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    • 5. 发明申请
    • ORGANOMETALLIC COMPLEXES
    • 有机复合物
    • WO2007087223A2
    • 2007-08-02
    • PCT/US2007001372
    • 2007-01-19
    • DU PONTHERRON NORMANSHUEY STEVEN WMERLO JEFFREY A
    • HERRON NORMANSHUEY STEVEN WMERLO JEFFREY A
    • H01L51/00
    • H01L51/5016C09K11/06C09K2211/186H01L51/0081H01L51/0084H01L51/5048H05B33/20
    • The present disclosure relates to organometallic complexes and electronic devices containing the complexes. The complexes have the formula MY n Z, where n is 1 , 2, or 3; M is a metal in a +2, +3, or +4 oxidation state, Y is selected from an 8-hydroxyquinolate and a substituted 8-hydroxyquinolate, and Z is a phenolate. At least one Y is a substituted 8-hydroxyquinolate having the formula (III) where: R 1 and R 2 are the same or different at each occurrence and each represents one or more of a substituent selected from the group consisting of H, alkyl, fluoroalkyl, aryl, fluoroaryl, alkylaryl, alkoxy, aryloxy, fluoroalkoxy, fluoroaryloxy, heteroalkyl, fluoroheteroalkyl, heteroaryl, fluoroheteroaryl, heteroalkylaryl, heteroalkoxy, heteroaryloxy, fluoroheteroalkoxy, fluoroheteroaryloxy, a solvent- solubilizing group, and a Tg enhancing group, wherein at least one of R 1 and R 2 is a solvent-solubilizing or Tg enhancing group; and R 3 is selected from the group consisting of H, an alkyl group, and a substituted alkyl group.
    • 本公开涉及含有该配合物的有机金属配合物和电子装置。 络合物具有式MY N Z Z,其中n为1,2或3; M是+2,+3或+4氧化态的金属,Y选自8-羟基喹啉酸盐和取代的8-羟基喹喔啉,Z是酚盐。 至少一个Y是具有式(III)的取代的8-羟基喹喔啉,其中:R 1和R 2各自在每次出现时相同或不同,并且各自代表一个或 更多的选自H,烷基,氟烷基,芳基,氟芳基,烷芳基,烷氧基,芳氧基,氟烷氧基,氟芳氧基,杂烷基,氟代杂烷基,杂芳基,氟杂芳基,杂烷基芳基,杂烷氧基,杂芳氧基,氟代杂环氧基,氟代杂芳基氧基,溶剂 - 增溶基团和Tg增强基团,其中R 1和R 2中的至少一个是溶剂增溶或Tg增强基团; 和R 3选自H,烷基和取代的烷基。