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    • 1. 发明申请
    • CHEMICAL AGENTS CAPABLE OF FORMING COVALENT 3-D NETWORKS
    • 形成合并三维网络的化学试剂
    • WO2010100410A1
    • 2010-09-10
    • PCT/GB2010/000368
    • 2010-03-02
    • OXFORD ADVANCED SURFACES LTDGRIFFITHS, Jon-PaulEASON, Michael, DouglasBEAL, Sarah, LouiseVICKERS, SarahWINCEWICZ, Richard, CharlesKING, David, Simon
    • GRIFFITHS, Jon-PaulEASON, Michael, DouglasBEAL, Sarah, LouiseVICKERS, SarahWINCEWICZ, Richard, CharlesKING, David, Simon
    • C07C245/14C07C251/80
    • C07C311/49C08J7/04Y10T428/2998Y10T428/31536
    • The invention provides a functionalised compound of formula (II), which functionalised compound comprises n carbene precursor groups which are the same or different, wherein n is an integer equal to or greater than 3: wherein x is 1, E is a group which is capable of being converted into a carbene reactive intermediate group, Q is a core moiety, a polymer or a dendrimer, and each of the [R] x -E-L- groups, which are the same or different, is independently selected from a group of formula (Ie) and a group of formula (Ia): wherein L is a single bond or a linker group as defined herein, R is a terminal group as defined herein, and R 1 is as defined herein. Further provided is the use of the functionalised compound as an agent for producing a chemically-bound three-dimensional network on or within a substrate. Processes for producing the following products using the functionalised compounds of the invention are also provided, as are the resulting products: a chemically- bound three-dimensional network on or within a substrate; a chemically-bound three- dimensional network between a first substrate and a second substrate; a film or a coating; a coated substrate; a product which comprises a first substrate, a second substrate and a composition at an interface of the first and second substrates; a treated particle. The invention further provides a process for cross linking a first substrate to a second substrate, using a functionalised compound of the invention, and the resulting cross-linked product. The invention also provides a process for producing the functionalised compounds of the invention.
    • 本发明提供了官能化的式(II)化合物,该官能化化合物包含相同或不同的n个卡宾前体基团,其中n为等于或大于3的整数,其中x为1,E为 能够转化为卡宾反应性中间体,Q是核心部分,聚合物或树枝状大分子,并且相同或不同的[R] xEL-基团中的每一个独立地选自式( Ie)和式(Ia)的基团:其中L是单键或如本文所定义的连接基团,R是如本文所定义的端基,并且R 1如本文所定义。 还提供了使用官能化化合物作为在基底上或内部产生化学结合的三维网络的试剂。 还提供了使用本发明的官能化化合物生产以下产物的方法,以及所得产物:底物上或内部的化学结合的三维网络; 在第一衬底和第二衬底之间的化学结合的三维网络; 薄膜或涂层; 涂布基材; 产品,其包括第一基板,第二基板和在第一和第二基板的界面处的组合物; 经处理的颗粒。 本发明还提供了使用本发明的官能化化合物和所得交联产物将第一底物交联到第二底物的方法。 本发明还提供了制备本发明的官能化化合物的方法。
    • 2. 发明申请
    • CROSS-LINKABLE POLYMERS
    • 交联聚合物
    • WO2010100413A3
    • 2010-11-18
    • PCT/GB2010000373
    • 2010-03-02
    • OXFORD ADVANCED SURFACES LTDGRIFFITHS JON PAULEASON MICHAEL DOUGLASWINCEWICZ RICHARD CHARLESHUNTER STUART JAMES
    • GRIFFITHS JON PAULEASON MICHAEL DOUGLASWINCEWICZ RICHARD CHARLESHUNTER STUART JAMES
    • C07C311/49C08J3/24C08K5/435C09J125/08
    • C07C311/49C08J7/04Y10T428/2998Y10T428/31536
    • The invention provides a functionalised compound which is a sulfonylhydrazone compound of formula (XXXa) wherein n is an integer equal to or greater than 3; L is a single bond or a linker group of formula (XII) as defined herein, R and R2 are as defined herein, and Q is a polymer or a dendrimer. Further provided are the uses of the functionalised compound as a cross linking agent or as an adhesive. The invention further provides a process for cross linking or adhering a first substrate to a second substrate, which process comprises contacting the first and second substrates with a functionalised compound of the invention, and generating carbene reactive intermediate groups from the reactive intermediate precursor groups, so that carbene reactive intermediate groups react with the first and second substrates, thereby cross linking or adhering the first and second substrates. The resulting cross-linked products are also provided. The invention also provides an adhesive composition comprising the functionalised compound of the invention, a process for producing the functionalised compounds of the invention, and precursor compounds which are used in that process.
    • 本发明提供了官能化的化合物,其是式(XXXa)的磺酰腙化合物,其中n是等于或大于3的整数; L是如本文所定义的式(XII)的单键或连接基团,R和R 2如本文所定义,并且Q是聚合物或树枝状聚合物。 还提供了官能化的化合物作为交联剂或作为粘合剂的用途。 本发明进一步提供了用于将第一基材交联或粘合至第二基材的方法,该方法包括使第一和第二基材与本发明的官能化的化合物接触并由反应性中间体前体基团产生卡宾反应性中间体基团,如此 卡宾反应性中间体基团与第一和第二基底反应,从而交联或粘附第一和第二基底。 还提供了所得到的交联产物。 本发明还提供了包含本发明的官能化的化合物的粘合剂组合物,用于制备本发明的官能化的化合物的方法以及在该方法中使用的前体化合物。
    • 4. 发明申请
    • CROSS-LINKABLE POLYMERS
    • 交联聚合物
    • WO2010100413A2
    • 2010-09-10
    • PCT/GB2010/000373
    • 2010-03-02
    • OXFORD ADVANCED SURFACES LTDGRIFFITHS, Jon, PaulEASON, Michael, DouglasWINCEWICZ, Richard, CharlesHUNTER, Stuart, James
    • GRIFFITHS, Jon, PaulEASON, Michael, DouglasWINCEWICZ, Richard, CharlesHUNTER, Stuart, James
    • C07C311/49C08J7/04Y10T428/2998Y10T428/31536
    • The invention provides a functionalised compound which is a sulfonylhydrazone compound of formula (XXXa) wherein n is an integer equal to or greater than 3; L is a single bond or a linker group of formula (XII) as defined herein, R and R2 are as defined herein, and Q is a polymer or a dendrimer. Further provided are the uses of the functionalised compound as a cross linking agent or as an adhesive. The invention further provides a process for cross linking or adhering a first substrate to a second substrate, which process comprises contacting the first and second substrates with a functionalised compound of the invention, and generating carbene reactive intermediate groups from the reactive intermediate precursor groups, so that carbene reactive intermediate groups react with the first and second substrates, thereby cross linking or adhering the first and second substrates. The resulting cross-linked products are also provided. The invention also provides an adhesive composition comprising the functionalised compound of the invention, a process for producing the functionalised compounds of the invention, and precursor compounds which are used in that process.
    • 本发明提供官能化化合物,其为式(ⅩⅩaa)的磺酰腙化合物,其中n为等于或大于3的整数; L是如本文所定义的单键或式(XII)的连接基团,R和R 2如本文所定义,Q是聚合物或树枝状聚合物。 还提供了官能化化合物作为交联剂或粘合剂的用途。 本发明还提供了将第一基底交联或粘合到第二基底的方法,该方法包括使第一和第二底物与本发明的官能化化合物接触,并从反应性中间体前体基团产生卡宾反应性中间体,因此 该卡宾反应性中间体与第一和第二基材反应,从而交联或粘合第一和第二基材。 还提供了所得的交联产物。 本发明还提供了包含本发明的官能化化合物,本发明的官能化化合物的制备方法和在该方法中使用的前体化合物的粘合剂组合物。