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    • 9. 发明申请
    • CURABLE COMPOSITIONS PREPARED FROM MULTIFUNCTIONAL AND HYBRID N-VINYLFORMAMIDE COMPOUNDS
    • 多功能和混合N-乙烯酰胺化合物制备的可固化组合物
    • WO2009099436A1
    • 2009-08-13
    • PCT/US2008/052983
    • 2008-02-05
    • NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATIONMUSA, Osama, M.SRIDHAR, Laxmisha, M.KONG, Shengqian
    • MUSA, Osama, M.SRIDHAR, Laxmisha, M.KONG, Shengqian
    • C08F12/28C08L33/24C08K3/00
    • C09D139/02C08F212/34C08F226/02C08F290/06C08F2222/1013C08F222/40C08F222/12
    • A curable composition comprises a multi-functional N-vinylformamide compound and/or a hybrid N-vinylformamide compound and an initiator, optionally, an additional curable compound; and optionally, a filler. The hybrid N-vinylformamide compound has a second reactive functionality in addition to N-vinylformamide functionality selected from the group consisting of acrylate, methacrylate, cyanoacrylate, maleimide, cinnamyl, maleate, fumarate, epoxy, oxetane, silane, styrenic, benzoxazine, oxazoline, vinyl ester, vinyl ether, and combinations of these. These multi-functional and hybrid N-vinylformamide compounds are prepared through an alkylation procedure employing either cesium carbonate or potassium t-butoxide as base to deprotonate, from the nitrogen atom, the hydrogen atom bonded to the nitrogen atom. Reaction schemes include: formulae (I) and (II) in which n = 2 to 100; v is 1 to 100; w is 1 to 10; Y is an aliphatic or aromatic hydrocarbon {including those with heteroatoms); X is a second reactive functionality; and L is a leaving group; and each L and X present can be the same or different.
    • 可固化组合物包含多官能N-乙烯基甲酰胺化合物和/或杂化N-乙烯基甲酰胺化合物和引发剂,任选另外的可固化化合物; 和任选的填料。 杂化N-乙烯基甲酰胺化合物除了选自丙烯酸酯,甲基丙烯酸酯,氰基丙烯酸酯,马来酰亚胺,肉桂基,马来酸酯,富马酸酯,环氧,氧杂环丁烷,硅烷,苯乙烯,苯并恶嗪,恶唑啉等的N-乙烯基甲酰胺官能团之外,具有第二反应性官能团。 乙烯基酯,乙烯基醚以及它们的组合。 这些多功能和杂化的N-乙烯基甲酰胺化合物是通过烷基化方法制备的,其使用碳酸铯或叔丁醇钾作为碱,从氮原子去除与氮原子键合的氢原子。 反应方案包括:式(I)和(II)其中n = 2至100; v为1〜100; w为1〜10; Y是脂族或芳族烃(包括具有杂原子的烃); X是第二反应性官能团; L是离去组; 并且存在的每个L和X可以相同或不同。