that the above oxidation reactor is used; and a method for analyzing an easily polymerizable compound wherein a gas containing the easily polymerizable compound is introduced to an analyzing instrument through a sampling tube, characterized in that a double tube is used as the sampling tube and a heating medium is supplied to an outer tube thereof. The oxidation reactor allows the stable production of the above products, and the method for analysis allows the inhibition of condensation and polymerization of an easily polymerizable compound in a sampling tube, which leads to an on-line analysis being precise and stable for a long period of time.
摘要翻译：一种氧化反应器，其具有从反应器主体突出设置的人孔喷嘴，其特征在于，所述井下喷嘴具有将所述井下喷嘴的内部与所述反应器内部分隔开的隔板; 上述氧化反应器还具有用于向人孔喷嘴内部供应惰性气体的装置; 通过氧化反应器中丙烷，丙烯或异丁烯的催化气相氧化制备（甲基）丙烯酸或（甲基）丙烯醛的方法，其特征在于使用上述氧化反应器; 以及用于分析容易聚合的化合物的方法，其中将含有易聚合性化合物的气体通过采样管引入分析仪器，其特征在于，使用双管作为采样管，并将加热介质供应到外管它们。氧化反应器能够稳定地生产上述产物，并且分析方法允许抑制采样管中易于聚合的化合物的缩合和聚合，这导致在线分析长时间精确和稳定的时间。

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