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    • 4. 发明申请
    • METHOD OF CARRYING OUT A WELLBORE OPERATION
    • 执行井筒操作的方法
    • WO2010010325A1
    • 2010-01-28
    • PCT/GB2009/001765
    • 2009-07-17
    • BP EXPLORATION OPERATING COMPANY LIMITEDSAWDON, Christopher Alan
    • SAWDON, Christopher Alan
    • C09K8/36C09K8/52B01F17/00
    • C09K8/36C09K8/52C09K2208/18
    • The invention relates to a wellbore operation, which includes the steps of: (a) introducing into a wellbore a wellbore fluid in the form of a water-in-oil emulsion comprising a dispersed brine phase and comprising as an emulsifier at least one polymer which contains both hydrophilic units and hydrophobic units, at least some of said hydrophilic units containing sulfonate groups, and at least some of said hydrophobic units containing pendant alkyl groups having at least 8 carbon atoms, wherein the sulfonate groups have been introduced into said polymer by first preparing a precursor polymer containing units derived from at least one unsaturated carboxylic acid and/or unsaturated anhydride and then reacting at least a portion of the carboxylic acid and/or anhydride groups of the precursor polymer with a compound of general formula R 1 2 N(CH 2 ) n SO 3 X (I) and/or a compound of general formula HO(CH 2 ) n SO 3 X (II) wherein each R1 is independently selected from hydrogen, methyl or ethyl, X is H, ammonium, or a Group IA metal, and n is an integer of from 1 to 6; (b) allowing a filter-cake to form; and subsequently (c) bringing an aqueous-based fluid into contact with the filter-cake, said aqueous- based fluid having a level of salinity which is lower than the level of salinity of said dispersed brine phase in said wellbore fluid.
    • 本发明涉及井眼操作,其包括以下步骤:(a)将包含分散的盐水相的油包水乳液形式的井眼流体​​引入井筒中,并且包含作为乳化剂的至少一种聚合物, 含有亲水单元和疏水单元,至少一些所述含有磺酸盐基团的亲水单元和至少一些含有至少8个碳原子的侧基烷基的所述疏水单元,其中所述磺酸盐基团已经通过第一 制备含有衍生自至少一种不饱和羧酸和/或不饱和酸酐的单元的前体聚合物,然后将前体聚合物的至少一部分羧酸和/或酸酐基与通式为R 1 N 2(CH 2) nSO 3 X(I)和/或通式HO(CH 2)n SO 3 X(II)的化合物,其中每个R 1独立地选自氢,甲基或乙基,X是H,am 或IA族金属,n为1〜6的整数, (b)形成滤饼; 并且随后(c)使水基流体与滤饼接触,所述水基流体的盐度水平低于所述井筒流体中所述分散的盐水相的盐度水平。
    • 5. 发明申请
    • WELLBORE FLUID
    • 井底流体
    • WO2009047478A1
    • 2009-04-16
    • PCT/GB2008/003233
    • 2008-09-24
    • BP EXPLORATION OPERATING COMPANY LIMITEDSAWDON, Christopher, Alan
    • SAWDON, Christopher, Alan
    • C09K8/36C09K8/64
    • C09K8/36C09K8/502C09K8/52C09K2208/14
    • The invention provides an oil-based wellbore fluid in the form of an emulsion which comprises a continuous phase comprising an oil and, dispersed therein, a first dispersed liquid phase and a second separate dispersed liquid phase, the first dispersed liquid phase being a brine phase, and the second dispersed liquid phase comprising a polar organic liquid, said polar organic liquid being insoluble or sparingly soluble in the brine comprising said first dispersed liquid phase, but being soluble in pure water. There is also provided a method of carrying out a wellbore operation, which includes the steps of (a) introducing into a wellbore a wellbore fluid of the invention; (b) allowing a filter-cake to form; and subsequently (c) allowing a further fluid to come into contact with the filter- cake, said further fluid having a level of salinity which is lower than the level of salinity of said first dispersed liquid phase, and being such that said polar organic liquid is soluble therein. The fluid of the invention may be used in a variety of drilling operations where a low-permeability filter-cake is required initially, but where higher permeability is required at a later stage.
    • 本发明提供一种乳液形式的油基井眼流体,其包括连续相,其包含油并分散在其中的第一分散液相和第二分离的分散液相,第一分散液相为盐水相 并且所述第二分散液相包含极性有机液体,所述极性有机液体不溶或微溶于包含所述第一分散液相的盐水中,但可溶于纯水中。 还提供了进行井眼操作的方法,其包括以下步骤:(a)将本发明的井眼流体​​引入井筒; (b)形成滤饼; 并且随后(c)允许另外的流体与滤饼接触,所述另外的流体的盐度水平低于所述第一分散液相的盐度水平,并且使得所述极性有机液体 在其中可溶。 本发明的流体可以用于首先需要低渗透性滤饼的各种钻井操作中,但是在稍后阶段需要更高的渗透性。
    • 7. 发明申请
    • METHOD OF CARRYING OUT A WELLBORE OPERATION
    • 执行井筒操作的方法
    • WO2012152889A1
    • 2012-11-15
    • PCT/EP2012/058690
    • 2012-05-10
    • BP EXPLORATION OPERATING COMPANY LIMITEDASTON, Mark SheltonGEORGE, Mary AnnSAWDON, Christopher Alan
    • ASTON, Mark SheltonGEORGE, Mary AnnSAWDON, Christopher Alan
    • C09K8/36
    • C09K8/36C09K8/34
    • A drilling mud comprising a base fluid in the form of a water-in-oil emulsion comprising droplets of a brine phase dispersed in a continuous oil phase wherein the brine phase has a dissolved salt concentration of at least 2.5 weight % and the emulsion is stabilized with (i) a first polymeric emulsifier that is a block or graft copolymer of the general formula (A-COO) m B, wherein m is an integer of at least 2, A is a polymeric component having a molecular weight of at least 500 and is the residue of an oil-soluble complex mono-carboxylic acid and (ii) a second polymeric emulsifier that is a graft copolymer of a polyvinylpyrrolidone polymer and an alpha olefin selected from the group consisting of C 14 to C 20 alphaolefins and mixtures thereof and wherein structural units derived from vinylpyrrolidone are present in the graft copolymer in an amount in the range of 40 to 60 mole%.
    • 一种钻井泥浆,其包括油包水乳液形式的基础液体,其包含分散在连续油相中的盐水相的液滴,其中所述盐水相具有至少2.5重量%的溶解盐浓度并且所述乳液被稳定 与(i)第一聚合乳化剂,其为通式(A-COO)mB的嵌段或接枝共聚物,其中m为至少2的整数,A为分子量为至少500的聚合物组分, 是油溶性络合物单羧酸的残基和(ii)第二聚合乳化剂,其是聚乙烯吡咯烷酮聚合物和选自C 14 -C 20α-烯烃及其混合物的α-烯烃的接枝共聚物,其中结构 衍生自乙烯基吡咯烷酮的单元以40至60摩尔%的量存在于接枝共聚物中。
    • 10. 发明申请
    • WELLBORE FLUID
    • 井底流体
    • WO2009047480A1
    • 2009-04-16
    • PCT/GB2008/003237
    • 2008-09-24
    • BP EXPLORATION OPERATING COMPANY LIMITEDSAWDON, Christopher Alan
    • SAWDON, Christopher Alan
    • C09K8/10C09K8/20C09K8/24C09K8/52C09K8/86C09K8/68
    • C09K8/514C09K8/10C09K8/206C09K8/28C09K8/52C09K8/68C09K8/90C09K2208/08C09K2208/18
    • A method of carrying out a wellbore operation, which includes the steps of: (a) introducing into a wellbore an aqueous-based wellbore fluid comprising: - an aqueous base fluid having a first level of salinity; and - at least one polymer dissolved in said aqueous base fluid at a concentration of at least 1.Og/1, said polymer (i) having a viscosity average molecular weight in the range of from 20,000 to 900,000; and (ii) having a molecular structure such that the polymer chains dissolved in said wellbore fluid adopt a globular conformation, while in a fluid of a second level of salinity, said second level being a lower level of salinity than said first level, the polymer chains adopt an extended conformation; (b) allowing a filter-cake including said polymer in globular conformation to form; and subsequently (c) bringing a second fluid into contact with the filter-cake, said second fluid having a level of salinity which is lower than the level of salinity of said aqueous base fluid such that said polymer chains in said filter-cake adopt an extended conformation, thereby increasing the permeability of said filter-cake. The invention also provides novel compositions for use in the method of the invention.
    • 一种进行井眼操作的方法,其包括以下步骤:(a)向井筒中引入含水基井筒流体,其包括: - 具有第一盐度水平的含水基液; 和 - 至少一种以至少1.0g / l的浓度溶于所述含水基础液体中的聚合物,所述聚合物(i)的粘均分子量为20,000至900,000; 和(ii)具有分子结构,使得溶解在所述井筒流体中的聚合物链采用球形构象,而在第二水平盐度的流体中,所述第二水平比所述第一水平低的盐度水平,所述聚合物 链采用扩展构象; (b)使含有球状构象的所述聚合物的滤饼形成; 并且随后(c)使第二流体与滤饼接触,所述第二流体的盐度水平低于所述含水基础流体的盐度水平,使得所述滤饼中的所述聚合物链采用 扩展构象,从而增加所述滤饼的渗透性。 本发明还提供了用于本发明方法的新型组合物。