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    • 2. 发明申请
    • METHOD FOR THE PRODUCTION OF CARBOXYLIC ACID METAL SOAPS
    • 生产羧酸金属盐的方法
    • WO2005007864A3
    • 2005-04-14
    • PCT/EP2004007361
    • 2004-07-06
    • COGNIS DEUTSCHLAND GMBHSCHOERKEN ULRICHBUSCH STEFANBOTH SABINEMAHNKE EIKE ULFCIRUELOS SANTIAGO
    • SCHOERKEN ULRICHBUSCH STEFANBOTH SABINEMAHNKE EIKE ULFCIRUELOS SANTIAGO
    • A23L1/30A23L1/302C12N9/98C12P7/64A23K1/00A23K1/16
    • C12N9/98A23L33/11A23L33/12A23L33/15C12P7/64
    • The invention relates to a method for the production of metal soaps, wherein alkyl esters of single or multiple unsaturated carboxylic acids are enzymatically converted into hydrolase in the presence of a basic metal salt. The invention relates to the use of multiple unsaturated carboxylic acid metal soaps produced according to the inventive method as food supplements and/or as food additives and/or as pharmaceutical fatty acid derivatives. The invention also relates to preparations containing multiple unsaturated carboxylic acid metal salts in the form of a granulate produced according to the inventive method as carriers or capsule material and one or several additional components which are selected from the group which is made up of enzymes, vitamins, antioxidants, conservation agents, colorants, carotinoides, sterols, flavone and isoflavone compounds and fatty acid derivatives. The invention further relates to a method for the production of preparations, wherein one or several additional components are directly incorporated into the granulate made of multiple unsaturated carboxylic acid metal soaps during enzymatic conversion, and to the use of the inventive preparations as food supplements and/or food additives and/or as pharmaceutical fatty acid derivatives.
    • 用于制备其中的单或多不饱和的羧酸在碱性金属盐的存在下的烷基酯,提出用水解酶和使用的金属皂的多不饱和的酶促反应的金属皂的方法由本发明的方法作为食品补充剂和/或作为饲料添加剂制备羧酸 和/或作为药物脂肪酸衍生物。 此外,制剂提出,其包括在通过本发明中用作从由酶,维生素,抗氧化剂,防腐剂,着色剂形成的组中选择的载体或封装材料,和一种或多种附加组分的方法制备的颗粒剂形式的多不饱和羧酸的金属皂 ,类胡萝卜素,甾醇,黄酮和异黄酮化合物和脂肪酸衍生物。 除了这些制剂wwird进一步提出了一种制造方法,其中一种或多种附加组分可以以多不饱和羧酸的金属皂颗粒中的酶反应过程中直接掺入的制剂,以及使用本发明组合物作为膳食补充剂和/或作为饲料添加剂的 和/或作为药物脂肪酸衍生物。
    • 6. 发明申请
    • PROCESS FOR PRODUCTION OF FATTY ACIDS, FATTY ACID ESTERS AND STEROLESTERS FROM SOAPSTOCK
    • 用于生产脂肪酸,脂肪酸酯和皂甙的脱水剂的方法
    • WO2008003420A3
    • 2008-02-28
    • PCT/EP2007005663
    • 2007-06-27
    • COGNIS IP MAN GMBHKEMPERS PETERSCHOERKEN ULRICHWOLF THOMASSATO SETSUOBUENO DE ALMEIDA WANDERSONSILVA BIZZARRI PABLOSHIGUERU ARAUJO ALEXSSANDER
    • KEMPERS PETERSCHOERKEN ULRICHWOLF THOMASSATO SETSUOBUENO DE ALMEIDA WANDERSONSILVA BIZZARRI PABLOSHIGUERU ARAUJO ALEXSSANDER
    • C11B13/02A23K1/16C11C3/10
    • C11B13/02A23L33/11C10G2300/1011C11C1/045C11C1/10C11C3/003Y02E50/13Y02P30/20Y02W30/74
    • The invention relates to a first process for production of fatty acids directly from any soapstock generated in the alkali refining process comprising of a) adding a lipase directly to the alkaline soapstock to facilitate hydrolysis of mono-,di- and triglycerides without prior neutralisation b) neutralizing and splitting the soaps with strong acids until reaching pH 1-6, c) separating the fatty acid phase from the aqueous by settling and/or centrifugation. In a second embodiment a second process for production of fatty acids directly from any soapstock is subject of the invention. This process comprises i) neutralizing and splitting the soaps with strong acids until reaching pH 1-6 ii) adding a lipase to facilitate mono-/di-/triglyceride hydrolysis iii) separating the fatty acid phase from the aqueous by settling and / or centrifugation In a further subject matter the invention deals with the use of said fatty acids for enzymatic or chemical synthesis of C1 to C6 alcanol esters and / or for chemical dimerisation of the fatty acids. As a consequence the invention also refers to a process for obtaining sterolesters and/or fatty acid esters characterized in that the fatty acids obtained according to the processes for production of fatty acids directly from any soapstock as aforementioned described are a) esterified with C1 to C6 alkanol with a Lipase that is selective for fatty acids and does not transesterify the sterolesters b) the fatty acid esters are separated from the sterolesters by distillation The use of said sterolesters for animal feed, food, health foods and as pharmaceutical agent for lowering cholesterol and/or as precursor for steroid synthesis as well as the use of said fatty acid esters as solvent, for the production of fatty alcohols, as biofuel, and biodiesel, as plastisicer or for dimerization is also subject of the invention.
    • 本发明涉及直接从碱炼油工艺中产生的任何皂料生产脂肪酸的第一种方法,包括a)将脂肪酶直接加入到碱性皂脚中以促进单甘油酯,二甘油酯和甘油三酯的水解,而无需事先中和b) 用强酸中和和分解肥皂直至达到pH1-6,c)通过沉降和/或离心将脂肪酸相与水分离。 在第二个实施方案中,直接从任何皂脚生产脂肪酸的第二种方法是本发明的主题。 该方法包括i)用强酸中和和分解肥皂直至达到pH 1-6,ii)加入脂肪酶以促进甘油一酯/甘油二酯/甘油三酯水解,iii)通过沉降和/或离心将脂肪酸相与水分离 在另一主题中,本发明涉及所述脂肪酸用于酶促或化学合成C 1至C 6烷醇酯和/或用于化学二聚化脂肪酸的用途。 因此,本发明还涉及用于获得胆固醇酯和/或脂肪酸酯的方法,其特征在于根据如前所述的任何皂料直接生产脂肪酸的方法获得的脂肪酸a)用C 1至C 6酯化 链烷醇与对脂肪酸具有选择性且不使胆固醇酯交换酯基的脂肪酶反应b)通过蒸馏将脂肪酸酯与胆固醇酯分离所述胆固醇酯用于动物饲料,食品,保健食品和作为药物用于降低胆固醇和 /或作为类固醇合成的前体以及所述脂肪酸酯作为溶剂的用途,用于生产脂肪醇,生物燃料和生物柴油,作为增塑剂或用于二聚化也是本发明的主题。
    • 9. 发明申请
    • DERIVATIZATION OF HYDROXYACETALS AND HYDROXYACETAL MIXTURES
    • 衍生化hydroxyacetals和HYDROXYACETALGEMISCHEN的
    • WO2012031933A3
    • 2012-06-14
    • PCT/EP2011064844
    • 2011-08-29
    • COGNIS IP MAN GMBHBELLER MATTHIASKRAGL UDOSCHOERKEN ULRICHPAETZOLD ECKHARDJACKSTELL RALF
    • BELLER MATTHIASKRAGL UDOSCHOERKEN ULRICHPAETZOLD ECKHARDJACKSTELL RALF
    • C07D317/22C07D319/06
    • C07D317/22C07D319/06
    • A method is described in which hydroxyacetals or hydroxyacetal mixtures are used for catalytic C-O-C linking reactions to form ethers, especially by telomerizing diene systems, wherein palladium-(0) complexes are used as catalysts, carbonylating olefins with rhodium-(0) complexes and reacting the same with the hydroxyacetals or hydroxyacetal mixtures, and dimerizing the hydroxyacetals or hydroxyacetal mixtures with ruthenium-(0) complexes while eliminating water. The method allows the carbon chain of the hydroxyacetal or hydroxyacetal mixture used to be extended by several C atoms, the calorific value of the products to be increased, and the evaporation temperature to be lowered. The products can be used as fuels, solvents, detergents, cosmetics, softeners, stabilizers, pharmaceuticals, fungicides and microbicides, flavors, intermediate products, and as additives in various fields of application.
    • 描述了从hydroxyacetals或Hydroxyacetalgemischen催化COC-键形成于醚形成反应,尤其是由二烯系统,其中,钯(0)配合物用作催化剂,烯烃与铑(0)配合物和羰基化的调聚反应开始的处理他们的 与hydroxyacetals或共混物反应是还有hydroxyacetals的二聚化或 - 与钌的混合物(0)同时消除水络合物。 该方法允许使用的羟基缩醛或的碳链的延伸 - 几个C原子的混合物,并增加了产品的热值的和在蒸发温度的降低。 该产品可以用作燃料,溶剂,洗涤剂,化妆品,增塑剂,稳定剂,药物,杀真菌剂和杀微生物剂,香料物质,中间体和作为添加剂用于各种应用。