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1. 发明申请

WO2009012933A1 PLASTIC COMPONENT FOR A LIGHTING SYSTEMS 审中-公开
标题翻译：用于照明系统的塑料组件
公开(公告)号：WO2009012933A1
公开(公告)日：2009-01-29
申请号：PCT/EP2008/005866
申请日：2008-07-17
申请人： DSM IP ASSETS B.V. , RULKENS, Rudy , VAN DIJK, Hans, Klaas , JAIN, Sanjay, Kumar, Ramesh, Kumar
发明人： RULKENS, Rudy , VAN DIJK, Hans, Klaas , JAIN, Sanjay, Kumar, Ramesh, Kumar
IPC分类号： C08K3/00 , C08L77/06 , H01L33/00 , C08G69/26
CPC分类号： C08K3/0008 , C08G69/265 , C08K3/01 , C08K3/013 , C08L77/06 , C08L77/10 , C08K3/0033
摘要： The invention relates to a plastic component for use in a lighting system, the plastic component comprising a semi-aromatic polyamide (X) comprising repeat units derived from aliphatic diamines and dicarboxylic acids wherein: (a) the aliphatic diamines consist a mixture of 10-70 mole% of a short chain aliphatic diamine with 2-5 C atoms and 30-90 mole % of a long chain aliphatic diamine with at least 6 C atoms; (b) the dicarboxylic acids consist of a mixture of 5-65 mole% aliphatic dicarboxylic acid and optionally aromatic dicarboxylic acid other than terephthalic acid, and 35-95 mole % terephthalic acid; and (c) the combined molar amount of terephthalic acid and the long chain aliphatic diamine is at least 60 mole %, relative to the total molar amount of the dicarboxylic acids and diamines. The invention also relates to a polymer composition that can be used for making the said plastic component comprising 100 pbw of a semi-aromatic polyamide (X) and 1-250 pbw of an inorganic material.
摘要翻译：本发明涉及一种用于照明系统的塑料部件，该塑料部件包括半芳族聚酰胺（X），其包含衍生自脂族二胺和二羧酸的重复单元，其中：（a）脂族二胺由10- 70摩尔％的具有2-5个C原子的短链脂族二胺和30-90摩尔％具有至少6个C原子的长链脂族二胺; （b）二羧酸由5-65摩尔％脂族二羧酸和除对苯二甲酸之外的任选的芳族二羧酸和35-95摩尔％对苯二甲酸的混合物组成; 和（c）相对于二羧酸和二胺的总摩尔量，对苯二甲酸和长链脂族二胺的组合摩尔量为至少60摩尔％。本发明还涉及可用于制造所述塑料组分的聚合物组合物，其包含100pbw的半芳族聚酰胺（X）和1-250pbw的无机材料。

2. 发明申请

WO2009012932A1 POLYAMIDE COMPOSITIONS AND BOBBINS MADE THEREOF 审中-公开
标题翻译：聚酰胺组合物及其制备方法
公开(公告)号：WO2009012932A1
公开(公告)日：2009-01-29
申请号：PCT/EP2008/005865
申请日：2008-07-17
申请人： DSM IP ASSETS B.V. , RULKENS, Rudy , PELT, VAN, Wilfred, Wilhelmus, Gerardus, Johannes , KAO, Cheng-Yueh , HSU, Kang-Tse
发明人： RULKENS, Rudy , PELT, VAN, Wilfred, Wilhelmus, Gerardus, Johannes , KAO, Cheng-Yueh , HSU, Kang-Tse
IPC分类号： C08G69/26 , C08K3/00 , C08L77/06 , H01F41/06
CPC分类号： C08G69/265 , C08L77/06 , H01F5/02 , Y10T29/49071 , C08L2666/66
摘要： The invention relates to a bobbin for an electrical coil comprising an plastic core made of an electrically insulating plastic material and to a polyamide composition that can be used as the electrically insulating plastic material in the bobbin, comprising a semi-crystalline semi-aromatic polyamide comprising units derived from aliphatic diamines consisting of a mixture of 10-70 mole% of a short chain aliphatic diamine with 2-5 C atoms and 30-90 mole % of a long chain aliphatic diamine with at least 6 C atoms; and units derived from dicarboxylic acids consisting of a mixture of 5- 65 mole% aliphatic dicarboxylic acid and 35-95 mole % aromatic dicarboxylic acid comprising terephthalic acid, and wherein the combined molar amount of terephthalic acid and the long chain aliphatic diamine is at least 60 mole %, relative to the total molar amount of the dicarboxylic acids and diamines. The invention also relates to an electrical coil comprising the bobbin and an electrically conductive winding around the core of the bobbin.
摘要翻译：本发明涉及一种用于电线圈的线轴，其包括由电绝缘塑料材料制成的塑料芯和可用作线轴中的电绝缘塑料材料的聚酰胺组合物，其包含半结晶半芳族聚酰胺，其包含衍生自由10-70摩尔％短链脂族二胺与2-5个碳原子和30-90摩尔％长链脂族二胺与至少6个C原子的混合物组成的脂族二胺的单元; 和衍生自由5-65摩尔％脂族二羧酸和35-95摩尔％芳族二羧酸的对苯二甲酸的混合物组成的二羧酸的单元，其中对苯二甲酸和长链脂族二胺的组合摩尔量至少为 60摩尔％，相对于二羧酸和二胺的总摩尔量。本发明还涉及一种电线圈，其包括线轴和围绕线轴的芯的导电绕组。

3. 发明申请

WO2007085406A1 SEMI-CRYSTALLINE SEMI-AROMATIC POLYAMIDE 审中-公开
标题翻译：半结晶半芳族聚酰胺
公开(公告)号：WO2007085406A1
公开(公告)日：2007-08-02
申请号：PCT/EP2007/000529
申请日：2007-01-23
申请人： DSM IP ASSETS B.V. , RULKENS, Rudy , CROMBACH, Robert, Conrad, Barbara
发明人： RULKENS, Rudy , CROMBACH, Robert, Conrad, Barbara
IPC分类号： C08G69/26 , C08G69/28 , C08G69/30
CPC分类号： C08G69/265 , C08G69/02 , C08G69/26 , C08G81/028 , C08L77/06
摘要： The invention relates to a semi-crystalline semi-aromatic polyamide comprising A-A-B-B units derived from (a) dicarboxylic acids consisting of a mixture of aromatic dicarboxylic acid and aliphatic dicarboxylic acid and (b) diamines consisting of a mixture of long chain aliphatic diamine and short chain aliphatic diamine, wherein (a- i) the aromatic dicarboxylic acid consists for at least 80 mole % of terephthalic acid, and (a-ii) the aliphatic dicarboxylic acid constitutes at least 5 mole% of the dicarboxylic acids, (b-i) the short chain aliphatic diamine constitutes at least 10 mole% of the diamines, and (c) the aromatic dicarboxylic acid and the long chain aliphatic diamine constitute 60-90 mole % of the total molar amount of dicarboxylic acids and diamines.
摘要翻译：本发明涉及一种半结晶半芳族聚酰胺，其包含衍生自（a）由芳族二羧酸和脂族二羧酸的混合物组成的二羧酸的AABB单元和（b）由长链脂肪族二胺和短链脂肪族二胺的混合物组成的二胺链烯基二胺，其中（a-i）芳族二羧酸由至少80摩尔％的对苯二甲酸组成，和（a-ii）脂族二羧酸占二羧酸的至少5摩尔％，（b）短链脂肪族二胺构成二胺的至少10摩尔％，（c）芳香族二羧酸和长链脂肪族二胺构成二羧酸和二胺的总摩尔量的60〜90摩尔％。

4. 发明申请

WO2013004531A1 BRANCHED POLYAMIDE WITH DIFFERENT BLOCKS 审中-公开
标题翻译：分支聚酰胺与不同的块
公开(公告)号：WO2013004531A1
公开(公告)日：2013-01-10
申请号：PCT/EP2012/062213
申请日：2012-06-25
申请人： DSM IP Assets B.V. , KUKALYEKAR, Nileshkumar Prakash , WANG, Zhujuan , RULKENS, Rudy , LIGTHART, Godefridus Bernardus Wilhelmus Leonardus
发明人： KUKALYEKAR, Nileshkumar Prakash , WANG, Zhujuan , RULKENS, Rudy , LIGTHART, Godefridus Bernardus Wilhelmus Leonardus
IPC分类号： C08G69/36 , C08G69/28 , C08G69/30 , C08L77/00
CPC分类号： C08G81/00 , B29C49/0005 , C08G69/28 , C08G69/30 , C08G69/36 , C08L77/00
摘要： The invention relates to a high molecular weight branched polyamide polymer comprising (a) blocks predominantly consisting of AA-BB repeat units, (b) blocks predominantly consisting of AB repeat units, and (c) branching units. The invention also relates to a process for the preparation of the high molecular weight branched polyamide polymer, comprising (1) a melt-mixing step wherein an essentially linear polyamide prepolymer (X-1), predominantly consisting of AA-BB repeat units, an essentially linear polyamide (pre)polymer (X-2), predominantly consisting of AB repeat units, and a branching agent are provided to and mixed and heated in a melt mixing apparatus, thereby forming a mixed melt, and the mixed melt being cooled, thereby forming a solid mixture; and (2) a solid state post condensation step wherein the solid mixture is post-condensed at elevated temperature in the solid state, thereby forming a high molecular weight branched polyamide polymer.
摘要翻译：本发明涉及一种高分子量支化聚酰胺聚合物，其包含（a）主要由AA-BB重复单元组成的嵌段，（b）主要由AB重复单元组成的嵌段，和（c）支化单元。本发明还涉及制备高分子量支化聚酰胺聚合物的方法，其包括（1）熔融混合步骤，其中主要由AA-BB重复单元组成的基本上线性的聚酰胺预聚物（X-1），提供主要由AB重复单元组成的基本上线性的聚酰胺（预）聚合物（X-2）和支化剂，并在熔融混合装置中混合并加热，从而形成混合熔体，并将混合的熔体冷却，从而形成固体混合物; 和（2）固态后冷凝步骤，其中固体混合物在固体状态下在升高的温度下后冷凝，从而形成高分子量支化聚酰胺聚合物。

5. 发明申请

WO2009063067A3 HIGH PERFORMANCE MEMBRANE 审中-公开
标题翻译：高性能膜
公开(公告)号：WO2009063067A3
公开(公告)日：2009-07-30
申请号：PCT/EP2008065593
申请日：2008-11-14
申请人： DSM IP ASSETS BV , QIU JUN , RULKENS RUDY , KAMP OP DEN JOHANNES LEONARDUS MARIA , THIES JENS CHRISTOPH
发明人： QIU JUN , RULKENS RUDY , KAMP OP DEN JOHANNES LEONARDUS MARIA , THIES JENS CHRISTOPH
IPC分类号： B01D67/00 , B01D69/12
CPC分类号： B01D67/0088 , B01D69/02 , B01D71/26 , B01D71/56 , B01D2323/02 , B01D2325/22 , B01D2325/24 , H01M2/145 , H01M2/1653
摘要： The invention relates to a micro-porous membrane comprising a porous membrane carrier made of a first polymeric material (A) and comprising a second polymeric material (B) intimately divided throughout the porous membrane carrier, wherein the porous membrane carrier comprises a plurality of interconnected polymeric fibers, fibrils, filaments and/or lamellae having a thickness of less than 1 µm, the porous membrane carrier has an interconnected open porous structure formed by the plurality of interconnected polymeric fibers, fibrils, filaments and/or lamellae and a porosity of at least 50%; and the polymeric material (B) comprises a thermoplastic polycondensation polymer and is present in an amount of at most 30 wt.%, relative to the total weight of (A) and (B). The invention also relates to a process for preparing such a micro-porous membrane comprising steps wherein (i) a porous membrane carrier made of a first polymeric material (A) is impregnated with a polymer solution comprising a second polymeric material (B) in a solvent system (X), and (ii) the resulting impregnated membrane carrier is quenched in a non-solvent system (Y), thereby precipitating at least part of the second polymeric material (B).
摘要翻译：本发明涉及一种微孔膜，其包含由第一聚合物材料（A）制成的多孔膜载体并且包含紧密分散在整个多孔膜载体中的第二聚合物材料（B），其中所述多孔膜载体包含多个互连的厚度小于1μm的聚合物纤维，原纤维，长丝和/或薄片，多孔膜载体具有由多个相互连接的聚合物纤维，原纤维，长丝和/或薄片形成的互连的开放多孔结构，孔隙率为至少50％; 并且聚合物材料（B）包含热塑性缩聚聚合物并且以相对于（A）和（B）的总重量计至多30重量％的量存在。本发明还涉及制备这种微孔膜的方法，其包括以下步骤：（i）用包含第二聚合物材料（B）的聚合物溶液浸渍由第一聚合物材料（A）制成的多孔膜载体，溶剂系统（X），和（ii）所得浸渍膜载体在非溶剂体系（Y）中骤冷，由此沉淀至少部分第二聚合物材料（B）。

6. 发明申请

WO2006133968A1 INTRINSICALLY GEL-FREE, RANDOMLY BRANCHED POLYAMIDE 审中-公开
标题翻译：本质无凝胶，随机分配聚酰胺
公开(公告)号：WO2006133968A1
公开(公告)日：2006-12-21
申请号：PCT/EP2006/005859
申请日：2006-06-19
申请人： DSM IP ASSETS B.V. , BRONSAER, Cornelia, Emilie, Maria , RULKENS, Rudy
发明人： BRONSAER, Cornelia, Emilie, Maria , RULKENS, Rudy
IPC分类号： C08G69/36 , C08G69/02 , C08G69/04 , C08G69/16 , C08G69/48
CPC分类号： C08G69/16 , B32B27/08 , B32B27/32 , B32B27/34 , B32B2250/24 , C08G69/02 , C08G69/04 , C08G69/36 , C08G69/48
摘要： The invention relates to an intrinsically gel-free, randomly branched polyamide that is built up at least of units derived from: 1. AB monomers; 2. at least one compound I, this being a dicarboxylic acid (A 2 ); 3. at least one compound II, this being a triamine (B 3 ); and 4. optionally a compound III, this being a monocarboxylic acid (A 1 ), characterized in that the polyamide is also built up of units derived from 5. at least one compound IV, this being a diamine (B 2 ); and in that the relative amounts n of the said compounds satisfy the following relationships.
摘要翻译：本发明涉及一种固有无凝胶的随机分支的聚酰胺，其至少由衍生自以下的单元构成：1.AB单体; 2.至少一种化合物I，其为二羧酸（A 2 S 2）; 3.至少一种化合物II，其为三胺（B 3 N 3）; 和4.任选的化合物III，它是一元羧酸（A 1 SUB），其特征在于聚酰胺也由衍生自5.至少一种化合物IV的单元构成，这是二胺（B _{2 ）; 并且所述化合物的相对量n满足以下关系。}

7. 发明申请

WO2011135018A1 SEMI-AROMATIC POLYAMIDE 审中-公开
标题翻译：半芳族聚酰胺
公开(公告)号：WO2011135018A1
公开(公告)日：2011-11-03
申请号：PCT/EP2011/056713
申请日：2011-04-28
申请人： DSM IP Assets B.V. , RULKENS, Rudy
发明人： RULKENS, Rudy
IPC分类号： C08G69/26 , C08G69/28 , C08L77/06
CPC分类号： C08G69/265 , C08G69/28 , C08L77/06
摘要： The invention relates to a semi-aromatic polyamide, and a polyamide composition comprising the semi-aromatic polyamide, comprising a diamine component (a) comprising, based on the total number of moles of the diamine component (a): between 5 and 30 mole% of at least one C2-C5 diamine, between 5 and 30 mole% of at least one C7+ diamine, and between 45 and 90 mole% of a C6 diamine; and a dicaboxylic acid component (b) comprising, based on the total number of moles of the dicaboxylic acid component (b): at least 50 mole % of terephthalic acid and at most 50 mole % of another dicarboxylic acid.
摘要翻译：本发明涉及半芳族聚酰胺和包含半芳族聚酰胺的聚酰胺组合物，其包含二胺组分（a），其基于二胺组分（a）的总摩尔数：5-30摩尔％的至少一种C 2 -C 5二胺，5至30摩尔％的至少一种C 7+二胺和45至90摩尔％的C 6二胺; 和二羧酸组分（b），其包含基于二十八烷酸组分（b）的总摩尔数：至少50摩尔％的对苯二甲酸和至多50摩尔％的另一种二羧酸。

8. 发明申请

WO2011006967A1 ELECTROSPINNING OF POLYAMIDE NANOFIBERS 审中-公开
标题翻译：聚氨酯纳米纤维的电纺
公开(公告)号：WO2011006967A1
公开(公告)日：2011-01-20
申请号：PCT/EP2010/060222
申请日：2010-07-15
申请人： DSM IP ASSETS B.V. , DULLAERT, Konraad, Albert, Louise, Hector , BULTERS, Markus, Johannes, Henricus , RULKENS, Rudy , CHICHE, Arnaud, David, Henri
发明人： DULLAERT, Konraad, Albert, Louise, Hector , BULTERS, Markus, Johannes, Henricus , RULKENS, Rudy , CHICHE, Arnaud, David, Henri
IPC分类号： D01D5/00 , D01F6/60 , D01F6/90
CPC分类号： D01D5/0038 , B01D39/1623 , B01D69/10 , B01D71/56 , B01D2239/025 , B01D2239/0631 , B01D2323/39 , B01D2325/48 , D01F6/60 , D01F6/90 , Y10T442/681
摘要： The invention relates to a process for the preparation of polyamide nanofibers by electrospinning, wherein the process is a multi-nozzle electrospinning process with the use of a multi-nozzle device or a nozzle-free electrospinning with the use of nozzle free device, comprising steps wherein a high voltage is applied, a polymer solution comprising a polymer and a solvent is fed to the multi-nozzle device or the nozzle free device and transformed under the influence of the high voltage into charged jet streams the jet streams are deposited on a substrate or taken up by a collector, and the polymer in the jet streams solidifies thereby forming nanofibres, and wherein the polymer comprises a semi-crystalline polyamide having a C/N ratio of at most 5.5 and a weight average molecular weight (Mw) of at most 35,000. The invention also relates polyamide nanofibers made by the electrospinning process, as well as to products made thereof and use thereof.
摘要翻译：本发明涉及一种通过静电纺丝制备聚酰胺纳米纤维的方法，其中该方法是使用多喷嘴装置或无喷嘴的静电纺丝的多喷嘴静电纺丝方法，其中使用无喷嘴的装置，包括步骤其中施加高电压，将包含聚合物和溶剂的聚合物溶液供给到多喷嘴装置或无喷嘴装置，并在高压影响下转化为带电喷射流，喷射流沉积在基板上或由收集器吸收，并且喷射流中的聚合物固化从而形成纳米纤维，并且其中聚合物包含C / N比至多5.5的半结晶聚酰胺和重均分子量（Mw）在最多35,000。本发明还涉及通过静电纺丝方法制造的聚酰胺纳米纤维，以及由其制成的产品及其用途。

9. 发明申请

WO2010081871A1 TRANSPARENT FILMS 审中-公开
标题翻译：透明胶片
公开(公告)号：WO2010081871A1
公开(公告)日：2010-07-22
申请号：PCT/EP2010/050448
申请日：2010-01-15
申请人： DSM IP Assets B.V. , STROEKS, Alexander Antonius Marie , RULKENS, Rudy , LEE, Sanghoon , SIDIKI, Tamim Peter
发明人： STROEKS, Alexander Antonius Marie , RULKENS, Rudy , LEE, Sanghoon , SIDIKI, Tamim Peter
IPC分类号： C08J5/18
CPC分类号： C08G69/26 , B29C47/0021 , B29C47/0057 , B29C47/8845 , B29C47/887 , B29C47/8875 , B29C47/8895 , C08J5/18 , C08J2377/00 , C08L77/06
摘要： The invention relates to an optically transparent polymer film or extrudate product made of a polymer composition comprising a semi-crystalline polyamide having a melting temperature of at least 270 °C or a blend of the semi- crystalline polyamide (A) and a second polymer (B), and optionally at least one additive, wherein the semi-crystalline polyamide (A) is present in an amount of more than 50 wt.%, relative to the total weight of the polymer composition, the polymer composition in the optically transparent polymer film or extrudate product has a melting temperature (Tm-C) in the range of 270-340 °C, and wherein the film or a part of the extrudate product has a haze of less than 12 % and a light transmittance, of at least 88 % measured with the method according to ASTM D1003A.
摘要翻译：本发明涉及由包含熔融温度至少为270℃的半结晶聚酰胺或半结晶聚酰胺（A）和第二聚合物（A）的共混物的聚合物组合物制成的光学透明聚合物膜或挤出物产品， B）和任选的至少一种添加剂，其中相对于聚合物组合物的总重量，半结晶聚酰胺（A）的存在量大于50重量％，光学透明聚合物中的聚合物组合物膜或挤出物的熔融温度（Tm-C）在270-340℃的范围内，并且其中所述膜或一部分挤出物产品的雾度小于12％，透光率至少为 88％用根据ASTM D1003A的方法测量。

10. 发明申请

WO2013014236A1 PROCESS FOR PREPARING A DIAMINE/DICARBOXYLIC ACID SALT 审中-公开
标题翻译：制备二胺/二羧酸盐的方法
公开(公告)号：WO2013014236A1
公开(公告)日：2013-01-31
申请号：PCT/EP2012/064698
申请日：2012-07-26
申请人： DSM IP ASSETS B.V. , GROLMAN, Eric , RULKENS, Rudy
发明人： GROLMAN, Eric , RULKENS, Rudy
IPC分类号： C07C209/68 , C07C211/09 , C07C211/12 , C07C51/41 , C07C63/331
CPC分类号： C07C209/68 , C07B2200/13 , C07C51/412 , C07C55/14 , C07C55/20 , C07C63/28 , C07C211/09 , C07C211/12 , C08G69/04 , C08G69/265 , C07C63/24 , C07C63/26 , C07C63/36
摘要： The present invention also relates to a process for preparing a diamine/dicarboxylic acid salt wherein the dicarboxylic acid comprises an aromatic dicarboxylic acid and is provided in a powder form; the diamine is provided in a liquid form gradually dosed to the dicarboxylic acid powder, while keeping the dicarboxylic acid powder in constant movement; the processing temperature is above 0º C and below the boiling temperature of the diamine and the melting temperature of the acid and the salt, and the reaction mixture comprises at most 5 wt.% of water. The present invention also relates to an anhydrous diamine/dicarboxylic acid salt obtainable by the process according to invention, or any embodiment thereof as described above.
摘要翻译：本发明还涉及一种制备二胺/二羧酸盐的方法，其中二羧酸包括芳族二羧酸并以粉末形式提供; 二胺以逐渐递送到二羧酸粉末的液体形式提供，同时保持二羧酸粉末恒定运动; 处理温度高于0℃且低于二胺的沸点温度和酸和盐的熔融温度，反应混合物含有至多5重量％的水。本发明还涉及通过本发明的方法获得的无水二胺/二羧酸盐或其如上所述的任何实施方案。

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